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个人简介

教育经历 1999.09-2004.01 浙江大学化学系,有机化学专业,理学博士; 1992.09-1996.06 浙江大学化学系,化学专业,理学学士; 工作经历 2021.09—至今,河南师范大学,学术副校长; 2018.08—至今,河南师范大学化学化工学院教授,博士生导师,院长; 2009.08—2018.08,河南大学河南省天然药物与免疫工程重点实验室教授,博士生导师,副主任; 2013.04—2013.10,新加坡南洋理工大学化学与生物化学学院,高级研究员; 2005.08—2009.08,新加坡国立大学化学系,博士后,合作导师:Choon-Hong Tan教授; 2004.02—2005.04,香港浸会大学化学系,博士后,合作导师:Wing-Hong Chan教授

研究领域

1. 可见光不对称有机催化 2. 不对称自由基化学 3. 手性杂环化学

近期论文

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Guo, Y.-Y.*, Tian, Z.-H., Zhang, L., Han, Y.-C., Zhang, B.-B., Xing, Q., Shao, T., Liu, Y., Jiang, Z.*. J. Am. Chem. Soc. 2024, DOI: 10.1021/jacs.4c10441. http://pubs.acs.org/doi/epdf/10.1021/jacs.4c10441 Li, F., Liu, F.-Y., Zhao, X*, Yin, Y., Yu, B., Zhang, J.*, Jiang, Z.* Unified Enantioselective Allylations and Vinylogous Reactions Enabled by Visible Light-Driven Chiral Lewis Acid Catalysis. ACS Catal. 2024, 14, 16479−16487. DOI: 10.1021/acscatal.4c04638. https://pubs.acs.org/doi/10.1021/acscatal.4c04638 Jiang, C., Yin, Y.*, Jiang, Z.* Advances in Photoenzyme-Catalyzed Asymmetric Radical Addition Reactions. Chin. J. Org. Chem. 2024, DOI: 10.6023/cjoc202408004. https://sioc-journal.cn/Jwk_yjhx/CN/10.6023/cjoc202408004 Wang, J., Fu, Q., Cao, S., Lv, X., Yin, Y., Ban, X., Zhao, X., Jiang, Z.* Enantioselective [2 + 2] Photocycloreversion Enables De Novo Deracemization Synthesis of Cyclobutanes. J. Am. Chem. Soc. 2024, 146, 22840−22849. DOI: 10.1021/jacs.4c08290. https://pubs.acs.org/doi/10.1021/jacs.4c08290 Liu, Y., Chu, M., Li, X., Cao, Z., Zhao, X., Yin, Y.*, Jiang, Z.* Photoredox Catalytic Deracemization Enabled Enantioselective and Modular Access to Axially Chiral N-Arylquinazolinones. Angew. Chem. Int. Ed. 2024, DOI: 10.1002/anie.202411236. https://onlinelibrary.wiley.com/doi/10.1002/anie.202411236 Tian, D., Shi, W., Sun, X., Zhao, X., Yin, Y., Jiang, Z.*, Catalytic asymmetric [4+2] dearomative photocycloadditions of anthracene and its derivatives with alkenylazaarenes. Nat. Commun. 2024, 15 (1), 4563. https://doi.org/10.1038/s41467-024-48982-y Sun, X., Liu, Y., Yin, Y., Ban, X., Zhao, X., Jiang, Z.*, Asymmetric Photoredox Catalytic Formal De Mayo Reaction Enabled by Sensitization-Initiated Electron transfer. Nat. Chem. 2024, 16, 1169-1176. https://www.nature.com/articles/s41557-024-01502-3 Kong, M., Wang, Z., Ban, X., Zhao, X., Yin, Y., Zhang, J., Jiang, Z.*, Radical Cross Coupling and Enantioselective Protonation through Asymmetric Photoredox Catalysis. Adv. Sci. 2024, 11 (12), 2307773. https://doi.org/10.1002/advs.202307773 Fu, Q., Cao, S., Wang, J.*, Lv, X.*, Wang, H., Zhao, X., Jiang, Z.*, Enantioselective [2π + 2σ] Cycloadditions of Bicyclo[1.1.0]butanes with Vinylazaarenes through Asymmetric Photoredox Catalysis. J. Am. Chem. Soc. 2024, 146 (12), 8372-8380. https://doi.org/10.1021/jacs.3c14077 Wei, W., Li, C., Fan, Y., Chen, X., Zhao, X., Qiao, B.*, Jiang, Z.*, Catalytic Asymmetric Redox-Neutral [3 + 2] Photocycloadditions of Cyclopropyl Ketones with Vinylazaarenes Enabled by Consecutive Photoinduced Electron Transfer. Angew. Chem. Int. Ed. 2024, e202406845. https://doi.org/10.1002/anie.202406845 Zhang, L., You, M., Ban, X., Zhao, X., Yin, Y., Cao, S.*, Jiang, Z.