Herbert, David E. - University of Manitoba

个人简介

Dave was born and raised in North York, Ontario. He attended the University of King’s College/Dalhousie University in Halifax, NS, where he worked with Prof. Neil Burford on the coordination chemistry of phosphorus-based cations (B.Sc. Hons., Chemistry, 2004). He then started graduate school at the University of Toronto (M.Sc., 2006) under the tutelage of Prof. Ian Manners, moving with Ian to the University of Bristol in England where he completed his Ph.D. (2009), earning a Faculty of Science Commendation for his thesis on metal-containing rings and polymers. Upon graduation, Dave moved to dusty central Texas to work with Prof. Oleg V. Ozerov at Texas A&M University on multi-nucleating pincer ligands and catalyst design for biomass deoxygenation, learning X-ray crystallography along the way. In 2011, Dave joined Prof. Theodor Agapie’s group at Caltech, where he divided his time between diverse projects in bioinorganic model-compound chemistry and C-H functionalization at earth-abundant metals. For more details, please see the publications section. In July 2013, Dave began his independent career as an Assistant Professor in the Chemistry Department at the University of Manitoba

近期论文

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"Phenanthridine-Containing Pincer-like Amido Complexes of Nickel, Palladium and Platinum"P. Mandapati, P.K. Giesbrecht, R.L. Davis, D.E. Herbert*, Inorganic Chemistry 2017, ASAP - DOI:10.1021/acs.inorgchem.7b00075 "Fluorocarbene, fluoroolefin, and fluorocarbyne complexes of Rh"C.J. Pell, Y. Zhu, R. Huacuja, D.E. Herbert, R.P. Hughes*, O.V. Ozerov. Chemical Science 2017, Advance Article - DOI:10.1039/C6SC05391B "Electrochemical Reduction of Carbon Dioxide to Methanol in the Presence of Benzannulated Dihydropyridine Additives"P.K. Giesbrecht, D.E. Herbert*. ACS Energy Letters 2017, ASAP, 549-555 - DOI: 10.1021/acsenergylett.7b00047 "Nickel(II), copper(I) and zinc(II) complexes supported by a (4-diphenylphosphino)phenanthridine ligand"?R. Mondal, P.K. Giesbrecht, D.E. Herbert* Polyhedron 2016, 108, 156-162(Invited Contribution to Special Issue: Modern Canadian Inorganic Chemistry) "Covalent Attachment of Ferrocene to Silicon Microwire Arrays"O.S. Kang, J.P. Bruce, D.E. Herbert*, M.S. Freund*. ACS Applied Materials and Interfaces 2015, 7, 26959–26967 "Aryl Ether Cleavage by Group 9 and 10 Transition Metals: Stoichiometric Studies of Selectivity and Mechanism"G.A. Edouard, P. Kelley, D.E. Herbert, T. Agapie*. Organometallics 2015, 34, 5254–5277 "Silyl-Silylene Interplay in Cationic PSiP Pincer Complexes of Platinum" J.C. Demott, W. Gu, B.J. McCulloch, D.E. Herbert, M.D. Goshert, J.R. Walensky, J. Zhou, O.V. Ozerov*. Organometallics 2015, 34, 3930-3933 "Comparison of the Electronic Properties of Diarylamido-Based PNZ Pincer Ligands: Redox Activity at the Ligand and Donor Ability Towards the Metal"J. Davidson, J.C. DeMott, C. Douvris, N. Bhuvanesh, C.-H. Chen, D.E. Herbert, C.-I. Lee, B.J. McCulloch, B. Foxman, O.V. Ozerov*. Inorganic Chemistry 2015, 54, 2916-2935 Heterometallic Triiron-Oxo/Hydroxo Clusters: Effect of Redox-Inactive Metals"D.E. Herbert, D. Lionetti, J. Rittle, T. Agapie*. Journal of the American Chemical Society 2013, 135, 19075-19078 "Dipalladium(I) Terphenyl Diphosphine Complexes as Models for Two-Site Adsorption and Activation of Organic Molecules"S. Lin, D.E. Herbert, A. Velian, M.W. Day, T. Agapie*. Journal of the American Chemical Society 2013, 135, 15830-15840 "Arene C-H Amination at Nickel in Terphenyl Diphosphine Complexes With Labile Metal-Arene Interactions"D.E. Herbert, N.C. Lara, T. Agapie*. Chemistry - A