Li, Xiaopeng - University of South Florida

个人简介

Education Ph.D., Chemistry, Cleveland State University, 2008 B.S., Chemistry, Zhengzhou University, China, 2004 Research Experience 2019 - present Associate professor, University of South Florida 2016 - 2019 Assistant professor, University of South Florida 2012 - 2016 Assistant professor, Texas State University 2009 - 2012 Postdoctoral fellow, University of Akron Awards & Honors 2019 Cram Lehn Pedersen Prize in Supramolecular Chemistry 2019 University of South Florida Faculty Outstanding Research Achievement Award 2017 Fellow of the Royal Society of Chemistry (FRSC) 2017 CAPA Distinguished Junior Faculty Award 2016 Texas State University Presidential Distinction Award for Excellence in Scholarly/Creative Activities 2015 Cottrell College Single Investigator Award, Research Corporation for Science Advancement

研究领域

Our research is focused on metal-mediated supramolecular chemistry to construct a series of 2D and 3D architectures with precise shapes and sizes. Our specific research interests include: Design, synthesis and self-assembly of giant supramolecules using multitopic ligands, which provide more geometric constraints to prevent the formation of multiple entities and to reach the most thermodynamically stable architectures. Incorporating a wide variety of functional groups into the supramolecular core structures through either pre- or post-assembly modification. Characterization of supramolecules using mass spectrometry, e.g., Matrix-Assisted Laser Desorption/Ionization (MALDI), Electrospray Ionization (ESI), and Ion Mobility-Mass Spectrometry (IM-MS). Exploring the applications of these assemblies in diverse fields, such as host-guest chemistry, molecular recognition, reactivity modulation, catalysis, template-directed synthesis and biology. Ultimately, fundamental advances in synthesis, self-assembly, and characterization of metallo-supramolecules will allow predictable incorporation of desired properties and functionality into supramolecular architectures with molecular level precision.

