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个人简介

Ph.D., The Johns Hopkins University, 1985

研究领域

Inorganic

Magnetic nanostructures and thin films, Biomolecules at inorganic interfaces, Biomineralization Our group is currently divided between three different materials chemistry and biomaterials chemistry projects. The theme that unites them is an understanding of the importance of surfaces and interfaces. Magnetic nanostructures and thin films. The first series of projects centers on magnetism and related properties in nanostructures and thin films of synthetic inorganic networks. This class of materials differs from traditional magnets in that synthetic chemistry can be used to prepare systems that combine properties, such as photomagnetism. Biomolecules at inorganic interfaces. This series of projects probes the binding of biomolecules to synthetic inorganic surfaces. Biomolecule adsorption at surfaces is important for many applications, including sensing and biochip technologies. We develop inorganic surface chemistry aimed a introducing specific ligand/metal interactions that can be used to bind and orient biomolecules at surfaces. Biomineralization. Our understanding of organic/inorganic interfaces is used to explore important biomineralization processes. Biological inorganic solids generally grow with the help of a biomolecule interface. We are exploring the details of these processes in both purposeful biominerals, such as in shells and bones, and pathological biominerals, such as kidney stones.

近期论文

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Light-Induced Magnetization Changes in a Coordination Polymer Heterostructure of a Prussian Blue Analogue and a Hofmann-like Fe(II) Spin Crossover Compound. Corey R. Gros, Markus K. Peprah, Brian D. Hosterman, Tatiana, V. Brinsari, Pedro A. Quintero, Mariana Sendova, Mark W. Meisel, Daniel R. Talham. J. Am. Chem. Soc. 2014, 126, 99846-9849. Size-Dependent MRI Relaxivity and Dual Imaging with Eu0.2Gd0.8PO4⋅H2O Nanoparticles. Yichen Li, Tao Chen, Weihong Tan, and Daniel R. Talham. Langmuir 2014, 30, 5873-5879. Li-ion and Na-ion Insertion into Size-controlled Nickel Hexacyanoferrate Nanoparticles. Carissa H. Li, Yusuke Nanba, Daisuke Asakura, Masashi Okubo, and Daniel R. Talham. RSC Adv. 2014, 4, 24955-24961. X-ray Absorption Study of Structural Coupling in Photomagnetic Prussian Blue Analogue Core@Shell Particles. Daniel M. Pajerowski, Bruce Ravel, Carissa H. Li, Matthieu F. Dumont and Daniel R. Talham. Chem. Mater. 2014, 26, 2586-2594. High Rate Sodium Ion Insertion into Core-Shell Nanoparticles of Prussian Blue Analogues. Masashi Okubo, Carissa H. Li, Daniel R. Talham. Chem. Commun. 2014, 50, 1353-1355. Photoinduced Perturbations of the Magnetic Superexchange in Core@Shell Prussian Blue Analogues. Elisabeth S. Knowles, Carissa H. Li, Matthieu F. Dumont, Marcus K. Peprah, Matthew J. Andrus, Daniel R. Talham, and Mark W. Meisel. Polyhedron, 2013, 66, 153-156. When Local Deformations Trigger Lattice Instability: Flow Diagram Investigations for Photoinduced and Quenched Metastable States in a Prussian Blue Analog. M. Itoi, I. Maurin, F. Varret, F.A. Frye, D.R. Talham, D. Chernyshov, K. Boukheddaden. Physical Review B 2013, 88, 094104. Effect