*, Visible Light-Driven Dearomative Ring Expansion of (Aza)arenes to Access Dihydrofuran-based Polycyclic Compounds. Chem. Sci. 2024, 15, 8828-8834. https://doi.org/10.1039/D4SC00748D Ban, X.*, Jiang, Z.*, Asymmetric Photochemical Transformations Using a Chiral Hydrogen Bond Donor. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. 2024, DOI:org/10.1016/B978-0-32-390644-9.00135-9 https://doi.org/10.1016/B978-0-32-390644-9.00135-9 Wang, E.-M., Wang, Z., Ban, X., Zhao, X., Yin, Y.*, Jiang, Z.*, Chemoselective Photocatalytic Sulfenylamination of Alkenes with Sulfenamides via Energy Transfer. Chin. Chem. Lett. 2024, DOI:org/10.1016/j.cclet.2024.109843 https://doi.org/10.1016/j.cclet.2024.109843 Zhang, L., Ma, J., Ban, X., Zhao, X., Yin, Y., Jiang, Z.*, Direct Enantioselective Reduction of C=C Bond of β-Polyfluoro-alkylated Enones via Asymmetric Photoredox Catalysis. Sci China Chem. 2024, 67, 2016-2021. http://doi.org/10.1007/s11426-023-1896-5 Jiang, Y., Yin, Y.*, Jiang, Z.* Recent Advances in Strategies for Halide Atom Transfer (XAT) and their Applications. Chinese J. Org. Chem. 2024, 44, 1733-1759. https://sioc-journal.cn/Jwk_yjhx/EN/10.6023/cjoc202401035 Ma, C., Shen, J., Qu, C., Shao, T.*, Cao, S.*, Yin, Y., Zhao, X., Jiang, Z.*, Enantioselective Chemodivergent Three-Component Radical Tandem Reactions through Asymmetric Photoredox Catalysis. J. Am. Chem. Soc. 2023, 145 (36) 20141-20148. https://doi.org/10.1021/jacs.3c08883 Liu, Y., Zhang, L., Zhang, Y., Cao, S., Ban, X., Yin, Y., Zhao, X., Jiang, Z.*, Asymmetric Olefin Isomerization via Photoredox Catalytic Hydrogen Atom Transfer and Enantioselective Protonation. J. Am. Chem. Soc. 2023, 145 (33), 18307-18315. https://doi.org/10.1021/jacs.3c03732 Wang, B., Liu, Y., Jiang, C., Cao, Z., Cao, S., Zhao, X., Ban, X.*, Yin, Y.*, Jiang, Z.* Catalytic Asymmetric Hydrophosphinylation of 2-Vinylazaarenes to Access P-Chiral 2-Azaaryl-Ethylphosphine Oxides. Angew. Chem. Int. Ed. 2023, e202216605. https://doi.org/10.1002/anie.202216605 Wang, G., Li, L., Jiang, Y., Zhao, X., Ban, X. , Shao, T., Yin, Y. , Jiang, Z.* Kinetic Resolution of Azaarylethynyl Tertiary Alcohols by Chiral Bronsted Acid Catalysed Phosphine-Mediated Deoxygenation. Angew. Chem. Int. Ed. 2023, 62, e202214838. https://doi.org/10.1002/anie.202214838 Guo, Y.-Y., Tian, Z.-H., Ma, C., Han, Y.-C., Bai, D., Jiang, Z., Unlocking Mild-condition Benzene Ring Contraction Using Nonheme Diiron N-oxygenase. Chem. Sci. 2023, 14 (42) 11907-11913. https://doi.org/10.1039/D3SC04660E Yao, S., Zhao, X., Ban, X., Shao, T., Yin, Y., Hu, W.*, Jiang, Z.* Visible light-driven direct access to imine-containing azaarene-substituted highly functionalized pyrroles. Org. Chem. Front. 2023, 10 (19), 4779-4785. https://doi.org/10.1039/d3qo01056b. Luo, C., Yin, Y., Jiang, Z.* Recent Advances in Asymmetric Synthesis of P-Chiral Phosphine Oxides. Chinese J. Org. Chem. 2023, 43 (6), 1963-1976. https://doi.org/10.6023/cjoc202212024 Yin. Y., Jiang, Z.* Copper(I)-Catalyzed Asymmetric Conjugate Addition of 1,4-Dienes to β-Substituted Alkenyl Azaarenes. Chinese J. Org. Chem. 2023, 43 (3), 1203-1205. https://doi.org/10.6023/cjoc202300014 Song, X., Zhang, Y., Li, Y., Zhao, X., Yin, Y., Ban, X., Jiang, Z.