Kays, Deborah - University of Nottingham

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Dr Deborah Kays began her academic career with an MChem (Hons) degree from Cardiff University in 2000. Remaining at Cardiff she obtained her PhD in 2003 for the investigation of the synthesis and reactivity of novel transition metal complexes of boron, under the supervision of Dr Simon Aldridge. A postdoctoral position, also with Simon Aldridge, followed, which saw her research interests expand into the synthesis and reactivity of B/N vinylidene analogues, low-coordinate complexes featuring the heavier group 13 elements and Lewis acidic boryl compounds for C-H activation chemistry. Deborah took up a Junior Research Fellowship at Merton College, Oxford (2005-2007), which allowed her to build up an independent research programme investigating the synthesis and bonding of low-coordinate main group and transition metal centres. She was appointed Lecturer in Inorganic Chemistry at the University of Nottingham in 2007.

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GRIDLEY, B.M., MOXEY, G.J., LEWIS, W., BLAKE, A.J. and KAYS, D.L., 2013. Conformational isomerism in monomeric, low-coordinate group?12 complexes stabilized by a naphthyl-substituted m-terphenyl ligand Chemistry: A European Journal. 19(34), 11446-11453 MOORHOUSE RS, MOXEY GJ, ORTU F, READE TJ, LEWIS W, BLAKE AJ and KAYS DL, 2013. Structural diversity in alkali metal complexes of sterically demanding carbazol-9-yl ligands. Inorganic chemistry. 52(5), 2678-83 RICHARDS, V.J., GOWER, A.L., SMITH, J.E.H.B., DAVIES, E.S., LAHAYE, D., SLATER, A.G., LEWIS, W., BLAKE, A.J., CHAMPNESS, N.R. and KAYS, D.L., 2012. Synthesis and characterisation of BODIPY radical anions Chemical Communications. 48(12), 1751-1753 GRIDLEY, B.M., BLAKE, A.J., DAVIS, A.L., LEWIS, W., MOXEY, G.J. and KAYS, D.L., 2012. Low-coordinate cobalt(II) terphenyl complexes: precursors to sterically encumbered ketones Chemical Communications. 48(71), 8910-8912 BLAKE, AJ, GOWER, AL, LEWIS, W, MOXEY, GJ, READE, TJ and KAYS, DL, 2011. Synthesis And Characterisation Of Complexes Of The 2,6-Diphenoxyphenyl Ligand Journal Of Organometallic Chemistry. 696(9), 1787-1791 SIMON ALDRIDGE, ANTHONY J. DOWNS and DEBORAH L. KAYS, 2011. Formal Oxidation State +3: Organometallic Chemistry. In: SIMON ALDRIDGE and ANTHONY J. DOWNS, eds., The Group 13 Metals Aluminium, Gallium, Indium and Thallium: Chemical Patterns and Peculiarities John Wiley & Sons. 148-245 KAYS, D.L., 2010. The Stabilisation of Organometallic Complexes Using m-Terphenyl Ligands. In: SPR Organometallic Chemistry Royal Society of Chemistry. (In Press.) VIDOVIC, D., PIERCE, G.A., COOMBS, N.D., KAYS, D.L., THOMPSON, A.L. STASCH, A. and ALDRIDGE, S., 2010. Synthesis and Structural Characterization of terminal (Diisopropylamino)borylene Complexes of Group 8 Metals Main Group Chemistry. (In Press.) BLAKE, A.J., GILLIBRAND, N.L., MOXEY, G.J. and KAYS, D.L., 2009. Differing coordination environments in transition metal derivatives of 1,8-bis(silylamido)naphthalene ligands. Inorganic Chemistry. 48(22), 10837–10844 DE, S., PIERCE, G.A., VIDOVIC, D., KAYS, D.L., COOMBS, N.D., JEMMIS, E.D. and ALDRIDGE, S., 2009. Reactivity of Cationic Terminal Borylene Complexes: Novel Mechanisms for Insertion and Metathesis Chemistry Involving Strongly Lewis Acidic Ligand Systems Organometallics. VOL 28(NUMB 10), 2961-2975 ASHLEY, A.E., COWLEY, A.R., GREEN, J.C., JOHNSTON, D.R, WATKIN, D.J. and KAYS, D.L., 2009. Synthesis and Characterisation of Low-coordinate Transition-Metal Complexes Stabilised by Sterically Demanding Carbazolido Ligands European Journal of Inorganic Chemistry. 