Metallinos, Costa - Brock University - Department of Chemistry

研究领域

Synthetic organic and organometallic chemistry

近期论文

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Metallinos, C.; Stromski, K., “Metalation Reactions of Pyridines, Quinolines, and Isoquinolines with Ate Bases and Their Alkali Metal Salt-Modified Congeners” in Metalation of Azines and Diazines (Topics in Heterocyclic Chemistry); Schnürch, M.; Mihovilovic, M. D. (Eds.), Springer, 2013, pp. 65-92. Deng, W.-P.; Snieckus, V.; Metallinos, C., "Stereoselective Synthesis of Planar Chiral Ferrocenes" in Chiral Ferrocenes in Asymmetric Catalysis: Synthesis and Applications; Dai, L.-X.; Hou, X.-L. (Eds.), Wiley-VCH Verlag GmbH & Co. KGaA: Weinheim, Germany 2010, pp. 15-53. Metallinos, C., “Method for Preparing Ortho-Substituted Aminoferrocenes”, United States Patent 7,982,064, July 19, 2011. Metallinos, C., "Product Class 8.1.24: Carbamoyllithium and Trihalomethyllithium Compounds" in Science of Synthesis, Vol. 8a; Majewski, M.; Snieckus, V. (Eds.), Georg Thieme-Verlag KG: Stuttgart, Germany 2006, pp. 795-804. Wilson-Konderka, C.; Doxtator, K.; Metallinos, C., “Selective Synthesis of Enantiomeric η6-Arene Chromium Tricarbonyl Complexes with Epimeric Pyrroloimidazolones”, Adv. Synth. Catal. 2016, 358, 2599-2603. Wilson-Konderka, C.; Lough, A. J.; Metallinos, C., “(+)-trans-Chlorido{2-[(Rp)-2-(methylsulfanyl)ferrocenyl]-2,5,6,7-tetrahydropyrrolo[1,2-c]imidazol-3-ylidene}bis(triphenylphosphane-κP)palladium(II) hexafluoridophosphate dichloroform disolvate”, Acta Cryst. E 2016, 72, 1330-1334. John, J.; Wilson-Konderka, C.; Metallinos, C., “Low Pressure Asymmetric Hydrogenation of Quinolines using an Annulated Planar Chiral N-Ferrocenyl NHC-Iridium Complex”, Adv. Synth. Catal. 2015, 357, 2071-2081. Giannopoulos, D. P..; Wilson-Konderka, C.; Gagnon, K. J., Teat, S. J.; Escuer, A. Metallinos, C., Stamatatos, T. C., “Synthesis and First Use of Pyridine-2,6-diylbis-(pyrazine-2-ylmethanone) in Metal Cluster Chemistry: A {MnIII3Na2} Complex with an Ideal Trigonal Bipyramidal Geometry”, Dalton Trans. 2015, 44, 4318-4327. Metallinos, C.; Sadraei, S. E.; Zhukovskaya, N., “Diastereoselective Synthesis of 5-Substituted Tetrahydro-1H-pyrrolo[1,2-c]imidazol-3(2H)-ones using an N-Silyl Protecting Group", Heterocycles 2014, 88, 347-362 (by invitation). Metallinos, C.; John, J.; Nelson, J.; Dudding, T.; Belding, L. “Reversal of Stereoselectivity in Lithiation of Ferrocenyl-imidazolones: Epimeric Substrates lead to Planar Chiral Enantiomers”, Adv. Synth. Catal. 2013, 355, 1211-1219. Metallinos, C.; John, J.; Zaifman, J.; Emberson, K., “Diastereoselective Synthesis of N-Substituted Planar Chiral Ferrocenes Using a Proline Hydantoin-Derived Auxiliary” Adv. Synth. Catal. 