* Catalytic Asymmetric Synthesis of Azaarene-Functionalized Tertiary Amines and α-Amino Acid Derivatives from E/Z-Ketimine Mixtures via Enantioselective Radical Coupling. ACS Catal. 2023, 13 (9), 6396-6402. https://doi.org/10.1021/acscatal.3c00756 Lv, X., Qi, Y.-N., Wang, J., Zhao, X., Jiang, Z.* Photoinduced Vinylogous Dearomatization. Org. Lett. 2023, 25 (17), 3114-3119. https://doi.org/10.1021/acs.orglett.3c00966 Wang, J., Lv, X., Jiang, Z.* Visible-Light-Mediated Photocatalytic Deracemization. Chem. Eur. J. 2023, 29 (29), e202204029. https://doi.org/10.1002/chem.202204029 Lv, X.*, Gao, P., Zhao, X., Jiang, Z.* Metal-Free Construction of Multisubstituted Indolizines via Intramolecular Amination of Allylic Alcohols. J. Org. Chem. 2023, 88 (13), 9459-9468. https://doi.org/10.1021/acs.joc.3c00469 Guo, Y.-Y. *, Tian, Z.-H., Han, Y.-C., Ma, D., Shao, T., Jiang, Z.*, Hantzsch Ester as Efficient and Economical NAD(P)H Mimic for In Vitro Bioredox Reactions. Chem. Eur. J. 2023, 29 (45), e202301180. https://doi.org/10.1002/chem.202301180 Shao, T.*, Ban, X., Jiang, Z.* α-Amino Acids: An Emerging Versatile Synthon in Visible Light-Driven Decarboxylative Transformations. Chem. Rec. 2023, e202300122. https://doi.org/10.1002/tcr.202300122 Dai, Y., Huang, H., Liang, S., Yin, Y., Ban, X., Zhao, X., Jiang, Z.* Catalytic Asymmetric Intermolecular [3 + 2] Photocycloaddition of Cyclopropylamines with Electron-Deficient Olefins. Org. Lett. 2023, 25 (24), 4551-4555. https://doi.org/10.1021/acs.orglett.3c01585 Gu, Z., Zhang, L., Li, H., Cao, S.*, Yin, Y., Zhao, X., Ban, X., Jiang, Z.* Deracemization through Sequential Photoredox-Neutral and Chiral Bronsted Acid Catalysis. Angew. Chem. Int. Ed. 2022, 61, e202211241. https://doi.org/10.1002/anie.202211241 Chai, X., Hu, X., Zhao, X., Yin, Y.*, Cao, S.*, Jiang, Z.* Asymmetric Hydroaminoalkylation of Alkenylazaarenes via Cooperative Photoredox and Chiral Hydrogen-Bonding Catalysis. Angew. Chem. Int. Ed. 2022, 61, e202115110. https://doi.org/10.1002/anie.202115110 Li, Y., Han, C., Wang, Y., Huang, X., Zhao, X., Qiao, B.*, Jiang, Z.* Catalytic Asymmetric Reductive Azaarylation of Olefins via Enantioselective Radical Coupling. J. Am. Chem. Soc. 2022, 144(17), 7805−7814. https://doi.org/10.1021/jacs.2c01458 Li, S., Tian, D., Zhao, X., Yin, Y., Lee, R., Jiang, Z.* Visible light-driven copper(II) catalyzed aerobic oxidative cleavage of carbon-carbon bonds: a combined experimental and theoretical study. Org. Chem. Front. 2022, 9, 6299. https://doi.org/10.1039/D2QO01264B Tan, Y., Yin, Y.*, Cao, S., Zhao, X., Qu, G., Jiang, Z.* Conjugate addition-enantioselective protonation to forge tertiary stereocentres alpha to azaarenes via cooperative hydrogen atom transfer and chiral hydrogen-bonding catalysis. Chin. J. Catal. 2022, 43, 558−563. https://doi.org/10.1016/S1872-2067(21)63887-1 Dai, Y., Liang, S., Zeng, G., Huang, H., Zhao, X., Cao, S., Jiang, Z.* Asymmetric [3+2] photocycloadditions of cyclopropylamines with electron-rich and electron-neutral olefins. Chem. Sci. 2022, 13, 3787-3795. https://doi.org/10.1039/D1SC07044D Cao, K., Li, C., Tian, D., Zhao, X.., Yin, Y.*, Jiang, Z.* Catalytic Enantioselective Reductive Cross Coupling of Electron-Deficient Olefins. Org. Lett. 2022, 24, 4788−4792. https://doi.org/10.1021/acs.orglett.2c01801 Sun, X ., Qu, C., Ma, C., Zhao, X., Chai, G.