Amoroso, Angelo - Cardiff University

个人简介

PhD, University of Cambridge (1992, B. F. G. Johnson and J. Lewis, synthesis of high nuclearity osmium carbonyl clusters). Postdoctoral Research Fellow, Bristol (1992-1995, J. A. McCleverty and M. D. Ward, synthesis and properties of Mo(NO) species). Postdoctoral Research Fellow, University of Utah (1995-1997, J. A. Gladysz, synthesis and properties of Re(NO) species linked by polyacetylene fragments). Postdoctoral Research Fellow, University of Nottingham (1997-1998, M. Schröder, modelling Ni/Fe hydrogenases). Appointed Lecturer in Inorganic Chemistry, Cardiff, 1998.

研究领域

Development of highly fluorescent lanthanide complexes. We are synthesising lanthanide complexes and increasing their lifetimes and quantum yields. They will be used as biological tags or as chemical sensors. Design and synthesis of ligands suitable for MRI contrast agents. We are currently synthesising reagents which will show strong switching behaviour in their relaxivity thus producing effective diagnostic reagents. We are also seeking to increase water exchange rates in complexes, leading to higher relaxivities. Synthesis of fluorescent organometallic rhenium complexes. Ligand modifications resulting in modified stereochemistry and reactivity. Underlying our applied research is the intriguing topic of how simple changes to a ligand array may greatly affect topology and prehaps reactivity. Developing catalytic systems for the oxidation of alkanes. A major goal for industry as well as academia, we are aiming to produce electrochemically fuelled systems with a transition metal catalyst.

近期论文

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Amoroso, A. J., Fallis, I. A. and Pope, S. J. A. 2017. Chelating agents for radiolanthanides: applications to imaging and therapy. Coordination Chemistry Reviews (10.1016/j.ccr.2017.01.010) pdf Amoroso, A.et al. 2016. Shaping and enforcing coordination spheres: probing the ability of tripodal ligands to favour trigonal prismatic geometry. Dalton Transactions 45(26), pp. 10630-10642. (10.1039/C6DT01165A) pdf Amoroso, A.et al. 2016. Co-ordination behaviour of a novel tristhiourea tripodal ligand; structural variations in a series of transition metal complexes. Dalton Transactions 45(25), pp. 10280-10288. (10.1039/C6DT01148A) pdf Jana, A.et al. 2016. Heteronuclear Ir(III)–Ln(III) luminescent complexes: small-molecule probes for dual modal imaging and oxygen sensing. Inorganic Chemistry 55(11), pp. 5623-5633. (10.1021/acs.inorgchem.6b00702) pdf Stacey, O.et al. 2016. Near-IR luminescent lanthanide complexes with 1,8-diaminoanthraquinone-based chromophoric ligands. Dalton Transactions 45, pp. 6674-6681. (10.1039/C5DT04351D) Stacey, O.et al. 2015. Water soluble, cyclometalated Pt(II)–Ln(III) conjugates towards novel bimodal imaging agents. Chemical Communications 51(61), pp. 12305-12308. (10.1039/C5CC02623G) pdf Amoroso, A. J. and Pope, S. J. A. 2015. Using lanthanide ions in molecular bioimaging. Chemical Society Reviews 44(14), pp. 4723-4742. (10.1039/C4CS00293H) Jana, A.et al. 2015. A new ligand skeleton for imaging applications with d–f complexes: combined lifetime imaging and high relaxivity in an Ir/Gd dyad. Chemical Communications 51(42), pp. 8833-8836. (10.1039/C5CC02130H) Foerster, C.et al. 2014. [64Cu]Cu-CryptTM – A novel cryptate for copper-64?. Nuclear Medicine and Biology 41(7), pp. 633. (10.1016/j.nucmedbio.2014.05.127) Foerster, C.et al. 2014. Synthesis, complex stability and small animal PET imaging of a novel 64Cu-labelled cryptand molecule. MedChemComm 5(7), pp. 958-962. (10.1039/c4md00174e) Hossain, G. M. G. and Amoroso, A. J. 2014. Bis[4-amino-N-(4-methylpyrimidin-2-yl-[kappa]N3)benzenesulfonamidato-[kappa]N](2,2'-bipyridine-[kappa]2N,N')mercury(II). Acta Crystallographica Section E - Structure Reports Online 70(4), pp. m127-m128. (10.1107/S1600536814004760) pdf