王泉明 - 清华大学

个人简介

EDUCATION AND RESEARCH EXPERIENCE 1985-1989 B.S., Department of Chemistry, Xiamen University 1989-1992 M.S., Department of Chemistry, Xiamen University 1992-1998 FuJian Institute of Research on The Structure 1998-2002 Ph.D., Department of Chemistry, The Chinese University of Hong Kong 2002-2004 Postdoc, Department of Chemistry, Rochester University 2004-2005 Postdoc, Department of Chemistry, UC Riverside 2005-2015 Professor, College of Chemistry and Chemical Enginnering, Xiamen University 2015- Professor, Department of Chemistry, Tsinghua University HONORS AND AWARDS 2001 CUHK Young Scholars Dissertation Award 2006 Supported by Program for New Century Excellent Talents in University 2011 The National Science Fund for Distinguished Young Scholars

研究领域

1、Rational synthesis of metal clusters with anionic templates 2、Cluster-based molecular luminescent materials 3、Coinage metal nanoclusters

近期论文

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Lu-Ming Zheng, Wan-Qi Shi, Feng Hu, Zong-Jie Guan*, and Quan-Ming Wang*, All-Calixarene-Protected Silver Nanocluster with All Silver Atoms in a Face-Centered Cubic Arrangement, J. Am. Chem. Soc., 2024, 10.1021/jacs.4c08094. Xian-Kai Wan & Xu-Shuang Han, Zong-Jie Guan, Wan-Qi Shi, Jiao-Jiao Li, and Quan-Ming Wang*, Interplay of kernel shape and surface structure for NIR luminescence in atomically precise gold nanorods, Nat. Commun., 2024, 15, 7214. Rui-Lin He, Feng Hu, Zong-Jie Guan*, and Quan-Ming Wang*, Large Scale Synthesis of a Stable Prefunctionalized Silver Nanocluster, Angew. Chem. Int. Ed., 2024, e202410827. Zhen Lei, Pei Zhao, Zong-Jie Guan, Zi-Ang Nan, Masahiro Ehara*, and Quan-Ming Wang*, ‘Passivated Precursor’ Approach to All-Alkynyl-Protected Gold Nanoclusters and Total Structure Determination of Au130, Chem. Eur. J., 2024, e202401094. Yang Yang*, Shan Guo, Qian Zhang, Zong-Jie Guan, and Quan-Ming Wang*, A Cages-on-Cluster Structure Constructed by Post-Clustering Covalent Modifications and Guest-Enabled Stimuli-Responsive Luminescence, Angew. Chem. Int. Ed., 2024, e202404798. Wan-Qi Shi & Linlin Zeng, Rui-Lin He, Xu-Shuang Han, Zong-Jie Guan, Meng Zhou* and Quan-Ming Wang*, Near-unity NIR phosphorescent quantum yield from a room-temperature solvated metal nanocluster, Science, 2024, 383, 6680, 326-330. Chun-Yu Liu & Tong-Yu Liu, Zong-Jie Guan, Song Wang, Yuan-Yuan Dong, Feng Hu, De-en Jiang* and Quan-Ming Wang*, Dramatic Difference between Cu20H8 and Cu20H9 Clusters in Catalysis, CCS Chemistry, 2024, 10.31635/ccschem.023.202303448. Xiao-Li Pei, Cheng Ma, Zong-Jie Guan, Shao-Fei Ni*, and Quan-Ming Wang*, Heterometallic AuI6AgI6 Macrocyclic Cluster Templated by a Supramolecular Melamine Dimer, Chem. Eur. J., 2024, e202301948. Feng Hu, Zong-Jie Guan, Shang-Fu Yuan, and Quan-Ming Wang*, Alkynyl-Protected Bimetallic Nanoclusters with a Hybrid Mackay Icosahedral Ag42Cu12Cl Kernel and an Octahedral Ag22Cu12 Kernel, Chem. Asian J., 2023, e202300605. Jia-Qi Wang, Rui-Lin He, Wen-Di Liu, Qi-Yun Feng, Yan-E Zhang, Chun-Yu Liu, Jing-Xuan Ge, and Quan-Ming Wang*, Integration of Metal Catalysis and