*, Jiang, Z.* Photoredox Catalytic Cascade Radical Addition to Construct 1,4-Diketone-Functionalized Quinoxalin-2(1H)-one Derivatives. Chin. J. Org. Chem. 2022, 42, 1396−1406. https://doi.org/10.6023/cjoc202201025 Tian, D., Sun, X., Cao, S., Wang, E., Yin, Y., Zhao, X., Jiang, Z.* Enantioselective intermolecular [2+2] photocycloadditions of vinylazaarenes with triplet-state electron-deficient olefins. Chin. J. Catal. 2022, 43, 2732−2742. https://doi.org/10.1016/S1872-2067(22)64156-1 Yin, Y., Zhao, X.*, Jiang, Z.*.Asymmetric Photocatalytic Synthesis of Enantioenriched Azaarene Derivatives. Chin. J. Org. Chem. 2022, 42, 1609−1625. https://doi.org/10.6023/cjoc202201047 Ban, X. , Jiang, Z.* Synergistic Photoredox Catalyzed Asymmetric Allylic Alkylation via C-H Dehydrogenation. Chin. J. Org. Chem. 2022, 42, 2248−2249. https://doi.org/10.6023/cjoc202200031 Kong, M., Tan, Y., Zhao, X., Qiao, B., Tan, C., Cao, S., Jiang, Z.* Catalytic Reductive Cross Coupling and Enantioselective Protonation of Olefins to Construct Remote Stereocenters for Azaarenes. J. Am. Chem. Soc. 2021,143, 4024−4031. https://doi.org/10.1021/jacs.1c01073 Chen, X., Wei, W., Li, C., Zhou, H., Qiao, B*., Jiang, Z.* Photoredox-Catalyzed Synthesis of Remote Fluoroalkylated Azaarene Derivatives and the alpha-Deuterated Analogues via 1,n-Hydrogen-Atom-Transfer-Involving Radical Reactions. Org. Lett. 2021, 23, 8744−8749. https://doi.org/10.1021/acs.orglett.1c03204 Xu, H., Liu, J., Nie, F., Zhao, X.,Jiang, Z.* Metal-Free Hydropyridylation of Thioester-Activated Alkenes via Electroreductive Radical Coupling. J. Org. Chem. 2021, 86, 16204−16212. https://doi.org/10.1021/acs.joc.1c01526 Yin, Y., Fan, Y., Zhao, X., Chai, G.,Jiang, Z.* Organocatalytic Enantioselective and Diastereodivergent Mannich Reactions of 5-Substituted Oxazolidin-2,4-Diones. Asian J. Org.Chem. 2021,10, 2538−2543. https://doi.org/10.1002/ajoc.202100480 Yang, H., Li, H., Wei, G.*, Jiang, Z.* Photoredox Catalytic Phosphite-Mediated Deoxygenation of alpha-Diketones Enables Wolff Rearrangement and Staudinger Synthesis of beta-Lactams. Angew. Chem. Int. Ed. 2021, 60, 19696−19700. https://doi.org/10.1002/anie.202107080 Guo, Z., Chen, X., Fang, H ., Zhao, X.*, Jiang, Z.* Divergent asymmetric synthesis of azaarene-functionalized cyclic alcohols through stereocontrolled Beckwith-Enholm cyclizations. Sci. China Chem. 2021, 6543−6550. https://doi.org/10.1007/s11426-021-1019-2 Hu, W., Zhan, Q., Zhou, H., Cao, S.* , Jiang, Z.* Radical-based functionalization-oriented construction: rapid assembly of azaarene-substituted highly functionalized pyrroles. Chem. Sci. 2021, 12, 6543-6550. https://doi.org/10.1039/D1SC01470F Jia, H., Qiao, B.*, Jiang, Z.* Photoredox Catalytic Radical Coupling to Access beta-Fluoro alpha-Amino Acid Derivatives. Acta Chim. Sinica, 2021, 79, 1477−1480. https://doi.org/10.6023/A21090432 Ban, X., Fan, Y., Kha, T., Lee, R., Kee, C. Jiang, Z.*, Tan, C.* Pentanidium-Catalyzed Direct Assembly of Vicinal All-Carbon Quaternary Stereocenters through C(sp3)-C(sp3) Bond Formation. CCS Chem. 2021, 3, 2192−2200. https://doi.org/10.31635/ccschem.021.202101013

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