近期论文

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Heng Wang, Chung-Hao Liu, Kun Wang, Minghui Wang, Hao Yu, Sneha Kandapal, Robert Brzozowski, Bingqian Xu, Ming Wang, Shuai Lu, Xin-Qi Hao, Prahathees Eswara, Mu-Ping Nieh*, Jianfeng Cai*, and Xiaopeng Li*. Assembling pentatopic terpyridine ligand into giant supramolecular hexagonal prism with three types of coordination moieties: Synthesis, self-assembly, characterization, and antimicrobial study. J. Am. Chem. Soc., 2019, DOI: 10.1021/jacs.9b08484 Gui-Fei Huo, Xueliang Shi,* , Qian Tu, Yi-Xiong Hu, Gui-Yuan Wu, Guang-Qiang Yin, Xiaopeng Li, Lin Xu, Hong-Ming Ding,* Hai-Bo Yang*. Radical-induced hierarchical self-assembly involving supramolecular coordination complexes in both solution and solid states. J. Am. Chem. Soc., 2019, DOI: 10.1021/jacs.9b08149 Koushik Acharyya*, Soumalya Bhattacharyya, Hajar Sepehrpour, Shubhadip Chakraborty, Shuai Lu, Bingbing Shi, Xiaopeng Li, Partha Sarathi Mukherjee*, Peter J. Stang*. Self-assembled fluorescent Pt(II) metallacycles as artificial light-harvesting systems. J. Am. Chem. Soc., 2019, DOI: 10.1021/jacs.9b08403 Yukun Zhang, Yulong Zhong, Alan L. Connor, Daniel P. Miller, Ruikai Cao, Jie Shen, Bo Song, Erin S. Baker, Quan Tang, Surya V. S. R. K. Pulavarti, Rui Liu, Qiwei Wang, Zhong-lin Lu, Thomas Szyperski, Huaqiang Zeng, Xiaopeng Li, Richard D. Smith, Eva Zurek, Jin Zhu* and Bing Gong*. Folding and assembly of short α, β, γ-hybrid peptides: minor variations in sequence and drastic differences in higher-level structures. J. Am. Chem. Soc., 2019, DOI:10.1021/jacs.9b06094 Yue Sun, Feng Ding, Zhao Chen, Ruiping Zhang, Chonglu Li, Yuling Xu, Yi Zhang, Ruidong Ni, Xiaopeng Li, Guangfu Yang, Yao Sun, and Peter J. Stang*. Melanin-dot–mediated delivery of metallacycle for NIR-II/photoacoustic dual-modal imaging-guided chemo-photothermal synergistic therapy .Proc. Natl. Acad. Sci. U.S.A, 2019, 116, 16729-16735 Yi Qin, Li-Jun Chen*, Ying Zhang, Yi-Xiong Hu, Wei-Ling Jiang, Guang-Qiang Yin, Hongwei Tan, Xiaopeng Li, Lin Xu * and Hai-Bo Yang*. Photoswitchable Fo¨rster resonance energy transfer (FRET) within a heterometallic Ir–Pt macrocycle. Chem. Commun., 2019, 55 , 11119 Yu Yan, Guang-Qiang Yin, Sandra Khalife, Zhan-Hang He*, Chen Xu and Xiaopeng Li*. Self-assembly of emissive metallocycles with tetraphenylethylene, BODIPY and terpyridine in one system.Supramol. Chem., 2019, DOI: 10.1080/10610278.2019.1659266 (Invited contribution) Alexander Filosa, Heng Wang, Wei‐Jian Li, Wenjing Zhang, Ellie Ngo, Jonathan E. Piccolo, Hai‐Bo Yang, Xiaopeng Li*. Order from chaos: self‐assembly of nanoprism from a mixture of tetratopic terpyridine‐porphyrin conformers.Chin. J. Chem., 2019, DOI: 10.1002/cjoc.201900177 (Invited contribution) Yu Shao, Jia Che, Xiang-Kui Ren, Xinlin Zhang, Guang-Zhong Yin, Xiaopeng Li, Jing Wang, Chrys Wesdemiotis, Wen-Bin Zhang, Shuguang Yang*, Bin Sun*, and Meifang Zhu*. Synthesis, self-assembly and characterization of tandem triblock BPOSS-PDI-X shape amphiphiles.Molecules, 2019, 24, 2114 Zecong Ye, Zhiyao Yang, Lei Wang, Lixi Chen, Yimin Cai, Pengchi Deng, Wen Feng, Xiaopeng Li, and Lihua Yuan*. A dynamic hydrogen-bonded azo-macrocycle for precisely photo-controlled molecular encapsulation and release . Angew. Chem. Int. Ed., 2019, 58, 12519 Heng Wang, Yiming Li, Hao Yu, Bo Song, Shuai Lu, Xin-Qi Hao, Yuan Zhang, Ming Wang, Saw-Wai Hla and Xiaopeng Li*. Combining synthesis and self-assembly in one pot to construct complex 2D metallo-supramolecules using terpyridine and pyrylium salts. J. Am. Chem. Soc., 2019, 141, 13187 Yan Shi, Guangqiang Yin, Zhiping Yan, Peng Sang, Minghui Wang, Robert Brzozowski, Prahathees Eswara, Lukasz Wojtas, You-Xuan Zheng*, Xiaopeng Li*, Jianfeng Cai*. Helical sulfono-γ-AApeptides with aggregation-induced emission and circularly polarized luminescence. J. Am. Chem. Soc., 2019, 141, 12697 Xuzhou Yan, *Peifa Wei, Yuhang Liu, Ming Wang, Chuanshuang Chen, Jun Zhao, Guangfeng Li, Manik Lal Saha, Zhixuan Zhou, Zhe An*, Xiaopeng Li and Peter J. Stang*. Endo- and exo-functionalized tetraphenylethylene M12L24 nanospheres: fluorescence emission inside a confined space. J. Am. Chem. Soc. , 2019, 141, 9673-9679 Yi Qin, Li-Jun Chen*, Fangyuan Dong, Shu-Ting Jiang, Guang-Qiang Yin, Xiaopeng Li, Yang Tian*, Hai-Bo Yang*. Light-controlled generation of singlet oxygen within a discrete dual-stage metallacycle for cancer therapy. J. Am. Chem. Soc., 2019, 141, 8943-8950 Zhixuan Zhou, Deng-Gao Chen, Manik Lal Saha, Heng Wang, Xiaopeng Li, Pi-Tai Chou*, Peter J. Stang*. Designed conformation and fluorescence properties of self-assembled phenazine-cored platinum(ii) metallacycles. J. Am. Chem. Soc., 2019, 141, 5535−5543 Zheng Niu, Lei Wang, Sheng Fang, Pui Ching Lan, Briana Aguila, Jason Perman, Jian-Gong Ma*, Peng Cheng, Xiaopeng Li and Shengqian Ma*. Solvent-assisted coordination driven assembly of a supramolecular architecture featuring two types of connectivity from discrete nanocages. Chem. Sci., 2019, 10, 6661-6665 Xiaoxia Fan, Dan Zhang, Shiyu Jiang, Heng Wang, Lin-Ting Lin, Bo Zheng, Wen-Hua Xu, Yanxia Zhao, Benjamin P. Hay, Yi-Tsu Chan, Xiao-Juan Yang*, Xiaopeng Li and Biao Wu *. Construction and interconversion of anion-coordination-based (‘aniono’) grids and double helicates modulated by counter-cations. Chem. Sci., 2019, 10, 6278-6284 Mingzhao Chen, Die Liu*, Jian Huang, Yiming Li,, Ming Wang, Kaixiu Li, Jun Wang, Zhilong Jiang, Xiaopeng Li and Pingshan Wang*. Trefoiled propeller-shaped spiral terpyridyl metal–organic architectures Inorg. Chem., 2019, 58, 11146 Wenbo Wang, Zhixuan Zhou, Jiong Zhou, Bingbing Shi, Bo Song, Xiaopeng Li, Feihe Huang* and Peter J. Stang*. Self-assembled amphiphilic janus double metallacycle. Inorg. Chem., 2019, 58, 7141-7145 Zeyuan Zhang, Zhengqing Zhao, Yali Hou, Heng Wang, Xiaopeng Li, Gang He and Mingming Zhang*. Aqueous platinum(ii) cage‐based light‐harvesting system for photocatalytic cross‐coupling hydrogen evolution reaction. Angew. Chem. Int. Ed., 2019, 58 ,862–8866