2012, 354, 602-606. Metallinos, C.; Van Belle, L., "Asymmetric Hydrogenation of Alkenes with Cationic Iridium(I) Complexes of Planar Chiral 2-Phosphino-1-Aminoferrocene Ligands " J. Organomet. Chem. 2011, 696, 141-149 (by invitation). Metallinos, C.; Zaifman, J.; Dudding, T.; Van Belle, L.; Taban, K., "Asymmetric Lithiation of BF3-Activated Aminoferrocenes: An Experimental and Computational Investigation", Adv. Synth. Catal. 2010, 352, 1967-1982. Metallinos, C.; Xu, S., "Stereoselective Synthesis of 5-Substituted Pyrrolo[1,2-c]imidazole-3-ones. Access to Annulated Chiral Imidazol(in)ium Salts", Org. Lett. 2010, 12, 76-79. Metallinos, C.; Zaifman, J.; Van Belle, L.; Dodge, L.; Pilkington, M., "Palladium(II), Platinum(II) and Iridium(I) Complexes of 2-Phosphino-1-dimethylaminoferrocenes: A Survey of Structure and Catalysis", Organometallics 2009, 28, 4534-4543. Metallinos, C.; Du, X. "Neutral and Cationic Iridium(I) Complexes Bearing Chiral Phenanthroline-Derived Benzimidazolylidenes: Synthetic, Structural and Catalytic Studies", Organometallics 2009, 28, 1233-1242. Metallinos, C.; Zaifman, J.; Dodge, L., "Aminoferrocene Lithiation by Boron Trifluoride Activation", Org. Lett. 2008, 10, 3527-3530. Metallinos, C.; Barrett, F. B.; Xu, S., "Brønsted Acid Catalyzed Asymmetric Reduction of 2- and 2,9-Substituted 1,10-Phenanthrolines", Synlett 2008, 720-724. Blanchet, J.; Macklin, T.; Ang, P.;Metallinos, C.; Snieckus, V., "Directed ortho Metalation-Cross Coupling Strategies. N-Cumyl Arylsulfonamides. Facile Deprotection and Expedient Route to 4- and 4,7-Substituted Saccharins", J. Org. Chem. 2007, 72, 3199-3206. Metallinos, C.; Dudding, T; Zaifman, J.; Chaytor, J. L.; Taylor, N. J., "An Experimental and Theoretical Study of the Asymmetric Lithiation of 1,2,3,5,6,7-Hexahydro-3a,4a-diazacyclopenta[def]phenanthren-4-one", J. Org. Chem. 2007, 72, 957-963. Metallinos, C.; Barrett, F. B.; Wang, Y.; Xu, S.; Taylor, N. J., "Reduction of Substituted 1,10-Phenanthrolines as a Route to Rigid Chiral Benzimidazolylidenes", Tetrahedron 2006, 62, 11145-11157. Metallinos, C.; Tremblay, D. T.; Barrett, F. B.; Taylor, N. J., "1,1′-Bis(phosphoranylidenamino)ferrocene Palladium(II) Complexes: An Unusual Case of Dative Fe→Pd Bonding", J. Organomet. Chem. 2006, 691, 2044-2047. Metallinos, C.; Barrett, F. B.; Chaytor, J. L.; Heska, M. E. A.,"A Benzimidazole-Based N-Heterocyclic Carbene Derived from 1,10-Phenanthroline", Org. Lett. 2004, 6, 3641-3644. Beierle, J. M.; Osimboni, E. B.; Metallinos, C.; Zhao, Y.; Kelly, T. R., "Synthesis of Louisianin C", J. Org. Chem. 2003, 68, 4970-4972. Metallinos, C.; Szillat, H.; Taylor, N. J.; Snieckus, V., "(–)-Sparteine-Mediated Directed ortho Metalation of N-Cumyl-N-Ethyl Ferrocenecarboxamide. Versatile Routes to Planar Chiral Ferrocenecarboxamides, Amines, Esters and Phosphines", Adv. Synth. Catal. 2003, 345, 370-382.