European Journal 2013, “Monomeric Rh(II) Complexes Supported by a Diarylamido/bis(phosphine) PNP Pincer Ligand and Their Reactivity Towards Dihydrogen”D.A. Smith, D.E. Herbert, J.R. Walensky, O.V. Ozerov*. Organometallics 2013, 32, 2050–2058 “Phosphorus(III) Cations Supported by a PNP Pincer Ligand and Sub-Stoichiometric Generation of P4 from Thermolysis of a Nickel Insertion Product”D.E. Herbert, A.D. Miller, O.V. Ozerov*. Chemistry – A European Journal 2012, 18, 7696-7704 “C-H and C-O Oxidative Addition in Reactions of Aryl Carboxylates with a PNP Pincer-Ligated Rh(I) Fragment”Y. Zhu, D.A. Smith, D.E. Herbert, S. Gatard, O.V. Ozerov*. Chemical Communications 2012, 48, 218-220 “Binuclear Palladium Complexes Supported by Bridged Pincer Ligands”D.E. Herbert, O.V. Ozerov*. Organometallics 2011, 30, 6641–6654 “Catalysis of Kumada-Tamao-Corriu Coupling by a (POCOP)Rh Pincer Complex”S.D. Timpa, C.M. Fafard, D.E. Herbert, O.V. Ozerov*. Dalton Transactions 2011, 40, 5426-5429 “Reactivity of a Pd(I)-Pd(I) Dimer With O2: Monohapto Pd Superoxide and Dipalladium Peroxide in Equilibrium”R. Huacuja, D. Graham, C. Fafard, C.-H. Chen, B. Foxman, D.E. Herbert, G. Alliger, C.M. Thomas*, O.V. Ozerov*. Journal of the American Chemical Society 2011, 133, 3820-3823 “A Terminal Palladium Fluoride Complex Supported by an Anionic PNP Pincer Ligand” R. Huacuja, D.E. Herbert, C.M. Fafard, O.V. Ozerov*. Journal of Fluorine Chemistry 2010, 131, 1257-1261 (Special issue in honour of R. P. Hughes) “Strain-Induced Cleavage of Carbon-Carbon Bonds: Bridge Rupture Reactions of Group 8 Dicarba[2]metallocenophanes”D.E. Herbert, J.B. Gilroy, A. Staubitz, M.F. Haddow, J.N. Harvey, I. Manners*. Journal of the American Chemical Society, 2010, 132, 1988-1998 “Redox-Active Metallomacrocycles and Cyclic Metallopolymers: Photocontrolled Ring-Opening Oligomerization and Polymerization of Silicon-Bridged [1]Ferrocenophanes Using Substitutionally-Labile Lewis Bases as Initiators”D.E. Herbert, J.B. Gilroy, W.Y. Chan, L. Chabanne, A. Staubitz, A.J. Lough, I. Manners*. Journal of the American Chemical Society 2009, 131, 14958-14968 “Photocontrolled Ring-Opening Polymerization of Strained Dicarba[2]ferrocenophanes: A Route to Well-Defined Polyferrocenylethylene Homopolymers and Block Copolymers”D.E. Herbert, U.F.J. Mayer, J.B. Gilroy, M.J. López-Gómez, A.J. Lough, J.P.H. Charmant, I. Manners*. Chemistry – A European Journal 2009, 15, 12234-12246 “Synthesis and Reactivity of a Strained Silicon-Bridged [1]Ferroceniumphane”G. Masson, D.E. Herbert, G.R. Whittell, J.P. Holland, A.J. Lough, J.C. Green*, I. Manners*. Angewandte Chemie International Edition in English 2009, 48, 4961-4964 “Strain-Controlled, Photochemically, or Thermally Promoted Haptotropic Shifts of Cyclopentadienyl Ligands in Group 8 Metallocenophanes”D.E. Herbert, M. Tanabe, S.C. Bourke, A.J. Lough, I. Manners*. Journal of the American Chemical Society 2008, 130, 4166-4176 “Strained Metallocenophanes and Related Organometallic Rings Containing π-Hydrocarbon Ligands and Transition-Metal Centers”D.E. Herbert, U.F.J. Mayer, I. Manners*. Angewandte Chemie International Edition in English 2007, 46, 5060-5081 “Reversible, Strain-Controlled Haptotropic Shifts of Cyclopentadienyl Ligands in [1]- and [2]Metallocenophanes”M. Tanabe, S.C. Bourke, D.E. Herbert, A.J. Lough, I. Manners*. Angewandte Chemie International Edition in English 2005, 44, 5886-5890 “Diphosphine-Phosphenium Coordination Complexes Representing Monocations With Pendant Donors and Ligand Tethered Dications” N. Burford*, D.E. Herbert, P.J. Ragogna, R. McDonald, M.J. Ferguson. Journal of the American Chemical Society 2004, 126, 17067-17073