研究领域

Organic chemistry

Use of diazo compounds and azomethine imines in asymmetric synthesis Design and development of novel organocatalysts

近期论文

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"Enantioselective Formal Alkenylations of Imines Catalyzed by Axially Chiral Dicarboxylic Acid Using Vinylogous Aza-Enamines" T. Hashimoto, H. Kimura, K. Maruoka, Angew. Chem. Int. Ed. 2010, 49, 6844-6847 . "Catalytic Enantioselective 1,3-Dipolar Cycloaddition of C,N-Cyclic Azomethine Imines with α,β-Unsaturated Aldehydes" T. Hashimoto, Y. Maeda, M. Omote, H. Nakatsu, K. Maruoka, J. Am. Chem. Soc. 2010, 132, 4076-4077. "α-Chiral Acetylenes Having an All-Carbon Quaternary Center: Phase Transfer Catalyzed Enantioselective α Alkylation of α-Alkyl-α-alkynyl Esters" T. Hashimoto, K. Sakata, K. Maruoka, Angew. Chem. Int. Ed. 2009, 48, 5014-5017 . "Stereoselective Synthesis of α-Alkyl-β-keto Imides via Asymmetric Redox C-C Bond Formation between α-Alkyl-α-diazocarbonyl Compounds and Aldehydes" T. Hashimoto, H. Miyamoto, Y. Naganawa, K. Maruoka, J. Am. Chem. Soc. 2009, 131, 11280-11281 . "Stereoselective Construction of Seven-Membered Rings with an All-Carbon Quaternary Center by Direct Tiffeneau-Demjanov-type Ring Expansion" T. Hashimoto, Y. Naganawa, K. Maruoka, J. Am. Chem. Soc. 2009, 131, 6614-6617. "Trans-Selective Asymmetric Aziridination of Diazoacetamides and N-Boc Imines Catalyzed by Axially Chiral Dicarboxylic Acid" T. Hashimoto, N. Uchiyama, K. Maruoka, J. Am. Chem. Soc. 2008, 130, 14380-14381. "Asymmetric Imino Aza-enamine Reaction Catalyzed by Axially Chiral Dicarboxylic Acid: Use of Arylaldehyde N,N-Dialkylhydrazones as Acyl Anion Equivalent" T. Hashimoto, M. Hirose, K.Maruoka, J. Am. Chem. Soc. 2008, 130, 7556-7557 . "Brønsted Acid-Catalyzed Insertion of Aryldiazoacetates to sp2 Carbon-CHO Bond: Facile Construction of Chiral All-Carbon Quaternary Center" T. Hashimoto, Y. Naganawa, K. Maruoka, J. Am. Chem. Soc. 2008, 130, 2434-2435 . "Design of Axially Chiral Dicarboxylic Acid for Asymmetric Mannich Reaction of Arylaldehyde N-Boc Imines and Diazo Compounds" T. Hashimoto, K. Maruoka, J. Am. Chem. Soc. 2007, 129, 10054-10055.