Organocatalysis in a Metal Nanocluster with Anchored Proline, J. Am. Chem. Soc., 2023, 10.1021/jacs.3c02567. Feng Hu, Rui-Lin He, Zong-Jie Guan, Chun-Yu Liu, and Quan-Ming Wang*, Disc-like Silver Nanocluster Ag93 Built with Bicapped HexagonalPrismatic Ag15 and Ino Decahedral Ag13 Units, Angew. Chem. Int. Ed., 2023, e202304134. Feng Hu, Heng-Wang Luyang, Rui-Lin He, Zong-Jie Guan, Shang-Fu Yuan*, and Quan-Ming Wang*, Face-Centered Cubic Silver Nanoclusters Consolidated with Tetradentate Formamidinate Ligands, J. Am. Chem. Soc., 2022, 144, 42, 19365–19371. Zong-Jie Guan, Jiao-Jiao Li, Feng Hu and Quan-Ming Wang*, Structural Engineering toward Gold Nanocluster Catalysis, Angew. Chem. Int. Ed., 2022, 61, e202209725. Shang-Fu Yuan, Zong-Jie Guan, and Quan-Ming Wang*, Identification of the Active Species in Bimetallic Cluster Catalyzed Hydrogenation, J. Am. Chem. Soc., 2022, 144, 25, 11405–11412. Jiao-Jiao Li&Chun-Yu Liu,Zong-Jie Guan,Zhen Lei, and Quan-Ming Wang*, Anion-Directed Regulation of Structures and Luminescence of Heterometallic Clusters, Angew. Chem. Int. Ed., 2022, 61, e202201549. Chun-Yu Liu, Shang-Fu Yuan, Song Wang, Zong-Jie Guan, De-en Jiang* and Quan-Ming Wang*, Structural transformation and catalytic hydrogenation activity of amidinate-protected copper hydride clusters, Nat. Commun., 2022, 13, 2082. Wan-Qi Shi, Zong-Jie Guan, Jiao-Jiao Li, Xu-Shuang Hana and Quan-Ming Wang*, Site-specific doping of silver atoms into a Au25 nanocluster as directed by ligand binding preferences, Chem. Sci., 2022, 13, 5148-5154. Shang-Fu Yuan, Wen-Di Liu, Chun-Yu Liu, Zong-Jie Guan and Quan-Ming Wang*, Nitrogen donor protection for atomically precise metal nanoclusters, Chem. Eur. J., 2022, 28, e202104445. Zong-Jie Guan, Rui-Lin He, Shang-Fu Yuan, Jiao-Jiao Li, Feng Hu, Chun-Yu Liu and Quan-Ming Wang*, Ligand Engineering toward the Trade-off between Stability and Activity in Cluster Catalysis, Angew. Chem. Int. Ed., 2022, 61, e202116965. Jiao-Jiao Li, Zhikun Liu, Zong-Jie Guan, Xu-Shuang Han, Wan-Qi Shi and Quan-Ming Wang*, A 59-Electron Non-Magic-Number Gold Nanocluster Au99(C≡CR)40 Showing Unexpectedly High Stability, J. Am. Chem. Soc., 2022, 144, 690–694. Shao-Yu Kang, Zi-Ang Nan* and Quan-Ming Wang*, Superatomic Orbital Splitting in Coinage Metal Nanoclusters, J. Phys. Chem. Lett., 2022, 13, 291–295. Feng Hu, Zong-Jie Guan, Gaoyuan Yang, Jia-Qi Wang, Jiao-Jiao Li, Shang-Fu Yuan, Gui-Jie Liang* and Quan-Ming Wang*, Molecular Gold Nanocluster Au156 Showing Metallic Electron Dynamics, J. Am. Chem. Soc., 2021, 143, 17059–17067. Shang-Fu Yuan, Cong-Qiao Xu*, Wen-Di Liu, Jing-Xuan Zhang, Jun Li and Quan-Ming Wang*, Rod-Shaped Silver Supercluster Unveiling Strong Electron Coupling between Substituent Icosahedral Units, J. Am. Chem. Soc., 2021, 143, 12261–12267. Xian-Kai Wan, Jia-Qi Wang and Quan-Ming Wang*, Ligand-Protected Au55 with a Novel Structure and Remarkable CO2 Electroreduction Performance, Angew. Chem. Int. Ed., 2021, 60, 20748-20753. Shang-Fu Yuan, Rui-Lin He, Xu-Shuang Han, Jia-Qi Wang, Zong-Jie Guan and Quan-Ming Wang*, Robust Gold Nanocluster Protected