2547-2552 PIERCE, G.A., VIDOVIC, D., KAYS, D.L., COOMBS, N.D., THOMPSON, A.L., JEMMIS, E.D., DE, S. and ALDRIDGE, S., 2009. Half-Sandwich Group 8 Borylene Complexes: Synthetic and Structural Studies and Oxygen Atom Abstraction Chemistry Organometallics. VOL 28(NUMB 10), 2947-2960 KAYS, D.L. and ALDRIDGE, S., 2009. Bridging the Gap between Coordination and Cluster Compounds: Unusual Bonding Modes for Zinc Angewandte Chemie International Edition. 48, 4109-4111 ZHOU, B., DENNING, M.S., KAYS, D.L. and GOICOECHEA, J.M., 2009. Synthesis and isolation of [Fe@Ge10]3-: a pentagonal prismatic zintl ion cage encapsulating an interstitial iron atom Journal of the American Chemical Society. 131(8), 2802-2803 KAYS, D.L. and ALDRIDGE, S., 2008. Transition Metal Boryl Complexes. In: Structure and Bonding: Contemporary Metal Boron Chemistry I 130. Springer-Verlag. 29-122 COWLEY, A.R., JOHNSTON, D.R., KAYS, D.L. and WATKIN, D.J., 2008. Crystal Structure of 1,3,6-Tribromocarbazole Analytical Sciences. 24, x189-x190 KAYS (NEE COOMBS), D. L. and COWLEY, A. R., 2007. Monomeric, two-coordinate Mn, Fe and Co(II) complexes featuring 2,6-(2,4,6-trimethylphenyl)phenyl ligands CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY. VOL 2007(NUMBER 10), 1053-1055 ALDRIDGE, S., JONES, C., GANS-EICHLER, T., STASCH, A., KAYS (NEE COOMBS), D. L., COOMBS, N. D. and WILLOCK, D. J., 2006. Cationic Terminal Borylene Complexes: Structure/Bonding Analysis and [4+1] Cycloaddition Reactivity of a BN Vinylidene Analogue ANGEWANDTE CHEMIE -INTERNATIONAL EDITION IN ENGLISH-. VOL 45(NUMBER 37), 6118-6122 KAYS (NEE COOMBS), D. L., ROSSIN, A., DAY, J. K., OOI, L. L. and ALDRIDGE, S., 2006. Synthetic and reaction chemistry of heteroatom stabilized boryl and cationic borylene complexes DALTON TRANSACTIONS. NUMBER 2, 399-410 BUTTLER, O., AL-FAWAZ, A., KAYS, D. L., DAY, J. K., OOI, L. L. and ALDRIDGE, S., 2006. Halide Abstraction by Na[B{C6H3(CF3)2-3,5}4]: Synthesis and Structural Characterization of the Rhodium(I) Cations [(6-arene)Rh(PPh3)2]+ (Arene = benzene, toluene) ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. VOL 632(NUMBER 14), 2187-2189 KAYS (NEE COOMBS), D. L., DAY, J. K., ALDRIDGE, S., HARRINGTON, R. W. and CLEGG, W., 2006. Cationic Terminal Borylene Complexes: Interconversion of Amino and Alkoxy Borylenes by an Unprecedented Meerwein-Ponndorf Hydride Transfer ANGEWANDTE CHEMIE -INTERNATIONAL EDITION IN ENGLISH-. VOL 45(NUMBER 21), 3513-3516 COOMBS, N. D., BUNN, N. R., KAYS (NéE COOMBS), D. L., DAY, J. K., OOI, L. L. and ALDRIDGE, S., 2006. Substitution, abstraction and addition chemistry of low-coordinate gallium and indium ligand systems INORGANICA CHIMICA ACTA. VOL 359(NUMBER 11), 3693-3698 ALDRIDGE, S. and KAYS, D., 2006. Chemistry of metal-boron double bonds MAIN GROUP CHEMISTRY. VOL 5(NUMBER 4), 223-249 ALDRIDGE, S., KAYS (NEE COOMBS), D. L., AL-FAWAZ, A., JONES, K. M., HORTON, P. N., HURSTHOUSE, M. B., HARRINGTON, R. W. and CLEGG, W., 2006. Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY. NUMBER 24, 2578-2580 BUNN, N. R., ALDRIDGE, S., KAYS, D. L., COOMBS, N. D., ROSSIN, A., WILLOCK, D. J., DAY, J. K., JONES, C. and OOI, L.-L., 2005. Halide Abstraction as a Route to Cationic Transition-Metal Complexes Containing Two-Coordinate Gallium and Indium Ligand Systems ORGANOMETALLICS. VOL 24(NUMB 24), 5891-5900