个人简介
1994年毕业于中南大学应用有机化学专业,获工学硕士学位;2004年毕业于中山大学高分子化学与物理专业,获理学博士学位。2008年在南昌大学材料物理与化学博士后流动站完成博士后研究工作出站;2009-2010年期间赴美国麻省理工学院(MIT)化学系做访问学者,师从2005年诺贝尔化学奖得主理查德·施罗克(Richard R. Schrock)教授。
研究领域
烯烃聚合有机金属催化剂,烯烃催化配位可控聚合,高性能聚烯烃材料,功能聚烯烃锂离子电池隔膜材料,功能聚烯烃燃料电池离子交换膜材料。
近期论文
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1、 Ping Huo, Wanyun Liu, Xiaohui He, Zhenghong Wei, Yiwang Chen. Substituent effects and activation mechanism of norbornene polymerization catalyzed by three-dimensional geometry α-diimine palladium complexes. Polym. Chem., 2014, 5 (4): 1210-1218.
2、 Ping Huo, Wanyun Liu, Xiaohui He, Yiwang Chen. Novel poly(benzonorbornadiene) derivatives prepared by a three-dimensional geometry bimetallic nickel catalyst with good processability for electrospinning. Macromol. Mater. Eng., 2014, DOI: 10.1002/mame.201300193.
3、 Lu Chen, Zhichuan Zhong, Chao Chen, Xiaohui He, Yiwang Chen, N,O-chelating bidentate Ni (II) and Pd (II) complexes for copolymerization of norbornene and norbornene ester, Journal of Organometallic Chemistry, 2014, 752, 100-108.
4、 Xiaohui He, Yan Zheng, Hongli Yao, Yiwang Chen, Defu Chen, Hybrid Network Sulfonated Polynorbornene/Silica Membranes with Enhanced Proton Conductivity by Doped Phosphotungstic Acid. Fuel Cells. 2014, 14(1), 26-34.
5、 Ping Huo, Wanyun Liu, Xiaohui He, Hongming Wang, Yiwang Chen, Nickel (II) Complexes with Three-Dimensional Geometry α-Diimine Ligands: Synthesis and Catalytic Activity toward Copolymerization of Norbornene, Organometallics, 2013, 32, 2291-2299.
6、 Xiaohui He, Meiping Hu, Yiwang Chen, Defu Chen. Hybrid Polyelectrolytes based on Stable Sulfonated Polynorbornene with Higher Proton Conductivity and Lower Methanol Permeability, Journal of Power Sources, 2013, 242, 725-731.
7、 Meiping Hu, Xiaohui He, Yiwang Chen, Defu Chen, Sulfonated Copoly(norbornene)s Bearing Sultone Pendant Groups and Application as Proton Exchange Membranes Candidates, J. Polym. Res. 2012, 19(10), 9977.
8、 Xiaohui He, Yueman Liu, Lu Chen, Yiwang Chen, Defu Chen, Ni(II) and Pd(II) Complexes Bearing Benzocyclohexan-ketoarylimine for Copolymerization of Norbornene with 5-Norbornene-2-Carboxylic Ester, J. Polym. Sci. Part A: Polym. Chem. 2012, 50 (22), 4695–4704.
9、 Xiaohui He, Kaiti Wang, Yiwang Chen, Bin Yuan. Surface-Initiated Addition Polymerization of Norbornene by a Pd(II) Catalyst Bearing Acetylacetone Ligand on the Glass Slide. Applied Surface Science, 2012, 258(8), 3779-3784.
10、 Yongfen Tong, Lie Chen, Yiwang Chen, Xiaohui He, Enhanced Conductivity of Novel Star Branched Liquid Crystalline Copolymer Based on Poly(ethylene oxide) for Solid Polymer Electrolytes, Applied Surface Science, 2012, 258, 10095-10103.
11、 Bin Yuan, Xiaohui He, Yiwang Chen, Kaiti Wang. Preparation of Nanosilica/Polynorbornene Nanocomposite by Covalently Immobilized Silica-Supported Acetylacetonate Palladium(II) Dichloride Catalyst. macromolecules chemistry and physics, 2011, 212, 2378-2388.
12、 Kaiti Wang, Xiaohui He, Yiwang Chen, Weihua Zhou, Yueman Liu. Ni(II) and Pd(II) Complexes Bearing Novel Bis(β-ketoamino) Ligand and Their Catalytic Activity toward Copolymerization of Norbornene and 5-Norbornene-2-yl Acetate Combined with B(C6F5)3. J. Polym. Sci., Part A: Polym. Chem. 2011, 49(15), 3304–3313.
13、 Yuepeng Xing, Yiwang Chen, Xiaohui He. Copolymerization of Norbornene with Methoxycarbonylnorbornene Catalyzed by Ni{CF3C(O)CHC[N(naphthyl)]CH3}2/B(C6F5)3 Catalytic System and Good Processability for Dry/Wet Phase Inversion and Electrospinning Technique. J. Polym. Sci., Part A: Polym. Chem. 2011, 49(20), 4425-4432.
14、 Fuping He, Yiwang Chen, Xiaohui He, Muqing Chen, Weihua Zhou, Qing Wu. Copolymerization of Norbornene and 5-norbornene-2-yl acetate Using Novel Bis(β-ketoamino)Ni(II)/B(C6F5)3/AlEt3 Catalyst System. J. Polym. Sci., Part A: Polym. Chem. 2009, 47(16)3990-4000.
15、 Xiaohui He, Yiwang Chen, Yongming Liu, Shuxian Yu, Sanguo Hong, Qing Wu, Addition polymerization of norbornene using bis(β-ketoamino)nickel(II)/tris(pentafluorophenyl)borane catalytic systems, Journal of Polymer Science Part A: Polymer Chemistry, 2007, 45(20):4733-4743.
16、 Xiaohui He, Qing Wu, Polymerization of methyl methacrylate using bis(β-ketoamino)nickel(II)-MAO catalytic systems, Applied Organometallic Chemistry, 2006, 20 (4), 264-271.
17、 Xiaohui He, Yingzheng Yao, Xiang Luo, Zhang Ling, Qing Wu, Ni(II) Complexes Bearing N,O-Chelate Ligands: Synthesis, Solid-Structure Characterization and Reactivity toward the Polymerization of Polar Monomer, Organometallics, 2003, 22 (24), 4952-4957.