个人简介

PhD 2002, Harvard University, Cambridge, Massachusetts (R. H. Holm, advisor)

研究领域

Organometallic Chemistry/Inorganic Chemistry/Energy

A major focal point of research in the Gray Lab is the design of novel and useful complexes of gold. Below are presented a few excerpts from our research which highlight the utility of gold in areas including photophysics, catalysis, and general synthetic interest.

近期论文

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Maity, A.; Stanek, R.J.; Anderson, B.L.; Zeller, M.; Hunter, A.D.; Moore, C.E.; Rheingold, A.L.; Gray, T.G. "Fluoride Complexes of Cyclometalated Iridium(III)" Organometallics 2015, 34, 109-120. (DOI: 10.1021/om5009555) Maity, A.; Sulicz, A.N.; Deligonul, N.; Zeller, M.; Hunter, A.D.; Gray, T.G. "Suzuki–Miyaura coupling of arylboronic acids to gold(III)" Chemical Science 2015, 6, 981-986. (DOI: 10.1039/C4SC02148G) Browne, A.B.; Deligonul, N.; Anderson, B.L.; Rheingold, A.L.; Gray, T.G. "Geminally Diaurated Aryls Bridged by Semirigid Phosphine Pillars: Syntheses and Electronic Structure" Chemistry - A European Journal 2015, 20, 17552-17564. (DOI: 10.1002/chem.201403444) Deligonul, N.; Browne, A.B.; Golen, J.A.; Rheingold, A.L.; Gray, T.G. "Cyclometalated Iridium(III) Complexes of Azadipyrromethene Chromophores" Organometallics 2014, 33, 637-643. (DOI: 10.1021/om4007032) Deligonul, N.; Gray, T.G. "Azadipyrromethene Complexes of d8 Metal Centers: Rhodium(I), Iridium(I), Palladium(II), and Platinum(II)" Inorganic Chemistry 2013, 52, 13048-13057. (DOI: 10.1021/ic4017239) Wyss, C.M.; Tate, B.K.; Basca, J.; Gray, T.G.; Sadighi, J.P. "Bonding and Reactivity of a μ-Hydrido Dicopper Cation" Angew. Chem. Int. Ed. 2013, 52, 12920–12923. (DOI: 10.1002/anie.201306736) Maity, A.; Choi, J.-S.; Teets, T.S.; Deligonul, N.; Berdis, A.J.; Gray, T.G. "Cyclometalated Iridium(III) Complexes with Deoxyribose Substituents" Chemistry -- A European Journal 2013, 19, 15924-15932. (DOI: 10.1002/chem.201301776) Robilotto, T.J.; Deligonul, N.; Updegraff, J.B., III; Gray, T.G. "Azido, Triazolyl, and Alkynyl Complexes of Gold(I): Syntheses, Structures, and Ligand Effects" Inorganic Chemistry 2013, 52, 9659-9668. (DOI: 10.1021/ic4014569) Heckler, J.E.; Deligonul, N.; Rheingold, A.L.; Gray, T.G. "Gold(I) triazolyls: organometallic synthesis in air and aqueous media" Chemical Communications 2013, 49, 5990-5992. (DOI: 10.1039/C3CC43016B) Maity, A.; Anderson, B. L.; Deligonul, N; Gray, T. G. "Room-temperature synthesis of cyclometalated iridium(III) complexes: kinetic isomers and reactive functionalities" Chemical Science 2013, 4, 1175-1181. (DOI: 10.1039/C2SC21831C)