Miyake, Garret - Colorado State University

个人简介

B.S.: Pacific University Ph.D.: Colorado State University Postdoctoral Researcher: California Institute of Technology Awards and Honors: Finalist Blavatnik National Awards for Young Scientists (2024) Finalist Blavatnik National Awards for Young Scientists (2023) Dr. Robert Williams Professorship in Organic Chemistry (2021) ACS Division of Polymeric Materials: Science and Engineering Journal of Polymer Science Innovation Award (2021) Colorado State University Provost Research Scholar Award (2021) Colorado State University College of Natural Sciences Faculty Excellence in Graduate Teaching and/or Mentoring Award (2020) Camille Dreyfus Teacher-Scholar Award (2019) ACS Division of Polymer Chemistry POLY Fellow (2018) Cottrell Scholar Award (2018) Thieme Chemistry Journal Award (2018) ACS Division of Polymer Chemistry Herman F. Mark Young Scholar Award (2017) Sloan Research Fellow (2017) Camille and Henry Dreyfus Environmental Chemistry Fellow ACS Division of Polymer Chemistry AkzoNobel Award for Outstanding Graduate Research in Polymer Chemistry (2012)

研究领域

Our research interests are in the fields of catalysis, photochemistry, polymer chemistry, and materials science. A major focus of our research program is the design of photoredox catalysts for the application in organocatalyzed atom transfer radical polymerization (O-ATRP) and more recently small molecule synthesis. We are also interested in applications of self-assembled block copolymer nanostructures as photonic crystals.