of Pressure on the Magnetic Properties of LiCuFe and LiCuFe@LiNiCr Prussian Blue Analogues. Marcus K. Peprah, Carissa H. Li, Daniel R. Talham, Mark W. Meisel. Polyhedron, 2013, 66, 264-267. Films of photomagnetic CoFe Prussian blue analogue on thin manganite substrates: fabrication and characterization. P. A. Quintero, M. F. Dumont, D. M. Grant, E. S. Knowles, H. J. Jeen, A. Biswas, D. R. Talham, M. W. Meisel. Polyhedron, 2013, 66, 201-204. Synthesis and Size Control of Iron Hexacyanochromate(III) Nanoparticles and the Effect of Particle Size on Linkage Isomerism. Matthieu F. Dumont, Olivia N. Risset, Elisabeth S. Knowles, Takashi Yamamoto, Daniel M. Pajerowski, Mark W. Meisel, and Daniel R. Talham. Inorganic Chemistry, 2013, 52, 4494-4501. Influence of Particle Size on the Thermal Spin Transition of the Prussian Blue Analogue K0.4Co1.3[Fe(CN)6]・4.4 H2O. Matthew J. Andrus, Yitzi M. Calm, Elisabeth S. Knowles, Khalil A. Abboud, Mark W. Meisel, Daniel R. Talham. Polyhedron, 2013, 64, 289-293. Structural and Magnetic Properties of Four Layered Dicyanamide-Based Coordination polymers: M{N(CN)2}2(DMSO)2, [M = Mn, Fe, Co, Ni]. Divya Rajan, Pedro A. Quintero, Khalil A. Abboud, Mark W. Meisel, and Daniel R.Talham. Polyhedron 2013, 66, 142-146. Bimetallic Cyanide Bridged Coordination Polymers as Lithium ion Cathode Materials: Core@Shell Nanoparticles with Enhanced Cyclability. Daisuke Asakura, Carissa H. Li, Yoshifumi Mizuno, Masashi Okubo, Haoshen Zhou, and Daniel R. Talham. J. Am. Chem. Soc. 2013, 135, 2793-2799. RbjMk[Fe(CN)6]l (M = Co, Ni) Prussian Blue Analogue Hollow Nanocubes: a New Example of a Multilevel Pore System. Olivia N. Risset, Elisabeth S. Knowles, Shengqian Ma, Mark W. Meisel, and Daniel R. Talham. Chem. Mater. 2013, 25, 42-47. Magnetic Neutron Scattering of Thermally Quenched K-Co-Fe Prussian Blue Analogue Photomagnet. D. M. Pajerowski, V. O. Garlea, E. S. Knowles, M. J. Andrus, M. F. Dumont, Y. M. Calm, S. E. Nagler, X. Tong, D. R. Talham, M. W. Meisel. Physical Review B 2012, 86, 054431. DNA Surface Modified Gadolinium Phosphate Nanoparticles as MRI Contrast Agents. Matthieu F. Dumont, Celine Baligand, Yichen Li, Elisabeth S. Knowles, Mark W. Meisel, Glenn A. Walter, and Daniel R. Talham. Bioconjugate Chemistry 2012, 23, 951-957. Supported Lipid Bilayers at Skeletonized Surfaces for the Study of Transmembrane Proteins. Roxane M. Fabre, George O. Okeyo, and Daniel R. Talham Langmuir 2012, 28, 2835-2841. Engineering of a Phosphorylatable Tag for Specific Protein Binding on Zirconium Phosphonate Based Microarrays. M. Cinier, M. Petit, F. Pecorari, D. R. Talham, B. Bujoli, and C. Tellier J. Bio. Inorg. Chem. 2012, 17, 399-407. Metastable State of the Photomagnetic Prussian Blue Analog K0.3Co[Fe(CN)6]0.77 3.6H2O Investigated by Various Techniques. C. Chong, M. Itoi, K. Boukheddaden, E. Codjovi, A. Rotaru, F. Varret, F. Frye, D. R. Talham, I. Maurin, D. Chernyshov, and M. Castro. Phys. Rev. B. 2011, 84, 144102. Photoinduced Magnetism in a Series of Prussian Blue Analogue Heterostructures. D.M. Pajerowski, J. E. Gardner, F. A. Frye, M. J. Andrus, M. F. Dumont, E. S. Knowles, M. W. Meisel, and D. R. Talham. Chem. Mater. 2011, 23, 3045.

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