研究领域
My main area of research centres on the structure and reactivity of organometallic alkali metal reagents as well as their interaction with organomagnesium compounds. The chemistry which can be achieved by combining the two types of metal reagents is often uprecedented and can be utilised in organic synthesis to prepare otherwise unobtainable compounds, an important aspect for the pharmaceutical and agrochemical industries.
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Monodentate coordination of the normally chelating chiral diamine (R,R)-TMCDAOjeda-Amador Ana I., Martínez-Martínez Antonio J., Kennedy Alan R., Armstrong David R., O'Hara Charles T.Chemical Communications Vol 53, pp. 324-327, (2017)http://dx.doi.org/10.1039/C6CC07190B
Alkali metal magnesiates : reagents for regioselective double metalationsO'Hara CharlesGordon Research Conference: Organometallic Chemistry. Newport, Rhode Island USA, (2016)
Structural studies of cesium, lithium/cesium and sodium/cesium bis(trimethylsilyl)amide (HMDS) complexesOjeda Amador Ana I., Martínez-Martínez Antonio J., Kennedy Alan R., O'Hara Charles T.Inorganic Chemistry Vol 55, pp. 5719–5728, (2016)http://dx.doi.org/10.1021/acs.inorgchem.6b00839
Synthetic and reactivity studies of hetero-tri-anionic sodium zincatesFrancos Javier, Kennedy Alan R., O'Hara Charles T.Dalton Transactions Vol 45, pp. 6222-6233, (2016)http://dx.doi.org/10.1039/C5DT04329H
Lithium, sodium, and potassium magnesiate chemistry : a structural overviewMartínez-Martínez A. J., O'Hara C. T.Advances in Organometallic Chemistry, (2016)http://dx.doi.org/10.1016/bs.adomc.2016.02.001
Alkali-metal-mediated magnesiations of an N-heterocyclic carbene : normal, abnormal and "paranormal" reactivity in a single tritopic moleculeMartínez-Martínez Antonio J., Fuentes M. ángeles, Hernán-G?mez Alberto, Hevia Eva, Kennedy Alan R., Mulvey Robert E., O'Hara Charles T.Angewandte Chemie Vol 54, pp. 14075-14079, (2015)http://dx.doi.org/10.1002/anie.201507586