近期论文

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Liu, K.; Battson, M.; Zhitao H.; Zhao Y.; Rettner E.; Miscall J.; Rorrer N.; Miyake, G. M.; "Upcycling polynorbornene derivatives into chemically recyclable multiblock linear and thermoset plastics" Angew. Chem. Int. Ed., DOI: 10.1002/anie.202423111 Liu, X.; Sau, A.; Green A. R.; Popescu M. V.; Pompetti, N. F.; Li, Y.; Zhao, Y.; Paton, R. S.; Damrauer N. H.; Miyake, G. M.; "Photocatalytic C-F bond activation in small molecules and polyfluoroalkyl substances" Nature, DOI:10.1038/s41586-024-08327-7 Liu, X.; Hu, Z.; Portela, B. S.; Rettner, E.; Pineda A.; Miscall, J.; Krummel, A. T.; Paton, R. S.; Miyake, G. M.; "Photooxidation of Polyolefins to Produce Materials with In-chain Ketones and Improved Materials Properties" Angew. Chem. Int. Ed., DOI: 10.1002/anie.202418411 Zhao, Y.; Rettner, E.; Battson, M.; Hu Z.; Miscall, J.; Rorrer, N.; Miyake, G. M.; "Tailoring the Properties of Chemically Recyclable Polyethylene-Like Multiblock Polymers By Modulating the Branch Structure" Angew. Chem. Int. Ed., DOI: 10.1002/anie.202415707 Liu, X.; Portela, B. S.; Wiedenbeck, A.; Chrisman, C. H.; Paton, R. S.; Miyake, G. M.; "Organocatalyzed Carbonylation of Alkyl Halides Driven by Visible Light" Angew. Chem. Int. Ed., DOI: 10.1002/anie.202410928 Hu, Z.; Bernsten, S. N.; Shi, C.; Sangroniz, A.; Chen, E. Y.-X.; Miyake, G. M.; "Terpenoid-based high-performance polyester with tacticity-independent crystallinity and chemical circularity" Chem, DOI: 10.1016/j.chempr.2024.05.024 Sau A.; Pompetti,, N. F.; Green, A. R.; Popescu, M. V.; Paton, R. S; Miyake, G. M.; Damrauer, N. H. "Mechanistic Investigation of a Photocatalyst Model Reveals Function by Perylene-Like Closed Shell Super-Photoreductant Capable of Reducing Unactivated Arenes" ACS Catal, DOI: 10.1021/acscatal.3c05386 Zhao, Y.; Rettner, E. M.; Harry, K.L.; Hu, Z.; Rorrer, N.; Miyake, G. M.; "Chemically recyclable polyolefin-like multiblock polymers" Science, DOI: 10.1126/science.adh3353 Puffer, K.O; Corbin, D.A.; Miyake, G. M.; "Impact of Alkyl Core Substitution Kinetics in Diaryl Dihydrophenazine Photoredox Catalysts on Properties and Performance in O-ATRP" ACS Catal., DOI: 10.1021/acscatal.3c04060 Lan, Y.; Xu, J.; Lim, C.; Miyake, G. M.; and Liu, B.; "Visible-Light-Promoted C-S Cross-Coupling Reaction for Synthesis of Aromatic Thioethers" Org.Synth, DOI: 10.15227/orgsyn.100.0234 Chrisman, C.; Kudisch, M.; Puffer, K.; Stewart, T.; Lamb, Y., Lim, C.; Escobar, R., Thordarson, P., Johannes, J.; and Miyake, G. M.; "Halide Noninnocence and Direct Photoreduction of Ni(II) Enables Coupling of Aryl Chlorides in Dual Catalytic, Carbon–Heteroatom Bond-Forming Reactions" J. Am. Chem. Soc., DOI: 10.1021/jacs.3c02784 Delesky, E.; Garcia, L.; Lobo, A.; Mikofsky, R.; Dowdy, N.; Wallat, J.; Miyake. G. M.; and Srubar, W. V. "Bioinspired Threonine-Based Polymers with Potent Ice Recrystallization Inhibition Activity" ACS Appl. Polym. Mater., DOI: 10.1021/acsapm.2c01496 Chism. K; Corbin, D.; and Miyake. G. M.; "Removal of photoredox catalysts from polymers synthesized by organocatalyzed atom transfer radical polymerization" J. Polym. Sci., DOI: 10.1002/pol.20220320 Corbin, D.; Cremer, C.; Newell, B.; Patureau, F.; Puffer, K.; and Miyake, G. M.; "Effects of the Chalcogenide Identity in N-Aryl Phenochalcogenazine Photoredox Catalysts" Chem. Cat. Chem., DOI: 10.1002/cctc.202200485 Kientz, M.; Lowe, G.; McCarthy, B.; Miyake, G. M.; Bonin, J.; and Robert, M.; "Phenoxazine-Sensitized CO2-to-CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties-Catalytic Performance Study" Chem. Photo. Chem., DOI: 10.1002/cptc.202200009 Chenyu, W.; Corrigan, N.; Lim, C.; Liu, W.; Boyer, C.; and Miyake, G. M.; "Rational Design of Photocatalysts for Controlled Polymerization: Effect of Structures on Photocatalytic Activities" Chem. Rev., DOI: 10.1021/acs.chemrev.1c00409 Corbin, D. A.; and Miyake, G. M.; "Photoinduced Organocatalyzed Atom Transfer Radical Polymerization (O-ATRP): Precision Polymer Synthesis Using Organic Photoredox Catalysis" Chem. Rev., DOI: 10.1021/acs.chemrev.1c00603 Price, M. J.; Puffer, K. O.; Kudisch, M.; Knies, D.; and Miyake, G. M.; "Structure–property relationships of core-substituted diaryl dihydrophenazine organic photoredox catalysts