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Mukund Ghavre, Jordan Froese, Brennan Murphy, Razvan Simionescu, and Tomas Hudlicky, A Formal Approach to Xylosmin and Flacourtosides E and F: Chemoenzymatic Total Synthesis of the Hydroxylated Cyclohexenone Carboxylic Acid Moiety of Xylosmin, Organic. Letters., 2017 Yang, L.; Drew, B.; Yalagala, R.; Chaviwala, R.; Simionescu, R.; Lough, A.;* Yan, H.* Solvent-dependent behaviours of 3-amino-1,6-diethyl-4,4-diphenyl-2,5,7-trimethyl-1,5,7,8-tetramethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene, Acta Crystallogr. E. 2017, E73, 378. Yang Qu, Razvan Simonescu, and Vincenzo De Luca, Monoterpene Indole Alkaloids from the Fruit of Tabernaemontana Litoralis and Differential Alkaloid Composition in Various Fruit Components, Journal of Natural Products, 2016 Lukas Rycek, John J. Hayward, Marwa Abdel Latif, James Tanko, Razvan Simionescu, and Tomas Hudlicky, Chemoenzymatic total synthesis of hydromorphone by an oxidative dearomatization/intramolecular [4+2] cycloaddition sequence: a 2nd generation approach, J. Org. Chem.,2016 Yang Qu, Michael L. A. E. Easson, Jordan Froese, Razvan Simionescu, Tomas Hudlicky, and Vincenzo De Luca, Completion of the seven-step pathway from tabersonine to the anticancer drug precursor vindoline and its assembly in yeast, Biological Sciences - Plant Biology 2015, Nikonov G.I., Vyboishchikov S.F., Shirobokov O.G., Simionescu R., “Serendipitous metal catalyzed H–H/Si–H exchange”, accepted to Eur. J. Inorg. Chem. 2014, Mary Ann A. Endoma-Arias, Jason Reed Hudlicky, Razvan Simionescu, Tomas Hudlicky,"Chemoenzymatic Formal Total Synthesis of ent-Codeine and Other Morphinans via Nitrone Cycloadditions and/or Radical Cyclizations. Comparison of Strategies for Control of C-9/C-14 Stereogenic Centers", Advanced Sythesis and Catalysis, February 2014 Andrey Khalimon, Stanislav K. Ignatov, Andrey I. Okhapkin, Razvan Simionescu, Lyudmila G. Kuzmina, Judith A. K. Howard, Georgii I. Nikonov Unusual "Structure, Fluxionality, and Reaction Mechanism of Carbonyl Hydrosilylation by Silyl Hydride Complex [(ArN=)Mo(H)(SiH2Ph)(PMe3)3]", Chemistry - A European Journal 2013, 19, 8573-8590 • May 13, 2013 David Hurem , Andrey G. Moiseev , Razvan Simionescu , and Travis Dudding, "A Detailed NMR- and DFT-Based Study of the Sakurai–Hosomi–Yamamoto Asymmetric Allylation Reaction", Journal of Organic Chemistry, J. Org. Chem., 78 (9), pp 4440–4445, April 2013 Yang, L.; Li, J.; Simionescu, R.; Yan, H*. Observation of two N2-isobutyrylguanine tautomers by NMR spectroscopy, Magn. Reson. Chem., Vol 51., Issue 1, pages 60-64, Jan. 2013 Mark Frampton, Razvan Simionescu, Paul M. Zelisko "Enzyme-mediated Synthesis of Silsesquioxanes", Silicon 04/2012; 1(1):47-56 Khalimon A. Y., Shirobokov O.G., Peterson E., Simionescu R., KuzminaL.G., Howard J.A.K., Nikonov, G. I."Mechanistic Aspects of Hydrolsilylation Catalyzed by (ArN=)Mo(H)(Cl)(PMe3)3", Inorg. Chem.2012,51 (7), pp 4300–4313 An Unexpected Mechanism of Hydrosilylation by a Silyl Hydride Complex of Molybdenum, Andrey Y. Khalimon, Stanislav K. Ignatov, Razvan Simionescu, Lyudmila G. Kuzmina, Judith A. K. Howard, and Georgii I Nikonov, Inorg. Chem., 2012, 51 (2), pp 754–7562012 Catalytic and stoichiometric reactivity of β-silylamido agostic complex of Mo: intermediacy of a silanimine complex and applications to multicomponent coupling, Khalimon, Andrey Y.; Simionescu, Razvan; Nikonov, Georgii I.,Journal of the American Chemical Society, 2011, 133(18), 7033-7053. Some observations relating to the stability of the BODIPY fluorophore under acidic and basic conditions: Lijing Yang, Razvan Simionescu, Alan Lough and Hongbin Yan, Dyes and Pigments, 2011 Dauben–Michno oxidative transposition of allylic cyanohydrins — Enantiomeric switch of (–)-carvone to (+)-carvone, Jason R. Hudlicky, Lukas Werner, Vladislav Semak, Razvan Simionescu, and Tomas Hudlicky, Canadian Journal of Chemistry, 2011, 89:535-543, 10.1139/v11-026 Oleg G. Shirobokov, Serge I. Gorelsky, Razvan Simionescu, Lyudmila G. Kuzmina and Georgii I. Nikonov; The unexpected mechanism of carbonyl hydrosilylation catalyzed by (Cp)(ArN)Mo(H)(PMe3) Chem. Commun., 2010, 46, 7831-7833 Frampton, MB; Simionescu, R; Dudding, T; Zelisko, PM. The Enzymatic Cleavage of Si-O Bonds: A Kinetics Analysis of the Biocatalyzed Hydrolysis of Phenyltrimethoxysilane. J. Mol. Cat. B: Enzymatic, 2010, 66, 105-112. Design of Thermally Stable Versions of the Burgess Reagent: Stability and Reactivity Study, Thomas A. Metcalf, Razvan Simionescu, and Tomas Hudlicky*, J. Org. Chem. 2010, 75, 3447–3450 Mark Frampton, Razvan Simionescu and Paul M. Zelisko, “Enzyme-Mediated Synthesis of Silsesquioxanes”, Silicon 2009 , Volume 1, 47-56. Peterson, E.; Khalimon, A. Y.; Simionescu, R.; Kuzmina, L.G.; Howard, J.A.K.; Nikonov, G. I. “Diversity of catalysis by an imido-hydrido complex of molybdenum. Mechanism of carbonyl hydrosilylation and silane alcoholysis.”, J. Am. Chem. Soc. 2009, 113, 1199-1209. Andrey Y. Khalimon, Razvan Simionescu, Lyudmila G. Kuzmina, Judith A. K. Howard and Georgii I. Nikonov "Agostic NSi-H-Mo Complexes: From Curiosity to Catalysis" - Angew. Chem. Int. Ed. 2008, 47, 7701-7704 Stephan Ohnmacht, Ryan West, Razvan Simionescu, Jeffrey Atkinson. "Assignment of the 1H and 13C NMR of Tocotrienols". Mag. Res. Chem. 2008 46(3), 287-294. Zelisko, PM; Arnelien, KR; Dudding, T; Simionescu, R; Stanisic, H. Enzyme Mediated Cross-Linking of Silicone Polymers. Polymer Preprints, 2007, 48(2), 984-985. Khalimon A. Y., Lin Z., Simionescu R., Vyboishchikov S. F., Nikonov G. I. “Persistent silylium ions stabilized by polyagostic Si-H-Si interactions”, Angew. Chem. Int. Ed. 2007, 46, 4530-4533.

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