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C-H Activation Luminescent Complexes

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Room-temperature cyclometallation of amines, imines and oxazolines with [MCl2Cp* ]2 (M = Rh, Ir) and [RuCl2(p- cymene)]2 D.L. Davies, O. Al-Duaij, J. Fawcett, M. Giardiello, S.T. Hilton, and D.R. Russell, Dalton Trans., 2003, 4132-4138. Computational Study of the Mechanism of Cyclometallation by Palladium Acetate D.L. Davies, S.M.A. Donald, and S.A. Macgregor, J. Amer. Chem. Soc., 2005, 127, 13754-55. Electrophilic C-H Activation at {Cp*Ir}: Ancillary-Ligand Control of the Mechanism of C-H Activation D.L. Davies, S.M.A. Donald, O. Al-Duaij, S.A. Macgregor, and M. Polleth, J. Am. Chem. Soc., 2006, 128, 4210-4211. Mechanisms of C-H bond activation: rich synergy between computation and experiment: Y. Boutadla, D. L. Davies, S. A. Macgregor and A. I. Poblador-Bahamonde, Dalton Trans, 2009, 5820-5831. Mechanistic Study of Acetate-Assisted C-H Activation of 2-Substituted Pyridines with [MCl2CP*](2) (M = Rh, Ir) and [RuCl2(p-cymene)](2). Y. Boutadla, O. Al-Duaij, D.L. Davies, G.A. Griffith, and K. Singh, Organometallics, 2009, 28, 433-440. The Scope of Ambiphilic Acetate-Assisted Cyclometallation with Half-Sandwich Complexes of Iridium, Rhodium and Ruthenium: Y. Boutadla, D. L. Davies, R. C. Jones and K. Singh, Chem. Eur. J., 2011, 17, 3438-3448. Alkyne insertion into cyclometallated pyrazole and imine complexes of iridium, rhodium and ruthenium; relevance to catalytic formation of carbo- and heterocycles: Y. Boutadla, D. L. Davies, O. Al-Duaij, J. Fawcett, R. C. Jones and K. Singh, Dalton Trans, 2010, 39, 10447-10457. Reactions of Cyclometalated Oxazoline Half-Sandwich Complexes of Iridium and Ruthenium with Alkynes and CO: D. L. Davies, O. Al-Duaij, J. Fawcett and K. Singh, Organometallics, 2010 29, 1413-1420. Tuning emission wavelength and redox properties through position of the substituent in iridium(III) cyclometallated complexes: D. L. Davies, M. P. Lowe, K. S. Ryder, K. Singh and S. Singh, Dalton Trans, 2011 40, 1028-1030. Luminescent iridium complexes for detection of molybdate: C. E. Castillo, D. L. Davies, A.-K. D. Klair, K. Singh and S. Singh, Dalton Trans, 2012, 41, 628-635.

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