with Amidinates for Electrocatalytic CO2 Reduction, Angew. Chem. Int. Ed., 2021, 60, 14345-14349. Xiao-Li Pei, Zong-Jie Guan, Zi-Ang Nan and Quan-Ming Wang*, Heterometallic Coinage Metal Acetylenediide Clusters Showing Tailored Thermochromic Luminescence, Angew. Chem. Int. Ed., 2021, 60, 14381-14384. Zhen Lei, Jiao-Jiao Li, Zi-Ang Nan, Zhan-Guo Jiang* and Quan-Ming Wang*, Cluster From Cluster: A Quantitative Approach to Magic Gold Nanoclusters [Au25(SR)18]‐, Angew. Chem. Int. Ed., 2021, 60, 14415-14419. Shang-Fu Yuan, Heng-Wang Luyang, Zhen Lei, Xian-Kai Wan, Jiao-Jiao Li and Quan-Ming Wang*, A stable well-defined copper hydride cluster consolidated with hemilabile phosphines, Chem. Commun., 2021, 57, 4315-4318 . Wen-Di Liu, Jia-Qi Wang, Shang-Fu Yuan, Xi Chen* and Quan-Ming Wang*, Chiral Superatomic Nanoclusters Ag47 Induced by the Ligation of Amino Acids, Angew. Chem. Int. Ed., 2021, 60, 11430-11435. Jiao-Jiao Li, Zong-Jie Guan, Shang-Fu Yuan, Feng Hu and Quan-Ming Wang*, Enriching Structural Diversity of Alkynyl‐Protected Gold Nanoclusters with Chlorides, Angew. Chem. Int. Ed., 2021, 60, 6699-6703. Shang-Fu Yuan, Zhen Lei, Zong-Jie Guan and Quan-Ming Wang*, Atomically precise preorganization of open metal sites on gold nanocluster with high catalytic performance, Angew. Chem. Int. Ed., 2021, 60, 5225-5229. Jia-Qi Wang, Shuang Shi, Rui-Lin He, Shang-Fu Yuan, Gao-Yuan Yang, Gui-Jie Liang* and Quan-Ming Wang*, Total Structure Determination of the Largest Alkynyl-Protected FCC Gold Nanocluster Au110 and the Study on its Ultrafast Excited-State Dynamics, J. Am. Chem. Soc., 2020, 142, 18086–18092. Zong-Jie Guan and Quan-Ming Wang*, Ligand Engineering in Metal Nanoclusters:from Structural Control to Functional Modulation, Chinese J. Struct. Chem., 2020, 39, 1194-1200. Zong-Jie Guan, Feng Hu, Jiao-Jiao Li, Zirui Liu and Quan-Ming Wang*, Homoleptic Alkynyl-Protected Gold Nanoclusters with Unusual Compositions and Structures, Nanoscale, 2020, 12, 13346-13350. Shang-Fu Yuan, Jiao-Jiao Li, Zong-Jie Guan, Zhen Lei and Quan-Ming Wang*, Ultrastable Hydrido Gold Nanoclusters with the Protection of Phosphines, Chem. Commun., 2020, 56, 7037-7040. Zong-Jie Guan, Feng Hu, Jiao-Jiao Li, Zhao-Rui Wen, Yu-Mei Lin and Quan-Ming Wang*, Isomerization in Alkynyl-Protected Gold Nanoclusters, J. Am. Chem. Soc., 2020, 142, 2995 3001. Feng Hu, Jiao-Jiao Li, Zong-Jie Guan, Shang-Fu Yuan and Quan-Ming Wang*, Formation of an Alkynyl‐Protected Silver Nanocluster Ag112 Promoted by in situ Released Chlorides from CH2Cl2, Angew. Chem. Int. Ed., 2020, 59, 5312-5315. Xu-Shuang Han, Xinqi Luan, Hai-Feng Su, Jiao-Jiao Li, Shang-Fu Yuan, Zhen Lei, Yong Pei* and Quan-Ming Wang*, Structure Determination of Alkynyl-Protected Gold Nanocluster Au22(tBuC≡C)18 and the Thermochromic Luminescence, Angew. Chem. Int. Ed., 2020, 59, 2309-2312. Zhao-Rui Wen, Zong-Jie Guan, Ying Zhang, Yu-Mei Lin* and Quan-Ming Wang, [Au7Ag9(dppf)3(CF3CO2)7BF4]n: A Linear Nanocluster Polymer from Molecular Au7Ag8 Clusters Covalently Linking by Silver Atoms, Chem. Commun., 2019, 55, 12992-12995. Shang-Fu Yuan, Zong-Jie