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High-Pressure In Situ NMR Methods for the Study of Reaction Kinetics in Homogeneous Catalysis The inter-conversions of platinum carbonyl dianions [Pt3(CO)6]n2- (n = 2-5) in THF and acetonitrile. A combined in situ FTIR specstrocopic and BTEM study leading to the characterization of the new [H4-xPt15(CO)19]x- (x = 3, 4) cluster A rare example of a di-cationic hydrido carbonyl tetra-nuclear cluster, [H2Rh2Pt2(CO)7(PPh3)3]2+ The synthesis of, and characterization of the dynamic processes occurring in Pd(II) chelate complexes of 2-pyridyldiphenylphosphine The loss of CO from [Rh12(µ12-Sn)(CO)27]4-: Synthesis, Spectroscopic and Structural Characterization of the Electron-deficient, Icosahedral [Rh12(µ12-Sn)(CO)25]4- and [Rh12(µ12-Sn)(CO)26]4- Tetra-anionsThe loss of CO from [Rh12(µ12-Sn)(CO)27]4-: Synthesis, Spectroscopic and Structural Characterization of the Electron-deficient, Icosahedral [Rh12(µ12-Sn)(CO)25]4- and [Rh12(µ12-Sn)(CO)26]4- Tetra-anions Multinuclear NMR studies of the products resulting from the reaction of pyridine or 2,2′-bipyridine with [Rh 4 (CO) 12 ] The reaction of mixtures of [Rh4(CO)12] and triphenylphosphite with carbon monoxide or syngas as studied by high-resolution, high-pressure NMR spectroscopy A novel heterobidentate chiral phosphine and its coordination chemistry in transition metal clusters Sn-centred icosahedral Rh carbonyl clusters: synthesis and structural characterization and 13C–{103Rh} HMQC NMR studies CO fluxionality in Rh4(CO)12 and Rh6(CO)16 The mechanism of the hydroalkoxycarbonylation of ethene and alkene-CO copolymerization catalyzed by Pd-II-diphosphine cations 'Comparison of theoretical studies and experimental results in the oxidative addition of alkyl or aryl halides to metal complexes' Catalytic mechanisms from spectroscopic measurements "Methanolysis of Acylpalladium (II) complexes relevant to CO/Ethene coupling reaction" “An Investigation of palladium-(2-pyridyldiphenylphosphine) complexes as possible precursors in alkyne carbonylation.” 174."The Application of HMQC Spectroscopy to the Observation of the Metal resonance in polymetallic Compounds; the Effect of Multiple-Metal Spin Transitions" Methanolysis of acyl–Pd( ii ) complexes relevant to CO/ethene coupling reactions Synthesis and structural characterization of two novel heterometallic clusters: [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppm)2] The Complete Delineation of the Initiation, Propagation, and Termination Steps of the Carbomethoxy Cycle for the Carboalkoxylation of Ethene by Pd–Diphosphane Catalysts "Elucidation of palladium carbomethoxy catalytic cycle in the Pd-catalysed CO/ ethylene reaction" "NMR, X-ray Crystallographic Studies and DFT Calculations on Products resulting from the Oxidative Addition of Rhodium(I)/beta-diketonate Complexes with Methyl Iodide." "Rhodium Complexes containing either the hybrid ligand Ph2PNHC(O)Me, or anion, [Ph2PN----C(---O)Me]-" "The Structure and dynamic behaviour of disubstituted derivatives Rh6(CO)16 containing bidentate phosphorus ligands. Structure and dynamic behaviour" “Spectroscopic studies on catalytic intermediates involved in the methoxycarbonylation of ethylene.” “The Structure and Dynamic Behaviour of Disubstituted Derivatives of [Rh6(CO)16] Containing Heterobidentate Ligands”