Abboud, Khalil A. - University of Florida

个人简介

Ph.D., Louisiana State University, 1985

研究领域

Structural Chemistry, X-Ray diffraction, Structural studies of matter at the atomic level resolution The X-Ray laboratory at the University of Florida/Department of Chemistry provides single crystal structure determination expertise to characterize newly synthesized materials. All crystals of Organic, Inorganic, Organometallic, Metal organic and Metal clusters can be analyzed after their X-Ray diffraction patterns and intensities, which are scattered by the electron clouds around atoms, are measured. Our aim is to provide detailed three-dimensional architectures of molecules in the crystalline state. A knowledge which can be used to confirm the identity of the materials, provide insight to their formation and parameters for the optimization of the synthetic process, and to further our understanding of their microscopic and macroscopic properties. Additionally, we have collaborative research projects with industrial companies pursuing further knowledge in catalysis and with academic institutions in the field of drug design. Experience and interest includes: catalysis, chemical crystallography, clusters, coordination chemistry, crystal engineering, data collection and processing, disorder, hydrogen bonding, inorganic compounds, materials science, natural products, organic compounds, organometallic compounds, polymorphism, quasicrystals, semiconductors, small molecules, structural chemistry, structure determination, structure-activity relationships, superconductors, synchrotron radiation, teaching and education, X-ray diffraction, NLO, small molecule.

近期论文

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"Mixed 3d/4d and 3d/4f metal clusters: Tetranuclear (Fe2M2III)-M-III (M-III = Ln, Y) and (Mn2M2III)-M- IV (M = Yb, Y) complexes, and the first Fe/4f single-molecule magnets". Murugesu, M, Mishra, A, Wernsdorfer, W, Abboud, KA, Christou, G (2006). Polyhedron, 2592), 613-625. "Synthesis and structural investigation of tungsten imido amidinate and guanidinate complexes". Wilder, CB, Reitfort, LL, Abboud, KA, McElwee-White, L (2006). Inorg. Chem. 45(1), 263-268. "Synthesis and reactivity of molybdenum(IV) complexes with alkyl and aryl isocyanides". Ison, EA, Ortiz, CO, Abboud, K Boncella, JM (2005). Organomettalics 24926), 6310-6318. "(NH4)(3)CrO8: A new S=1/2 system exhibiting no magnetic transition down to 0.3 K". Harter, A, Cage, B, Nguyen, P, Abboud, KA, Dalal, NS (2005). Polyhedron, 24916-17), 2350-2354. "Two isomeric [Mn12O12(OMe)(2)(O2CPh)(16)(H2O)(2)](2-) single-molecule magnets and a Mn-III polymer prepared by a reductive aggregation synthetic route". Tasiopoulos, AJ, Wernsdorfer, W, Abboud, KA, Christou, G (2005). Polyhedron, 24(16-17), 2505-2512. "Single-molecule magnets: synthesis, structures and magnetic properties of Mn-11 and Mn-25 clusters". Murugesu, M, Wernsdorfer, W, Abboud, KA, Christou, G (2005). Polyhedron, 24(16-17), 2894-2899. "Highly pyramidalized cage alkene formed via the double Diels-Alder cycloaddition of syn-4,5,13,14- bis(dehydro)octafluoroparacyclophane to anthracene". Dolbier, WR, Zhai, YA, Battiste, MA, Abboud, KA, Ghiviriga, I 92005). J. Org. Chem. 70(25), 10336-10341. "Coupling of an aldehyde or ketone to pyridine mediated by a tungsten imido complex". Hayton, TW, Boncella, JM, Scott, BL, Abboud, KA, Mills, RC (2005). Inorg. Chem. 44(25), 9506-9517. "Single-molecule magnets: A reductive aggregation route to new types of Mn-12 complexes". King, P, Wernsdorfer, W, Abboud, KA, Christou, G (2005). Inorg. Chem. 44(24), 8659-8669. "A new route into hexahydro-cyclopenta[b]pyrrole-cis-3a,6-diols. Synthesis of constrained bicyclic analogues of pyrrolidine azasugars". Sun, H, Abboud, KA, Horenstein, NA 92005). Tetrahedron, 61(44), 10462- 10469. "High-nuclearity homometallic iron and nickel clusters: Fe-22 and Ni-24 complexes from the use of N- methyldiethanolamine". Foguet-Albiol, D, Abboud, KA, Christou, G (2005). Chem. Comm. 34, 4282-4284. "Tungsten allylimido complexes Cl-4(RCN)W(NC3H5) as single-source CVD precursors for WNxCy thin films. Correlation of precursor fragmentation to film properties". Bchir, OJ, Green, KM, Ajmera, HM, Zapp, EA, Anderson, TJ, Brooks, BC, Reitfort, LL, Powell, DH, Abboud, KA, McElwee-White, L (2005) Journal of the American Chemical Society, 127(21), 7825-7833. "[Mn12O12(OMe)(2)(O2CPh)(16)(H2O)(2)](2)-single-molecule magnets and other manganese compounds from a reductive aggregation procedure". Tasiopoulos, AJ, Wernsdorfer, W, Abboud, KA & Christou, G (2005). Inorganic Chemnistry, 44(18) 6324-6338. "Electrochromic conjugated N-salicylidene-aniline (anil) functionalized pyrrole and 2,5-dithienylpyrrole- based polymers". Thompson, BC, Abboud, KA, Reynolds, JR Nakatani, K & Audebert, P. (2005). New Journal of Chemistry 29(9), 1128-1134. "High-nuclearity homometallic iron and nickel clusters: Fe-22 and Ni-24 complexes from the use of N- methyldiethanolamine". Foguet-Albiol, D, Abboud, KA & Christou, G (2005). Chemical Communications 34, 4282-4284. "Single-molecule magnets: Structural characterization, magnetic properties, and F-19 NMR spectroscopy of a Mn-12 family spanning three oxidation levels". Chakov, NE, Soler, M, Wernsdorfer, W, Abboud, KA & Christou, G (2005). Inorganic Chemistry 44(15), 5304-5321. "New polynuclear manganese clusters from the use of the hydrophobic carboxylate ligand 2,2- dimethylbutyrate". Chakov, NE, Zakharov, LN, Abboud, KA & Christou, G (2005). Inorganic Chemistry 44(13), 4555-4567. "Bond valence sums and structural studies of antimony complexes containing Sb bonded only to O ligands". Palenik, RC, Abboud, KA & Palenik, GJ 92005). Inorganica Chimicia Acta 358(4), 1034-1040. "A platinum acetylide polymer with sterically demanding substituents: Effect of aggregation on the triplet excited state". Zhao, XM, Cardolaccia, T, Farley, RT, Abboud, KA & Schanze, KS (2005). Inorganic Chemistry 44(8), 2619-2627. "Highly active, regioselective, and enantioselective hydroformylation with Rh catalysts ligated by bis-3,4- diazaphospholanes". Clark, TP, Landis, CR, Freed, SL, Klosin, J & Abboud, KA. (2005). JACS, 127(14), 5040-5042.