and their application in O-ATRP" Polym. Chem., DOI: 10.1039/D1PY01060C Folkman, S. J.; Finke, R. G.; Galán-Mascarós, J. R.; and Miyake, G. M.; "Carbon-Electrode-Mediated Electrochemical Synthesis of Hypervalent Iodine Reagents Using Water as the O-Atom Source" ACS Sus. Chem. Eng., DOI: 10.1021/acssuschemeng.1c01315 Mensch, T.; Delesky, E. A.; Learsch, R.; Foster, K.; Yeturu, S. K.; Srubar, W.; and Miyake, G. M.; "Mechanical evaluation of 3D printed biomimetic non-Euclidean saddle geometries mimicking the mantis shrimp" Bioinspir. Biomim., DOI: 10.1088/1748-3190/ac0a33 Corbin, D. A.; Puffer, K. O.; Chism, K. A.; Cole, J. P.; Theriot, J. C.; McCarthy, B. G.; Buss, B. L.; Lim, C. H.; Lincoln, S. R.; Newell, B. S.; Miyake, G. M.; "Radical Addition to N,N-Diaryl Dihydrophenazine Photoredox Catalysts and Implications in Photoinduced Organocatalyzed Atom Transfer Radical Polymerization" Macromolecules, DOI: 10.1021/acs.macromol.1c00501 Corbin, D. A.; McCarthy, B. G.; van de Lindt, Z.; Miyake, G. M.; "Radical Cations of Phenoxazine and Dihydrophenazine Photoredox Catalysts and Their Role as Deactivators in Organocatalyzed Atom Transfer Radical Polymerization" Macromolecules, DOI: 10.1021/acs.macromol.1c00640 Lattke, Y. M.; Corbin, D. A.; Sartor, S. M.; McCarthy, B. G.; Miyake, G. M.; Damrauer, N. H.; "Interrogation of O-ATRP Activation Conducted by Singlet and Triplet Excited States of Phenoxazine Photocatalysts" J. Phys. Chem. A, DOI: 10.1021/acs.jpca.1c00855 Swisher, N. A.; Corbin, D. A.; Miyake, G. M.; "Synthesis, Characterization, and Reactivity of N-Alkyl Phenoxazines in Organocatalyzed Atom Transfer Radical Polymerization" ACS Macro Lett., DOI: 10.1021/acsmacrolett.1c00055 Foster, K. E. O.; Jones, R.; Miyake, G. M.; Srubar, W. V.; "Mechanics, optics, and thermodynamics of water transport in chemically modified transparent wood composites" Compos. Sci. Technol., DOI: 10.1016/j.compscitech.2021.108737 McCarthy, B. G.; Sartor, S. M.; Cole, J. P.; Damrauer, N. H.; Miyake, G. M.; "Solvent Effects and Side Reactions in Organocatalyzed Atom Transfer Radical Polymerization for Enabling the Controlled Polymerization of Acrylates Catalyzed by Diaryl Dihydrophenazines" Macromolecules, DOI: 10.1021/acs.macromol.0c02245 Boyle, B. M.; Collins, J. L.; Mensch, T. E.; Ryan, M. D.; Newell, B. S.; Miyake, G. M.; "Impact of backbone composition on homopolymer dynamics and brush block copolymer self-assembly" Polym. Chem., DOI: 10.1039/D0PY01007C Chen, D. F.; Bernsten, S; Miyake, G. M.; "Organocatalyzed Photoredox Radical Ring-Opening Polymerization of Functionalized Vinylcyclopropanes" Macromolecules, DOI: 10.1021/acs.macromol.0c01367 Cole, J. P.; Chen, D. F.; Kudisch, M.; Pearson, R. M.; Lim, C. H.; Miyake, G. M.; "Organocatalyzed Birch Reduction Driven by Visible Light" J. Am. Chem. Soc., DOI: 10.1021/jacs.0c05899. Corbin, D.A.; McCarthy, B. G.; Miyake, G. M.; "Impacts of Performing Electrolysis During Organocatalyzed Atom Transfer Radical Polymerization" Polym. Chem., DOI: 10.1039/D0PY00643B Abera, G.; Woldeyes, B.; Demash, H. D.; Miyake, G. M.; "The effect of plasticizers on thermoplastic starch films developed from the indigenous Ethiopian tuber crop Anchote (Coccinia abyssinica) starch" Int. J. Biol. Macromol., DOI: 10.1016/j.ijbiomac.2020.03.218 Liu, B.; Elder, Z. W.; Miyake, G. M.; "Scalable and Phosphine-Free Conversion of Alcohols to Carbon-Heteroatom Bonds through Blue-Light Promoted Iodination Reaction" J. Org. Chem., DOI: 10.1021/acs.joc.9b03373 Chen, D. F.; Chrisman, C. H.; Miyake, G. M.; "Bromine Radical Catalysis by Energy Transfer Photosensitization" ACS Catal., DOI: 10.1021/acscatal.0c00281 Sartor, S. M.; Chrisman, C. H.; Pearson, R. M.; Miyake, G. M.; Damrauer, N. H.; "Designing High Triplet Yield Phenothiazine Donor-Acceptor Complexes for Photoredox Catalysis" J. Phys. Chem. A, DOI: 10.1021/acs.jpca.9b10400 Buss, B.; Lim, C. H.; Miyake, G. M.; "Dimethyl‐dihydroacridines as Photocatalysts in the Organocatalyzed Atom Transfer Radical Polymerization of Acrylate Monomers" Angew. Chem. Int. Ed., DOI: 10.1002/anie.201910828 Liu, B.; Alegre-Requena, J.; Paton, R.; Miyake, G. M.; "Unconventional Reactivity of Ethynylbenziodoxolone (EBX) Reagents and Thiols: Scope and Mechanism" Chem. Eur. J., DOI: 10.1002/chem.201904520