Nikonov, Georgii I. - Brock University - Department of Chemistry

研究领域

Organometallic chemistry; Transition metal hydrides; Homogeneous catalysis; New ligand environments; Nonclassical bonding.

近期论文

查看导师新发文章（温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

MaiV. H., Korobkov I., Nikonov G.I., “Half-sandwich silane s-complexes of ruthenium supported by NHC carbene”, Organometallics, 2016, 35, 936–942. MaiV. H., Nikonov G.I., “Transfer hydrogenation of nitriles, olefins, and N-heterocycles catalyzed by an NHC-supported half-sandwich complex of ruthenium”, Organometallics, 2016, 35, 943–949. McLeod N.A.; Kuzmina L.G.,; Korobkov I., Howard J. A. K., Nikonov G.I., “Hydridosilylamido complexes of Ta and Mo isolobal with Berry’s zirconocenes: syntheses, β-Si–H agostic interactions, catalytic hydrosilylation, and insight into mechanism”, Dalton Transactions, 2016, 45, 2554 - 2561. Mai V.H., Kuzmina L.G., Churakov A.V., Korobkov I., Howard J. A. K., Nikonov G.I., “NHC-carbene supported half-sandwich hydridosilyl complexes of ruthenium: the impact of supporting ligands on Si…H interligand interactions”, Dalton Transactions, 2016, 45, 208 – 215. Chu T.,Boyko Y., Korobkov I., Nikonov G.I., “Transition metal-like oxidative addition of C-F and C-O bonds to an aluminum(I) center”, Organometallics, 2015, 34, 5363–5365. Khalimon A.Y., Farha P., Nikonov G.I., “Imido-hydride Complexes of Mo(IV): Catalysis and Mechanistic Aspects of Hydroboration Reactions”, Dalton Transactions, 2015, 44, 18945 – 18956. Nikonov G. I., “An Iron Catalyst for Asymmetric Alkene Hydrosilylation”, ChemCatChem 2015, 7, 1918–1919. Lee S.H., Nikonov G. I., “Transfer hydrogenation of ketones, nitriles and esters catalysed by a half-sandwich complex of ruthenium”, ChemCatChem 2015, 7, 107-113 (cover page). Revunova K., Nikonov G. I., “Main group catalysed reduction of unsaturated bonds”, Dalton Transactions 2015, 44, 840 - 866. Chu T., Korobkov I., Nikonov G.I. “Oxidative addition of s bonds to an Al(I) center”, J. Am. Chem. Soc. 2014, 136, 9195–9202. Nikonov G.I. Vyboishchikov S.F., Shirobokov O.G., Simionescu R., “Serendipitous metal catalyzed H–H/Si–H exchange”, Eur. J. Inorg. Chem. 2014, 2896–2901. Lee S.H., Nikonov G. I., “Semi-catalytic reduction of secondary amides to imines and aldehydes”, Dalton Transactions 2014, 43, 8888 - 8893. Khalimon A. Y., McLeod N. A., Ignatov S.K., Okhapkin A. I., Kuzmina L. G., Howard J. A.K., Nikonov G. I. “Multiple coupling of silanes with imido complexes of Mo”,Dalton Transactions 2014, 43, 8446 - 8453. Chu T., Belding L., van der Est A., Dudding T., Korobkov I, Nikonov G.I. “A coordination compound of Ge(0) stabilized by a diiminopyridine ligand”, Angew. Chem. Int. Ed. 2014, 53, 2711 –2715. Revunova K., Nikonov G. I., ”Metal-free base-catalyzed hydrosilylation: substrate scope and mechanism”, Chem. Eur. J. 2014, 20, 839- 845. McLeod N. A., Kuzmina L. G.,Churakov A. V., Mountford P., Nikonov G. I., ”Group 5 hydride and borohydride complexes supported by cyclopentadienyl-imido ligand sets”, Dalton Trans., 2014, 43,188. Lee S.H., Gorelsky S. I., Nikonov G. I., “Catalytic H/D Exchange of Unactivated Aliphatic C-H Bonds”, Organometallics, 2013, 32, 6599–6604. Boone C., Nikonov G.I., “The role of zinc hydride in catalytic hydrosilylation of ketones and nitriles: insertion versus cyclic mechanisms”, ACS Catalysis 2013, 3, 2336–2340. Khalimon A. Y., Ignatov S.K., Simionescu R., Kuzmina L. G., Howard J. A.K., Nikonov G. I.,“Unusual Structure, Fluxionality and Mechanism of Carbonyl Hydrosilylation by the Silyl Hydride Complex (ArN=)Mo(H)(SiH2Ph)(PMe3)3”, Chem. Eur. J. 2013, 19, 8573–859. Lee S.-H., Gutsulyak D. V., Nikonov G. I., “Chemo- and regioselective catalytic reduction of N-heterocycles by silane”, Organometallic, 2013, 32, 4457(invited to the cover page) Khalimon A. Y., Peterson E., Lorber C., KuzminaL.G., Howard J.A.K., Nikonov G. I., “Imido-Supported Borohydrides of Titanium, Vanadium and Molybdenum”, Eur J. Inorg. Chem. 2013, 2205–2211. Khalimon A. Y., Shirobokov O.G., Peterson E., Simionescu R., KuzminaL.G., Howard J.A.K., Nikonov G. I.,"Mechanistic Aspects of Hydrolsilylation Catalyzed by (ArN=)Mo(H)(Cl)(PMe3)3", Inorg. Chem. 2012, 51,4300–4313. Nikonov G.I., Vyboishchikov S.F., Shirobokov O.G., “Facile activation of H–H and Si–H bonds by boranes”, J. Am. Chem. Soc. 2012, 134,5488 Gutsulyak D.V., Nikonov G.I., “Chemoselective Ruthenium-catalyzed Reduction of Acid Chlorides to Aldehydes with Dimethylphenylsilane”, Adv. Synth.&Cat. 2012, 354, 607. Khalimon A. Y., Ignatov S.K., Simionescu R., Kuzmina L. G., Howard J. A.K., Nikonov G. I.,“An Unexpected Mechanism of Hydrosilylation by a Silyl Hydride Complex of Molybdenum”, Inorg. Chem. 2012, 51, 754-756.