Lemaire, Martin T. - Brock University - Department of Chemistry

研究领域

Molecule-based materials; Synthesis; Coordination chemistry; Redox-active ligands; Magnetic properties; Spin-crossover & valence tautomerism

近期论文

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Taylor, R.; Lough, A.J.; Seda, T.; Lemaire, M.T. Structure and unusual magnetic properties of an iron complex containing a redox arylazo ligand. Manuscript in preparation, 2015. Bonnano, N.M.; Walsby, C.; Prosser, K.; Lough, A.J.; Lemaire, M.T. Synthesis, structure and electronic properties of an open-shell stable ditopic redox-active ligands. Manuscript submitted to Dalton Transactions (in revision), 2015. Taylor, R.; Williams, H.; Cibian, M.; Hannon, G.; Lemaire, M.T. Ln(Papl)3 complexes (Ln = Gd, Dy, Tb): Synthesis, magnetism and emission behavior. Manuscript in preparation, 2015. Taylor, R.; Lough, A.J.; Lemaire, M.T.. Spin-crossover in a homoleptic cobalt(II) complex containing a redox-active NNO ligand. Manuscript submitted to Journal of Materials Chemistry C (in revision), 2015. Taylor, R.; Lough, A.J.; Lemaire, M.T Structural features and electronic properties of a cupric complex with redox active 1-(2-pyridylazo)-9-phenanthrol (papl). Manuscript in press, Polyhedron, 2015. Bonanno, N.M.; Van Damme N.; Lough, A.J.; Lemaire, M.T. Transition metal complexes containing a ditopic redox active ligand featuring very intense visible absorption bands. Dyes Pigm. 2015, 123, 212-217. Sheepwash, M.A.L.; Lough, A.J.; Poggini, L.; Poneti, G.; Lemaire, M.T. Structure, magnetic properties and electronic structure of a nickel(II) complex with redox-active 6-(8-quinolylamino)-2,4-bis(tert-butyl)phenol. Polyhedron 2015, http://dx.doi.org/10.1016/j.poly.2015.06.010. Dinsdale, D.R.; Lough, A.J.; Lemaire, M.T. Structure and magnetic properties of an unusual homoleptic iron(III) thiocyanate dimer. Dalton Trans. 2015, 44, 11077-11082. Dowling, C.; Dinsdale, D.R.; Lemaire, M.T. Preparation, electrochemical behavior and variable temperature magnetic properties of Co(3,5-DBSQ)2 complexes of imidazole- or pyrazole-substituted ligands. Can. J. Chem. 2015, 93, 769-774. Van Damme, N.; Zaliskyy, V.; Lough, A.J.; Lemaire, M.T. Structure and magnetic properties of a cobalt(III) complex with redox active 1-(2-pyridylazo)-2-phenanthrol (papl). Polyhedron 2015, 89, 155-159. Dowling, M.; Lemaire, M.T. Preparation, electrochemical behavior and variable temperature magnetic properties of transition metal complexes containing 2-phenyl-4,5-di-(2-pyridyl)imidazole. Transit. Metal Chem. 2014, 39, 843-848. Wilson, D.; Djukic, B.; Lemaire, M.T. Synthesis of bromine- or aryl-substituted ditopic Schiff base ligands and their bimetallic iron(II) complexes: Electronic and magnetic properties. Transit. Metal Chem. 2014, 39, 17-24. Van Damme, N.; Lough, A.J.; Gorelsky, S.I.; Lemaire, M.T. Molecular and electronic structures of complexes containing 1-(2-pyridylazo)-2-phenanthrol (PAPL): Revisiting a redox-active ligand. Inorg. Chem. 2013, 52, 13021-13028. Djukic, B.; Jenkins, H.A.; Seda, T.; Lemaire, M.T. Structural and magnetic properties of homoleptic iron(III) complexes containing N-(8-quinolyl)-salicylaldimine [Fe(Qsal)2]+X- {X = I or (Qsal)FeCl3}. Transit. Metal Chem. 2013, 38, 207-212. Revunova, K.; Gorelsky, S.I.; Lemaire, M. T. Synthesis and coordination chemistry of a ditopic precursor to a triarylamminium radical cation ligand. Polyhedron 2013, 52, 1118-1125. Djukic, B.; Lough, A. J.; Seda, T.; Gorelsky, S. I.; Lemaire, M.T. Pi-extended and six-coordinate iron(II) complexes: Structures, magnetic properties, and the electrochemical synthesis of a conducting iron(II) metallopolymer. Inorg. Chem. 2011, 50, 7334-7343. Lemaire, M.T. Progress and design challenges for high-spin molecules. Pure and Appl. Chem., 2011, 83, 141-149. Adugna, S.; Revunova, K.; Djukic, B.; Gorelsky, S.I.; Jenkins, H.A.; Lemaire, M.T. Persistent metal bis(hexafluoroacetylacetonato) complexes featuring a 2,2-bipyridine substituted triarylamminium radical cation. Inorg. Chem. 2010, 49, 10183-10190. Cheng, H.; Djukic, B.; Jenkins, H.A.; Gorelsky, S.I.; Lemaire, M.T. Iron(II) complexes containing thiophene-substituted “bispicen” ligands: Spin-crossover, ligand rearrangements, and ferromagnetic interactions. Can. J. Chem. 2010, 88, 954-963. Djukic, B; Singh, M.A.; Lemaire, M.T. Formation of Spin-Crossover Polymer Microspheres. Syn. Metals 2010, 160, 825-828. Djukic, B.; Lemaire, M.T. A Hybrid Spin-Crossover Conductor Exhibiting Unusual Variable Temperature Electrical Conductivity. Inorg. Chem. 2009, 48, 10489-10491. Djukic, B.; Poddutoori, P.K.; Dube, P.A.; Seda, T.; Jenkins, H.A.; Lemaire, M.T. Bimetallic iron(3+) spin-crossover complexes containing a 2,2’-bithienyl bridging bis-QsalH ligand. Inorg. Chem. 2009, 48, 6109-6166. O’Sullivan, T.J.; Djukic, B.; Dube, P.A.; Lemaire, M.T. Preparation and properties of thienyl and 2,2’-bithienyl substituted cobalt-bis(semiquinone) valence tautomers. Can. J. Chem. 2009, 87, 533-538. O’Sullivan, T.J.; Djukic, B.; Dube, P.A.; Lemaire, M.T. A Conducting Metallopolymer Featuring Valence Tautomerism. Chem. Commun. 2009, 1903-1905. Djukic, B.; Dube, P.A.; Razavi, F.; Seda, T.; Jenkins, H.A.; Britten, J. F.; Lemaire, M.T. Preparation and magnetic properties of iron(3+) spin-crossover complexes bearing a thiophene substituent: Toward multifunctional metallopolymers. Inorg. Chem. 2009, 48, 699-707.