个人简介

BS Summa Cum Laude, Hope College, 1987 PhD University of Minnesota, 1993 NSF Postdoctoral Research Fellow, Northwestern University, 1992-1995 Assistant Professor of Chemistry, Virginia Tech, 1995-2001 Associate Professor of Chemistry, Virginia Tech, 2001-present

研究领域

Polymer/Organometallic

Fluoropolymers represent a rapidly growing area within the broader field of synthetic polymer chemistry. Our group makes highly fluorinated aromatic polymers using novel synthetic methods that we develop in our laboratories. These polymers have truly unique structure and are expected to provide a range of materials with useful physical and chemical properties. Current projects include: Synthetic methodology for monomers, Polymer synthesis and characterization, and Fluorous nanomaterials. Organometallic chemistry is the study of metal-carbon bonds and is therefore an "interdisciplinary" blend of organic chemistry and inorganic chemistry. Organometallic compounds have important applications in catalysis and in materials chemistry. We are specifically interested in the chemistry of metallocenes and related complexes. Current research programs include: The design of electron-withdrawing cyclopentadienyl ligands, Activation and manipulation of carbon-fluorine bonds, and The use of 19F NMR spectroscopy to study organometallic reaction mechanisms. As one can see, our polymer synthesis and organometallic chemistry projects are bound together by a common theme: The effects of the element fluorine on structure, properties, and chemical reactivity.

近期论文

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"Synthesis and Structure of Piano Stool Complexes Derived from the Tetrakis(pentafluorophenyl)cyclopentadienyl Ligand." M. P. Thornberry, C. Slebodnick, P. A. Deck, and F. R. Fronczek. Organometallics 2001, 20, 920-926. "Step-Growth Polymers Derived from Indene and Decafluorobiphenyl. A New Polymerization Mode for Indene." P. A. Deck and C. R. Maiorana." Macromolecules 2001, 34, 9-13. "Structural and Electronic Effects of Pentafluorophenyl Substituents on Cyclopentadienyl Complexes of Fe, Co, Mn, and Re." M. P. Thornberry, C. Slebodnick, P. A. Deck, and F. R. Fronczek. Organometallics 2000, 19, 5352-5369. "Perfluoroaryl-substituted Cyclopentadienyl Complexes of Transition Metals." P. A. Deck. Coordination Chemistry Reviews 2006, 250, 1032-1055. "Preparation of Ferrocenes with High Fluorous-Phase Affinities." W. G. Hollis, Jr., M. G. Poferl, M. D. Wolter, and C. Slebodnick. Journal of Fluorine Chemistry, 2008, 129, 119-124.