Guan, Wen-Di Liu and Quan-Ming Wang*, Solvent-triggered reversible interconversion of all-nitrogen-donor-protected silver nanoclusters and their responsive optical properties, Nat. Commun., 2019, 10, 4032. Zi-Ang Nan, Ying Xiao, Xi-Yan Liu, Tan Wang, Xiao-Ling Cheng, Yang Yang, Zhen Lei and Quan-Ming Wang*, Monitoring the growth of Ag–S clusters through crystallization of intermediate clusters, Chem. Commun., 2019, 55, 6771-6774. Shang-Fu Yuan,§ Cong-Qiao Xu,§ Jun Li* and Quan-Ming Wang*, Ligand-Protected “Golden Fullerene”: the Dipyridylamido [Au32]8+ Nanocluster, Angew. Chem. Int. Ed., 2019, 58, 5906-5909. Zong-Jie Guan, Feng Hu, Shang-Fu Yuan, Zi-Ang Nan, Yu-Mei Lin* and Quan-Ming Wang*, The stability enhancement factor beyond eight-electron shell closure in thiacalix[4]arene-protected silver clusters, Chem. Sci., 2019, 10, 3360-3365. Jia-Qi Wang, Zong-Jie Guan, Wen-Di Liu, Yang Yang* and Quan-Ming Wang*, Chiroptical Activity Enhancement via Structural Control: the Chiral Syn-thesis and Reversible Interconversion of Two Intrinsically Chiral Gold Nanoclusters, J. Am. Chem. Soc., 2019, 141, 2384-2390. Zhen Lei, Quan-Ming Wang*, Homo and heterometallic gold(I) clusters with hypercoordinated carbon, Coord. Chem. Rev., 2019, 378, 382-394. Jiao-Jiao Li, Zong-Jie Guan, Zhen Lei, Feng Hu and Quan-Ming Wang*, Same Magic Number but Different Arrangement: Alkynyl‐Protected Au25 with D3 Symmetry, Angew. Chem. Int. Ed., 2019, 58, 1083-1087. Zi-Ang Nan, Yu Wang*, Zhi-Xin Chen, Shang-Fu Yuan, Zhong-Qun Tian and Quan-Ming Wang*, Catalyzed assembly of hollow silver-sulfide cluster through self-releasable anion template, Communications Chemistry, 2018, 1, 99. Zhen Lei, Xian-Kai Wan, Shang-Fu Yuan, Zong-Jie Guan, and Quan-Ming Wang*, Alkynyl Approach toward the Protection of Metal Nanoclusters, Acc. Chem. Res., 2018, 51, 2465-2474. Yang Du, Zong-Jie Guan, Zhao-Rui Wen, Yu-Mei Lin* and Quan-Ming Wang*, Ligand-Controlled Doping Effects in Alloy Nanoclusters Au4Ag23 and Au5Ag24, Chem. Eur. J., 2018, 24, 16029–16035. Ting Wang, Wen-Han Zhang, Shang-Fu Yuan, Zong-Jie Guan and Quan-Ming Wang*, Alkynyl-Protected Au40 Nanocluster featuring PhC≡C–Au–P^P Motifs, Chem. Commun., 2018, 54, 10367-10370. Yang Yang*, Yi Wu, Jian-Hua Jia, Xiu-Ying Zheng, Qian Zhang, Ke-Cai Xiong, Ze-Min Zhang, and Quan-Ming Wang*, Enantiopure Magnetic Heterometallic Coordination Cubic Cages [MII8CuII6] (M = Ni, Co). Cryst. Growth Des., 2018, 18, 4555-4561. Jean-Francois Greisch*, Ana Ballester-Caudet, Sebastian Volker Kruppa, Zhen Lei, Quan-Ming Wang, Christoph Riehn, and Francoise Remacle, Gas-Phase Photoluminescence and Photodissociation of Silver-Capped Hexagold Clusters, J. Phys. Chem. A, 2018, 122, 5799-5810. Zhen Lei, Jiao-Jiao Li, Xian-Kai Wan, Wen-Han Zhang and Quan-Ming Wang*, Isolation and Total Structure Determination of an All-Alkynyl-Protected Gold Nanocluster Au144, Angew. Chem. Int. Ed., 2018, 57, 8639-8643. Zong-Jie Guan, Jiu-Lian Zeng, Shang-Fu Yuan, Feng Hu, Yu-Mei Lin*, and Quan-Ming Wang*, Au57Ag53(C≡CPh)40Br12: A Large Nanocluster with C1 Symmetry, Angew. Chem. Int. Ed., 2018, 57, 5703–5707.