个人简介
1994 Special Postdoctoral Researcher, RIKEN
1994-1999 Assistant Professor, The University of Tokyo
2000-2007 Associate Professor, Institute for Molecular Science
2007-2011 Professor, Catalysis Research Center, Hokkaido University
2011- Professor, Department of Chemistry, The University of Tokyo
Awards:
1994 Inoue Research Award for Young Scientists
2006 GOLD2006, best presentation award
2009 The Chemical Society of Japan Award for Creative Work
研究领域
Physical chemistry/Nanoscience/Catalysis
(1) Chemical reactivities and electronic structures of free metal clusters
(2) Precision synthesis and characterization of metal cluster catalysts
(3) Development of chemically-modified superatoms and superatomic molecules
近期论文
查看导师最新文章
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"Nonscalable oxidation catalysis of gold clusters"
S. Yamazoe, K. Koyasu, T. Tsukuda,
Acc. Chem. Res. 47, 816–824 (2014).
"A twisted bi-icosahedral Au25 cluster enclosed by bulky arenethiolates"
J. Nishigaki, S. Yamazoe, S. Kohara, A. Fujiwara, W. Kurashige, Y. Negishi, T. Tsukuda,
Chem. Commun. 50, 839–841 (2014).
"Binding motif of terminal alkynes on gold clusters"
P. Maity, S. Takano, S. Yamazoe, T. Wakabayashi, T. Tsukuda,
J. Am. Chem. Soc. 135, 9450–9457 (2013).
"A new binding motif of sterically demanding thiolates on a gold cluster"
J. Nishigaki, R. Tsunoyama, H. Tsunoyama, N. Ichikuni, S. Yamazoe, Y. Negishi, M. Itoh, T. Matsuo, K. Tamao, T. Tsukuda,
J. Am. Chem. Soc. 134, 14295–14297 (2012).
"Stabilized gold clusters: from isolation toward controlled synthesis"
P. Maity, S. Xie, M. Yamauchi, T. Tsukuda,
Nanoscale 4, 4027–4038 (2012).
"Toward an atomic-level understanding of size-specific properties of protected and stabilized gold clusters"
T. Tsukuda,
Bull. Chem. Soc. Jpn. 85, 151–168 (2012).
"Enhancement in aerobic alcohol oxidation catalysis of Au25 clusters by single Pd atom doping"
S. Xie, H. Tsunoyama, W. Kurashige, Y. Negishi, T. Tsukuda,
ACS Catal. 2, 1519–1523 (2012).
"Selective synthesis of organogold magic clusters Au54(C≡CPh)26"
P. Maity, T. Wakabayashi, N. Ichikuni, H. Tsunoyama, S. Xie, M. Yamauchi, T. Tsukuda,
Chem. Commun. 48, 6085–6087 (2012).
"Organogold clusters protected by phenylacetylene"
P. Maity, H. Tsunoyama, M. Yamauchi, S. Xie, T. Tsukuda,
J. Am. Chem. Soc. 133, 20123–20125 (2011).
"Synthesis and characterization of Au102(p–MBA)44 nanoparticles"
Y. Levi–Kalisman, P. D. Jadzinsky, N. Kalisman, H. Tsunoyama, T. Tsukuda, D. A. Bushnell, R. D. Kornberg,
J. Am. Chem. Soc. 133, 2976–2982 (2011).
"Aerobic oxidation of cyclohexane catalyzed by size–controlled Au clusters on hydroxyapatite: size effect in the sub–2 nm regime"
Y. Liu, H. Tsunoyama, T. Akita, S. Xie, T. Tsukuda,
ACS Catal. 1, 2–6 (2011).
"Efficient and selective epoxidation of styrene with TBHP catalyzed by Au25 clusters on hydroxyapatite"
Y. Liu, H. Tsunoyama, T. Akita, T. Tsukuda,
Chem. Commun. 46, 550–552 (2010).
"Magic numbers of gold clusters stabilized by PVP"
H. Tsunoyama, T. Tsukuda,
J. Am. Chem. Soc. 131, 18216–18217 (2009).
"Effect of electronic structures of Au clusters stabilized by poly(N–vinyl–2–pyrrolidone) on aerobic oxidation catalysis"
H. Tsunoyama, N. Ichikuni, H, Sakurai, T. Tsukuda,
J. Am. Chem. Soc. 131, 7086–7093 (2009).
"Ubiquitous 8 and 29 kDa gold:alkanethiolate cluster compounds: mass–spectrometric determination of molecular formulas and structural implications"
N. K. Chaki, Y. Negishi, H. Tsunoyama, Y. Shichibu, T. Tsukuda,
J. Am. Chem. Soc. 130, 8608–8610 (2008).
"Origin of magic stability of thiolated gold clusters: a case study on Au25(SC6H13)18"
Y. Negishi, N. K. Chaki, Y. Shichibu, R. L. Whetten, T. Tsukuda,
J. Am. Chem. Soc. 129, 11322–11323 (2007).
"Biicosahedral gold clusters [Au25(PPh3)10(SCnH2n+1)5Cl2]2+ (n=2–18): a stepping stone to cluster–assembled materials"
Y. Shichibu, Y. Negishi, T. Watanabe, N. K. Chaki, H. Kawaguchi, T. Tsukuda,
J. Phys. Chem. C 111, 7845–7847 (2007).
"Large–scale synthesis of thiolated Au25 clusters via ligand exchange reactions of phosphine–stabilized Au11 clusters"
Y. Shichibu, Y. Negishi, T. Tsukuda, T. Teranishi,
J. Am. Chem. Soc. 127, 13464–13465 (2005).
"Size–specific catalytic activity of polymer–stabilized gold nanoclusters for aerobic alcohol oxidation in water"
H. Tsunoyama, H. Sakurai, Y. Negishi, T. Tsukuda,
J. Am. Chem. Soc. 127, 9374–9375 (2005).
"Glutathione–protected gold clusters revisited: bridging the gap between gold(I)–thiolate complexes and thiolate–protected gold nanocrystals"
Y. Negishi, K. Nobusada, T. Tsukuda,
J. Am. Chem. Soc. 127, 5261–5270 (2005).