Stephan, Douglas W. - University of Toronto

个人简介

2016 Einstein Visiting Fellow, TU Berlin 2015 Distinguished Adjunct Professor, King Abdulaziz University Thomson Reuters Highly Cited Researcher World's Most Influential Scientific Minds (1 of 5 Canadian Chemists) 2014 Applied Catalysis Award (Royal Society of Chemistry, UK) Corresponding Member of North-Rhein-Westfaelia Academy of the Sciences and Arts (Germany) Canadian Green Chemistry and Engineering Award CIC Medal(Chemical Institute of Canada) Laird Lecture, University of British Columbia Thomson Reuters Highly Cited Researcher Canada Research Chair in Catalysis and New Materials (Univery of Toronto; 2014-2020)Dow Lecture on Sustainable Chemistry, Colorado State University Member, Editorial Board of Philosophical Transactions A (Royal Society) 2013 Fellow of the Royal Society (London, UK) Henry Marshall Tory Medal (Royal Society of Canada) Honorary Member of the Israeli Chemical Society Resaearch highlighted in Silverberg, Chemistry, 1st Canadian Ed.Moses Gomberg Lecture, University of Michigan 2012 Member of the Editorial Board of Dalton Transactions Chair, Int. Symp. for Adv. Chem. Sci. (ISACS 8, Toronto) Guest Editor, Dalton Trans. - issue on FLPs. Humboldt Foundation Research Award, Re-invitation (Forschungpreis)Ludwig Mond Award (Royal Society for Chemistry (UK)) 2011 Kohler lecture, University of California Riverside Associate Editor, Chemical Society Reviews 2010 Fellow of the Royal Society of Chemistry (UK)Guest Editor, Chem. Commun. - web issue on Hydrogen Activation Member of the Editorial Board of Chem. Soc. Rev. 2009 Killam Research Fellowship 2008 Canada Research Chair in Catalysis and New Materials (University of Toronto)2007 Paper among 20 most highly cited papers in Organometallics in the last 10 years (top 1%) 2006 Publication named to Top 50 NSERC Discoveries 2005 Canada Research Chair (University of Windsor) Fellow of the Royal Society of Canada LeSueur Memorial Award (Soc. Chem. Ind.) 2004 Ciapetta Lectureship Award (N. Am. Cat. Soc.) 2003 NSERC Synergy Award (with NOVA Chemicals) University of Windsor Senior Award for Research 2002 Humboldt Foundation Research Award University of Windsor, University Professor 2001 NSERC/NOVA Chemicals Ind. Research Chair (through 2006) Alcan Award (Canadian Society for Chemistry) 1995 DAAD Visiting Scientist, Germany (declined) NSERC/DFG Visiting Scientist, Muenster 1994 Fellow of the Chemical Institute of

研究领域

Our research interests span a wide range of inorganic main group and organometallic chemistry. In the more fundamental projects, new reactivity and chemical transformations are targeted with a view to developing new catalysts to either new materials or new processes. In addition, collaborations with industry address the design and development of new catalyst and process technologies for use in commercial applications. These activities are supported by NSERC and industrial collaborators. Current fundamental projects are focused in the areas: · The reactivity of "frustrated Lewis pairs" · B-based hydrogenation catalysis · Main group CO2 chemistry · P-based Lewis acids · Transition metal mediated CO2 reduction · New ligands derived from FLP chemistry Current industrial/applied research projects are directed towards: · High temperature olefin polymerization catalysis · New approaches to olefin hydrogenation catalysts · New olefin metathesis catalysts Current Research support is derived from: · Canada Foundation for Innovation · Research and Innovation (ON) · Canada Research Chair · Digital Specialty Chemicals · LANXESS · NSERC-CRD (LANXESS) · NSERC-CRD (Digital) · NSERC Discovery Grant · NSERC Engage · NSERC Strategic · OCE (Digital) · University of Toronto · Qatar

