Newman, Paul - Cardiff University

个人简介

MSc (1988, R. D. Gillard) and PhD (1991, P. A. Williams), University of Wales Cardiff. Post -doctoral research associate, University of Wales Cardiff (1991-2, R. D. Gillard), University of Glasgow (1993-96, R. D. Peacock and R. J. Cross), Cardiff University (1997-2002, P. G. Edwards). Appointed Cardiff University Research Fellow 2002 and Cardiff Catalysis Institute (CCI) research officer (2009).

研究领域

Development of new ligand frameworks for application in coordination chemistry and homogeneous catalysis Phosphacyclic chemistry particularly the design and synthesis of structurally elaborate polycyclic phosphines as novel ligands Chiral metal complexes Rigid bicyclic N-heterocyclic carbenes with secondary donors as supporting ligands for high oxidation state metal centes Asymmetric transition metal catalysed oxidations Most of our work encompasses aspects of synthetic organic, inorganic and organometallic chemistry with an emphasis on preparing new ligands and exploring their coordination chemistry and deployment in homogeneous catalysis. Inherently chiral phosphines and N-heterocyclic carbenes (NHCs) are of particular interest.

近期论文

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Bouché, M.et al. 2016. Mono- and dimeric complexes of an asymmetric heterotopic P,CNHC,pyr ligand. Dalton Trans. (10.1039/C6DT02476A) pdf Cox, K.et al. 2016. N2S2 and N4S4 precursors to PS2 macrocycles and cyclic amidinium salts. Dalton Transactions 45, pp. 8485-8493. (10.1039/C6DT00806B) pdf Wilkins, L.et al. 2015. Pathways to functionalized heterocycles: propargyl rearrangement using B(C6F5)3. Organometallics 34(21), pp. 5298-5309. (10.1021/acs.organomet.5b00753) pdf Edwards, P.et al. 2014. Aspects of the coordination chemistry of rac-trans-1,2-diphosphinocyclohexane and the preparation of reinforced 9aneP3and 9anePN2macrocycles. Dalton Transactions 43(41), pp. 15532-15545. (10.1039/C4DT02239D) Edwards, P.et al. 2014. Manganese(i) templates for the construction of benzannulated triphosphamacrocycles. Dalton Transactions 43, pp. 15646-15655. (10.1039/C4DT02203C) Kariuki, B., Platts, J. A. and Newman, P. D. 2014. It's all about Me: methyl-induced control of coordination stereochemistry by a flexible tridentate N,C,N′ ligand. Dalton Transactions 43(7), pp. 2971-2978. (10.1039/c3dt52841c) Edwards, P.et al. 2014. Peripheral methyl activation in η4-1,2,3,4-tetramethylcyclobutadienylcobalt complexes: template synthesis and subsequent reactivity of triphosphamacrocycles. Organometallics 33(19), pp. 5440-5447. (10.1021/om500734b) Newman, P. D., Cavell, K. J. and Kariuki, B. 2012. Variable coordination of a chiral diphosphine containing an amidinium/NHC group within its backbone: μ-P,P′, κ2-P,P′ and κ3-P,C,P′ coordination modes. Dalton Transactions 41(40), pp. 12395-12407. (10.1039/c2dt31475d) pdf Newman, P. D., Cavell, K. J. and Kariuki, B. 2012. Monovalent chiral-at-copper complexes: halide-controlled diastereoselectivity. Chemical Communications 48(52), pp. 6511-6513. (10.1039/c2cc33036a) Newman, P. D., Cavell, K. J. and Kariuki, B. 2012. Monovalent chiral-at-copper complexes: halide-controlled diastereoselectivity. Chemical Communications 48(52), pp. 6511-6513. (10.1039/c2cc33036a) pdf Edwards, P.et al. 2011. Metal complexes of a structurally embellished phosphinane ligand: an assessment of stereoelectronic effects. European Journal of Inorganic Chemistry 2011(8), pp. 1230-1239. (10.1002/ejic.201001170) Albers, T.et al. 2011. Iron(ii) template synthesis of benzannulated triphospha- and triarsamacrocycles. Dalton Transactions 40(37), pp. 9525-9532. (10.1039/c0dt01724h)