Doherty, Simon - Newcastle University

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1994-1995 Lecturer in Inorganic Chemistry University of Wales, Swansea 1995-2001 Senior Lecturer in Inorganic Chemistry, University of Newcastle 2001-2004 Reader in Inorganic Chemistry, Queen’s University of Belfast 2004- Senior Lecturer in Inorganic Chemistry, University of Newcastle

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Geier SJ, Vogels CM, Daley EN, Decken A, Doherty S, Westcott SA. The Phosphinoboration of N-Heterocycles. J. Am. Chem. Soc 2016. Submitted. Doherty S, Knight JG, Backhouse T, Abood E, Alshaikh H, Fairlamb IJS, Bourne RA, Chamberlain TW, Stones R. Highly Efficient Aqueous Phase Chemoselective Hydrogenation of α,β-Unsaturated Aldehydes, Ketones, Esters and Nitriles Catalysed by Palladium Nanoparticles Stabilised with Phosphine-Decorated Polymer Immobilised Ionic Liquids. Green Chemistry 2017, epub ahead of print. Doherty S, Knight JG, Carroll MA, Clemmet AR, Ellison JR, Backhouse T, Holmes N, Bourne RA. Selective and Highly Efficient Hydrogen Peroxide-Mediated Oxidation of Sulfides in Batch and Continuous Flow using Styrene-Based Polymer Immobilised Ionic Liquid Phase Supported Peroxotungstates. RSC Advances 2016, 6, 73118-73131. Doherty S, Knight JG, Perry DO, Ward NAB, Bittner DM, McFarlane W, Wills C, Probert MR. Triaryl-Like MONO-, BIS- and TRISKITPHOS Phosphines: Synthesis, Solution NMR Studies and a Comparison in Gold-Catalysed Carbon-Heteroatom Bond Forming 5-Exo-Dig and 6-Endo-Dig Cyclizations. Organometallics 2016, 35(9), 1265-1278. Daley EN, Vogels CM, Geier SJ, Decken A, Doherty S, Westcott SA. The Phosphinoboration Reaction. Angewandte Chemie International Edition 2015, 54(7), 2121-2125. Doherty S, Knight JG, Carroll MA, Ellison JR, Hobson SJ, Stevens S, Hardacre C, Goodrich P. Efficient and selective hydrogen peroxide-mediated oxidation of sulfides in batch and segmented and continuous flow using a peroxometalate-based polymer immobilised ionic liquid phase catalyst. Green Chemistry 2015, 17(3), 1559-1571. Doherty S, Knight JG, Ward NAB, Perry DO, Bittner DM, Probert MR, Westcott SA. Palladium-Catalyzed Suzuki–Miyaura Cross-Couplings with 2-Diethylphosphonato-Substituted Aryl- and Naphthylboronate Esters as the Nucleophilic Partner: A Complementary Approach to the Synthesis of Biaryl Monophosphonates. Organometallics 2014, 33(19), 5209-5219. Doherty S. Homogeneous Catalysis in Ionic Liquids. In: Hardacre, C; Parvulescu, V, ed. Catalysis in Ionic Liquids: From Catalyst Synthesis to Application. Royal Society of Chemistry, 2014, pp.44-308. Doherty S, Knight JG, Ellison JR, Goodrich P, Hall L, Hardacre C, Muldoon M, Ribeiro A, Afonso C, Park S, Lourençoc MJ, Davey P. An efficient Cu(II)-bis(oxazoline)-based polymer immobilised ionic liquid phase catalyst for asymmetric carbon–carbon bond formation. Green Chemistry 2014, 16(3), 1470-1479. Doherty S, Knight JG, Ward NAB, Bittner DM, Wills C, McFarlane W, Clegg W, Harrington RW. Electron-Rich Trialkyl-Type Dihydro-KITPHOS Monophosphines: Efficient Ligands for Palladium-Catalyzed Suzuki–Miyaura Cross-Coupling. Comparison with Their Biaryl-Like KITPHOS Monophosphine