个人简介

Sara Kyne is a Lecturer in the School of Chemistry. Her research interests include organic and organometallic chemistry, primarily focused on developing Earth abundant metal catalysts for environmentally responsible synthetic and industrial processes. Particular emphasis is placed on understanding reaction mechanisms in modern catalytic processes. Department Responsibilities Module Leader for Practical Chemistry 1.1 — Fundamental Laboratory Techniques (CHM1005M) Module Leader for Core Chemistry 2.2 — Chemistry Of Activated Systems And Radicals (CHM2003M) Subject Specialism Sustainable chemical synthesis Qualifications PhD (Chemistry) — The University of Melbourne, 2010 B Sci (Honours) — The University of Melbourne, 2005 B Biomed Sci (Chemistry and Pharmacology) — The University of Melbourne, 2004 Awards Marie Curie Intra European Fellowship — European Commission Research Executive Agency, 2012 Monica Elizabeth Reum Memorial Prize — The University of Melbourne, 2010 Melbourne Research Scholarship — The University of Melbourne, 2006 Professional Affiliations Higher Education Academy — Fellow American Chemical Society — Member Royal Society of Chemistry — Member SCI — Member

研究领域

Cobalt complexes: Understanding changes in redox potential — University of Lincoln Undergraduate Research Opportunities Scheme in 2016 Selective (bio)catalytic conversion of Lincolnshire biomass — University of Lincoln Research Investment Fund in 2016 Biological protection of polysaccharides for selective modification — IBCarb Network in 2016 Mechanistic development of cobalt photoredox catalysts — Royal Society of Chemistry in 2016 Mechanistic development of cobalt photoredox catalysts — National Service for Computational Chemistry Software in 2015

Biomass valorisation Catalysis Environmental sustainability Organic chemistry Organometallic chemistry

近期论文

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Kyne, Sara H. and Camp, Jason E. (2017) Use of monosaccharides in metal-catalyzed coupling reactions. ACS Sustainable Chemistry & Engineering, 5 (1). pp. 41-48. ISSN: 2168-0485 Kyne, Sara H. and Lévêque, Christophe and Zheng, Shiwen and Fensterbank, Louis and Jutand, Anny and Ollivier, Cyril (2016) Iron(II) catalyzed reductive radical cyclization reactions of bromoacetals in the presence of NaBH4: optimization studies and mechanistic insights. Tetrahedron, 72 (48). pp. 7727 - 7737. ISSN: 0040-4020 Kyne, S. H. and Schiesser, C.H. (2014) N,S-Dimethyldithiocarbamyl oxalates as precursors for determining kinetic parameters for oxyacyl radicals. Chemical Communications, 50 (81). pp. 12040-12042. ISSN: 1359-7345 Aubert, C. and Barbazanges, M. and Jutand, A. and Kyne, S. H. and Ollivier, C. and Fensterbank, L. (2014) Organometallic catalysis for applications in radical chemistry and asymmetric synthesis. Pure and Applied Chemistry, 86 (3). pp. 273-281. ISSN: 0033-4545 MacDougall, P .E. and Aitken, H. M. and Scammells, P. J. and Kavanagh, Y. and Kyne, S. H. and Schiesser, C. H. (2012) 7-Selenabicyclo2.2.1heptane. Chemical Communications, 48 (73). pp. 9126-9128. ISSN: 1359-7345 Kyne, Sara and Aitken, Hesther M. and Horvat, Sonia M. and Lin, Ching Yeh and Coote, Michelle L. and Schiesser, Carl H. (2012) Homolytic substitution chemistry: from James Franz to antihypertensives. ChemInform, 43 (30). pp. 927-928. ISSN: 0931-7597 Kyne, S. H. and Miles, J. A. L. and Percy, J. M. and Singh, K. (2012) Executing and rationalizing the synthesis of a difluorinated analogue of a ring-expanded calystegine B2. Journal of Organic Chemistry, 77 (2). pp. 991-998. ISSN: 0022-3263 Neves, A. C. and Aitken, H. M. and Kyne, S. H. and Fensterbank, L. and Lacote, E. and Malacria, M. and Ollivier, C. and Schiesser, C. H. (2012) Intramolecular homolytic substitution of seleninates: a computational study. Tetrahedron, 68 (1). pp. 323-328. ISSN: 0040-4020 Nelson, D. J. and Ashworth, I. W. and Hillier, I. H. and Kyne, S. H. and Pandian, S. and Parkinson, J. A. and Percy, J. M. and Rinaudo, G. and Vincent, M. A. (2011) Why is RCM favoured over dimerisation? Predicting and estimating thermodynamic effective molarities by solution experiments and electronic structure calculations. Chemistry - A European Journal, 17 (46). pp. 13087-13094. ISSN: 0947-6539 Kyne, Sara H. and Percy, Jonathon M. and Pullin, Robert D. C. and Redmond, Joanna M. and Wilson, Peter G. (2011) One-pot near-ambient temperature syntheses of aryl(difluoroenol) derivatives from trifluoroethanol. Organic and Biomolecular Chemistry, 9 (24). pp. 8328-8339. ISSN: 14770520 Kyne, Sara H. and Aitken, Heather M. and Schiesser, Carl H. and Lacote, Emmanuel and Malacria, Max and Ollivier, Cyril and Fensterbank, Louis (2011) Intramolecular homolytic substitution of sulfinates and sulfinamides: a computational study. Organic and Biomolecular Chemistry, 9 (9). pp. 3331-3337. ISSN: 1477-0520 Kyne, S. H. and Schiesser, C. H. and Matsubara, H. (2011) An ab initio and DFT study of radical addition reactions of imidoyl and thioyl radicals to methanimine. Organic and Biomolecular Chemistry, 9 (9). pp. 3217-3224. ISSN: 1477-0520 Kyne, S. H. and Lin, C. Y. and Ryu, I. and Coote, M. L. and Schiesser, C. H. (2010) First determination of the rate constant for ring-closure of an azahexenoyl radical: 6-aza-7-ethyl-5-hexenoyl. Chemical Communications, 46 (35). pp. 6521-6523. ISSN: 1359-7345 Kyne, Sara and Schiesser, C. H. (2009) Ab initio studies of carbonyl radical additions to hydrazone systems. Australian Journal of Chemistry, 62 (7). pp. 728-733. ISSN: 0004-9425 Kyne, S. H. and Schiesser, C. H. and Matsubara, H. (2008) Multiorbital interactions during acyl radical addition reactions involving imines and electron-rich olefins. Journal of Organic Chemistry, 73 (2). pp. 427-434. ISSN: 0022-3263 Kyne, Sara and Schiesser, Carl H. and Matsubara, Hiroshi (2007) Multi-component orbital interactions during oxyacyl radical addition reactions involving imines and electron-rich olefins. Organic & Biomolecular Chemistry, 5 (24). pp. 3938-3943. ISSN: 1477-0520