近期论文

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A. Hermannsdorfer, D.W. Stephan, M. Driess, Taming a Silyldiium Cation and its Reactivity Towards Sodium Phosphaethynolate, Chem. Commun., DOI:10.1039/C8CC07632D. T.C. Johnstone, A.I. Briceno-Strocchia, D.W. Stephan, Frustrated Lewis Pair Oxidation Permits Synthesis of a Fluoroazaphosphatrane, [FP(MeNCH2CH2)3N]+, Inorg. Chem., accepted. J. Lam, K. Szkop, E. Mosaferi, D.W. Stephan, FLP Catalysis: Main Group Hydrogenations of Organic Unsaturated Substrates, Chem. Soc. Rev., DOI:10.1039/C8CS00277K. A.R. Jupp, T.C. Johnstone, D.W. Stephan, Improving the Global Electrophilicity Index (GEI) as a Measure for Lewis Acidity, Inorg. Chem., accepted. S.S. Chitnis, J. LaFortune, H. Cummings, L. Liu, R. Andrews, D.W. Stephan, Phosphorus Coordination Chemistry in Catalysis: Air-Stable P(III)-Dications as Lewis Acid Catalysts for the Allylation of C-F Bonds, Organometallics, DOI:10.1021/acs.organomet.8b00686, invited cover. J.M. Bayne, V. Fasano, K.M. Szkop, M.J. Ingelson, D.W. Stephan, Phosphorus(V) Lewis Acids: Water-Base Tolerant P3-trimethylated Trications, Chem. Comm., 54, 12467-12470, DOI:10.1039/C8CC06564K. K.M. Szkop, A.R. Jupp, D.W. Stephan, P,P-Dimethylformylphosphine: The Phosphorus Analogue of DMF, J. Am. Chem. Soc., DOI:10.1021/jacs.8b09266. A.J. Stepen, M. Bursch, S. Grimme, D.W. Stephan, J. Paradies, Electrophilic Phosphonium Cation-Mediated Phosphane Oxide Reduction Using Oxalyl Chloride and Hydrogen, Angew. Chem. Int. Ed., DOI:10.1002/anie.201809275. K.L. Bamford, S.S. Chitnis, Z-W. Qu, D.W. Stephan, Interactions of C-F Bonds with Hydridoboranes: Reduction, Borylation and Friedel-Crafts Alkylation, Chem. Eur. J., 24, 16014-16018, DOI:10.1002/chem.20184705. M. Volger, L. Süsse, J.H.W. LaFortune, D.W. Stephan, M. Oestreich, Electrophilic Phosphonium Cations as Lews-Acid Catalysts in Diels-Alder Reactions and Nazarov Cyclizations, Organometalics, accepted. J. Zhou, L.L. Liu, L.L. Cao, D.W. Stephan, The ŋ5-Pentamethylcyclopentadienyl Phosphorus Dications: [(ŋ5-Cp*)P]2+: A Phosphorus Super Acid, CHEM., 4, 2699-2708, DOI:10.1016/j.chempr.2018.08.038, Highlighted in Chemistry World: https://www.chemistryworld.com/news/rare-phosphorus-dication-synthesised/3009617.article . C. Schneider, J.H.W. LaFortune, R.L. Melen, D.W. Stephan, Lewis Brønsted Basicity of Phosphine-Diazomethane Derivatives, Dalton Trans., 47, 12742-12749, DOI:10.1039/C8DT02420K. J.H.W. LaFortune, K.M. Szkop, F.E. Farinha, T.C. Johnstone, S. Postle, D.W. Stephan, Probing Steric Influences on Electrophilic Phosphonium Cations: A Comparison of [3,5-((Cf3)2C6H3)3PF]+ and [(C6F5)3PF]+, Dalton Trans., 47, 11411-11419, DOI:10.1039/C8DT02594K. L.L. Cao, D.W. Stephan, Reversible 1,1-Hydridoaluminations and C-H Activation in Reactions of a Cyclic Alkyl Amino Carbene with Alane, Chem. Comm., 54, 8407-8410, DOI:10.1039/C8CC05013A. M. Xu, A.R. Jupp, Z-W. Qu, S. Grimme, D.W. Stephan, Alkali-Metal Species in the Reversible Activation of H2, Angew. Chem. Int. Ed., DOI:10.1002/anie.201806849. L. Fan, A.R. Jupp, D.W. Stephan, Remote Stereochemistry of a Frustrated Lewis Pair Provides Thermal and Photochemical Control of Reactivity, J. Am. Chem. Soc., 140, 8119-8123, DOI:10.1021/jacs.8b05176. L.L. Liu, L.L. Cao, J. Zhou, D.W. Stephan, A Room-Temperature-Stable Phosphanorcaradiene, J. Am. Chem. Soc., Accepted, DOI:10.1021/jacs.8b04930. K.M. Szkop, D. Zhu, L.E. Longobardi, J. Heck, D.W. Stephan, Interception of Intermediates in Phosphine Oxidation by Frustrated Lewis Pairs, Dalton Trans., 47, 8933-8939, DOI:10.1039/C8DT01717D. A. Waked, R.O. Memar, D.W. Stephan, Nitrogen-Based Lewis Acids Derived from Phosphonium Diazo Cations, Angew. Chem. Int. Ed., 57, 11934-11938, DOI:10.1002/anie.201804183. L.L. Liu, L.L. Cao, J. Zhou, D.W. Stephan, Homolytic Cleavage of Peroxide Bond via a Single Electron Transfer of Frustrated Lewis Pair, Chem. Commun., 54, 7431-7434, DOI:10.1039/C8CC03522A.