个人简介

BS, Michigan Technological University PhD, Cornell University Postdoctoral Associate, MIT Glennan Fellow, Case 1996-97 American Chemical Society Fellow 2013 Fellow, Royal Society of Chemistry 2014

研究领域

Inorganic Chemistry/Materials & Energy/Organometallic Chemistry/Catalysis/Computational Chemistry/Crystallography/Electrochemistry/Green Chemistry/Main Group Chemistry/Molecular Electronics/Nanotechnology/OLEDs/Optoelectronics/Physical Organic Chemistry/Photochemistry/Polymers/Solar Energy/Solid-State Chemistry/Spectroscopy/Supramolecular Chemistry/Synthesis

We are interested in the construction of conjugated materials that incorporate multiply bonded low coordinate main group elements, in particular, phosphorus. Many fascinating and technologically important polymers having backbones comprised of C=C units in a conjugated fashion, and such materials are being intensely studied for electronic and optical properties in areas such as organic light emitting diodes (OLEDs) and organic Solar Photovoltaics (PVs). Using the well-known diagonal relationship between carbon and phosphorus, one of our goals is to prepare new materials having having P=C and P=P double bonds along the conjugation pathway.

近期论文

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Gudimetla, V. B.; Ma, L.; Washington, M. P.; Payton, J. L.; Simpson, M. C.; Protasiewicz, J. D. "meta-Terphenyl phosphaalkenes bearing electron donating and accepting groups" Europ. J. Inorg. Chem. 2010, 854-865. Meprathu, B. V.; Protasiewicz, J. D. "Enhancing the solubility for hypervalent ortho-sulfonyl iodine compounds" Tetetrahon, 2010, 66, 5768-5774 (special issue on Hypervalent Iodine). Protasiewicz, J. D.; Washington, M. P.; Gudimetla, V. B., Payton, J. L.; Simpson, M. C. "A closer look at the phosphorus-phosphorus double bond lengths in meta-terphenyl substituted diphosphenes" Inorg. Chem. Acta, 2010, 364, 39-45 (special issue dedicated to Prof. Arnold Rheingold). Justik, M. W.; Kristufek, S. L.; Protasiewicz, J. D.; Deligonul, N. "Stereoselective Synthesis and X-ray Structures of Alkenyiodonium salts with a Pyridine N-oxide Moiety" Synthesis, 2010, 2345-2347. Washington, M. P.; Gudimetla, V. B.; Laughlin, F. L.; Deligonul, N.; He, S.; Payton, J. L.; Simpson, M. C.; Protasiewicz, J. D., "Phosphorus Can Also Be A "Photocopy"". J. Am. Chem. Soc. 2010, 132, 4566-4567. Shaffer, A. R.; Deligonul, N.; Scherson, D. A.; Protasiewicz, J. D., "A Hybrid Lithium Oxalate-Phosphinate Salt" Inorg. Chem. 2010, 49, 10756-10758. Yang, Y.; Samas, B.; Kennedy, V. O.; Macikenas, D.; Chaloux, B. L.; Miller, J. A.; Speer, R. L.; Protasiewicz, J.; Pinkerton, A. A.; Kenney, M. E., Long, Directional Interactions in Cofacial Silicon Phthalocyanine Oligomers. J. Phys. Chem. A 2011, 115, 12474-12485. Duraj, S. A.; Hepp, A. F.; Woloszynek, R.; Protasiewicz, J. D.; Dequeant, M.; Ren, T., Synthesis of two new group 13 benzoato-chloro complexes: A structural study of gallium and indium chelating carboxylates. Inorg. Chim. Acta 2011, 365 (1), 54-60. Washington, M. P.; Payton, John L.; Simpson, M. C.; Protasiewicz, J. D. "Redox Behavior of Benzoxaphospholes and Bezo[1,2-d:4,5-d']bisoxaphospholes" Organometallics, 2011, 30, 1975-1983. Laughlin, F. L.; Rheingold, A. L.; Deligonul, N.; Laughlin, B. J.; Smith, R. C.; Higham, L. J.; Protasiewicz, J. D. Dalton Trans. 2012, 41, 12016-12022. Peng, H.-L.; Payton, John L.; Simpson, M. C.; Protasiewicz, J. D. "P=P bond photophysics in a ArP=PAr diphosphene" Dalton Trans. 2012, 41, 13204-13209. Protasiewicz, J. D. "Coordination-Like Chemistry of Phosphinidenes by Phosphanes" Eur. J. Inorg. Chem., 2012, 4539-4549. Ay, B.; Yildiz, E.; Protasiewicz, J. D.; Rheingold, A. L. "Hydrothermal synthesis, crystal structure and heterogeneous catalytic activity of a novel inorganic-organic hybrid complex, possessing infinite La-O-La linkages" Inorg. Chim. Acta 2013, 399, 208-213. Simpson, M. C.; Protasiewicz, J. D. "Phosphorus as a Carbon Copy and as a Photocopy: New Conjugated Materials Featuring Multiply Bonded Phosphorus" Pure Appl. Chem., 2013, 85, 801-815. Laughlin, B. J.; Duniho, T. L.; Homsi, S. J. E.; Levy, B. E.; Deligonul, N.; Gaffen, J. R.; Protasiewicz, J. D.; Tennyson, A. G.; Smith, R. C. "Comparison of 1,4-distyrylfluorene and 1,4-distyrylbenzene analogues: synthesis, structure, electrochemistry and photophysics" Org. Biomol. Chem., 2013, 11, 5425-5434. Laughlin, F. L.; Deligonal, N.; Rheingold, A. L.; Golen, J. A.; Protasiewicz, J. D. "Fluorescent Heteroacenes with Multiply-Bonded Phosphorus" Organometallics 2013, manuscript in preparation. Rectenwald, M. F.; Hildebrant, D. K.; Deligonal, N.; Protasiewicz, J. D. "Synthesis and Characterization of Phosphrus Containing Self-Doped Polyanline and its Sodium Salts" J. Electrochem. Soc. 2013, manuscript in preparation. Protasiewicz, J. D. "Nitrogen, phosphorus, arsenic, antimony, and bismuth" Annu. Rep. Prog. Chem., Sect, A: Inorg. Chem., 2013, ASAP. Protasiewicz, J. D. Chapter 1.14. New Developments in Multiple Bonded Compounds - Group 15, contributed chapter to Comprehensive Inorganic Chemistry, 2013, in press