Counterparts. Organometallics 2013, 32(6), 1773-1788. Doherty S, Smyth C. Synthesis and Resolution of the Biaryl-Like Diphosphine (S)-Me2-CATPHOS, Preparation of a Derived Rhodium Precatalyst and Applications in Asymmetric Hydrogenation. Nature Protocols 2012, 7, 1884-1896. Doherty S, Smyth CH, Knight JG, Hashmi SAK. Synthesis of an Electron-Rich KITPHOS Monophosphine, Preparation of Derived Metal Complexes and Applications in Catalysis. Nature Protocols 2012, 7, 1870-1883. Doherty S, Knight JG, Mehdi-Zodeh H. Asymmetric carbonyl-Ene and Friedel-Crafts reactions catalyzed by Lewis acid platinum group metal complexes of the enantiopure atropisomeric biaryl-like diphosphine (S)-Me2-CATPHOS: a comparison with BINAP. Tetrahedron: Asymmetry 2012, 23(3-4), 209-216. Doherty S, Knight JG, Ellison J, Weekes D, Harrington RW, Hardacre C, Manyer H. An efficient recyclable peroxometalate-based polymer-immobilised ionic liquid phase (PIILP) catalyst for hydrogen peroxide-mediated oxidation. Green Chemistry 2012, 14(4), 925-929. Hashmi ASK, Loos A, Doherty S, Knight JGK, Robson KJ, Rominger F. Gold Catalyzed Cyclizations: A Comparative Study Between ortho,ortho'-Substituted KITPHOS Monophosphines and their Biaryl Monophosphine Counterpart SPHOS. Advanced Synthesis & Catalysis 2011, 353(5), 749-759. Doherty S, Knight JG, Addyman CR, Smyth CH, Ward NAB, Harrington RW. Ruthenium Complexes of κ(P)- and κ(P)-η6-Coordinated KITPHOS Monophosphines: Efficient Catalysts for the Direct Ortho Arylation of 2-Phenylpyridine and N-Phenylpyrazole with Aryl Chlorides. Organometallics 2011, 30(21), 6010-6016. Doherty S, Knight JG, Hashmi ASK, Smyth CS, Ward NAB, Robson KJ, Tweedley S, Harrington RW, Clegg W. Efficient Cycloisomerisation of Propargyl Amides by Electrophilic Gold(I) Complexes of KITPHOS Monophosphines: A Comparative Study. Organometallics 2010, 29(18), 4139-4147. Doherty S, Knight JG, McGrady JP, Ferguson AM, Ward NAB, Harrington RW, Clegg W. ortho,ortho'-Substituted KITPHOS Monophosphines: Highly Efficient Ligands for Palladium-Catalyzed C‒C and C‒N Bond Formation. Advanced Synthesis & Catalysis 2010, 352(1), 201-211. Doherty S, Smyth CH, Harriman A, Harrington RW, Clegg W. Can a Butadiene-Based Architecture Compete with its Biaryl Counterpart in Asymmetric Catalysis? Enantiopure Me-CATPHOS, a Remarkably Efficient Ligand for Asymmetric Hydrogenation. Organometallics 2009, 28(3), 888-895. Hashmi ASK, Loos A, Littmann A, Braun I, Knight J, Doherty S, Rominger F. Gold(I) Complexes of KITPHOS Monophosphines: Efficient Cycloisomerisation Catalysts. Advanced Synthesis & Catalysis 2009, 351(4), 576-582. Doherty S, Knight JG, Bell AL, El-Menabawey S, Westcott S. Rhodium Complexes of (R)-Me-CATPHOS and (R)-(S)-JOSIPHOS: Highly Enantioselective Catalysts for the Asymmetric Hydrogenation of (E)- and (Z)-beta-Aryl-beta-(Enamido)phosphonates. Tetrahedron: Asymmetry 2009, 20(12), 1437-1444. Doherty S, Smyth CH, Harrington RW, Clegg W. Synthesis of Biaryl Diphosphines via a Stepwise Regioselective Double Diels-Alder Cycloaddition Elimination Sequence: Efficient Ligands for the Palladium-Catalyzed Amination of Aromatic Bromides. Organometallics 2009, 28(17), 5273-5276.