个人简介
亢小辉,博士,教授,硕士生导师。2015年6月毕业于大连理工大学,获工学博士学位。先后于日本理化学研究所(联合培养博士)和中科院大连化学物理研究所(助理研究员)学习和工作。现任教于大连医科大学药学院药物化学教研室,主讲本科《药物化学》和《波谱分析》等课程,参编人卫本科规划教材《药学英语》1部。研究方向为医药用高分子材料合成机制的理论模拟研究。在国际著名期刊发表SCI论文70余篇,撰写英文专著1部;主持国家自然科学基金面上项目和青年项目各1项,辽宁省“兴辽英才计划”青年拔尖人才项目1项,大连市高层次人才创新创业项目1项,其他项目若干;入选辽宁省“兴辽英才计划”青年拔尖人才,辽宁省“百千万”人才工程,大连市青年科技之星。
研究领域
医用高分子材料合成机制和催化剂设计的理论模拟研究
金属蛋白酶催化药物代谢机制及新药设计的理论模拟研究
近期论文
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Guanglin Zhou, Hongliang Mu, Xiaohui Kang,* Zhongbao Jian,* Direct Synthesis of Ultrahigh Molecular Weight Functionalized Isotactic Polypropylene, CCS Chemistry 2023, 5, 2638–2649.
Chuang Song, Guoliang Mao, Xiukuan Yao, Yuxing Zhang, Wei Gao, Xiaohui Kang,* Zhongbao Jian*, Simple and sterically open Nickel catalyst for ultrahigh molecular weight polyethylene synthesis, Macromolecules, 2023, 56, 9540−9549.
Yuxing, Zhang, Xiaohui Kang*, Zhongbao Jian,* Selective branch formation in ethylene polymerization to access precise ethylene-propylene copolymers. Nature Communication, 2022, 13, 725.
Lanxiao Zhao, Peng Deng, Xun Gong, Xiaohui Kang,* Jianhua Cheng,* Regioselective C-H Alkylation of Aromatic Ethers with Alkenes by a Half-Sandwich Calcium Catalyst, ACS Catalysis, 2022, 12, 7877–7885.
Wenhui Ren, Fen You, Jingjing Zhai, Xiaohui Kang*, Yat-Ming So*, and Xiaochao Shi,* Living (Co)Polymerization of Isoprene and Butadiene with Unparallel Stereoselectivity Catalyzed by Single Rare-Earth Metal Cationic Species, Macromolecules, 2022, 55, 23, 10640–10650.
Kangkang Li, Hongliang Mu, Xiaohui Kang*, and Zhongbao Jian,* Suppression of Chain Transfer and Promotion of Chain Propagation in Neutral Anilinotropone Nickel Polymerization Catalysis, Macromolecules, 2022, 55, 2533–2541.
Chaoqun Wang,⊥ Xiaohui Kang,⊥ Jian Zhongbao,* Efficient Suppression of Chain Transfer and Branching via C-sType Shielding in a Neutral Nickel(II) Catalyst, Angew. Chem. Int. Ed., 2021, 60, 4018−4022.
Jinbo Zhang, Lebin Wang, Shaofeng Liu,* Xiaohui Kang,* Zhibo Li,* Lewis pair as organocatalyst for one-pot synthesis of block copolymers from mixture of epoxide, Anhydride, and CO2, Macromolecules, 2021, 54, 763−772.
Xiaohui Kang, Gen Luo, Lun Luo, Shaowei Hu, Yi Luo,* Zhaomin Hou,* Mechanistic Insights into ring cleavage and contraction of benzene over a titanium hydride cluster, Journal of the American Chemical Society 2016, 138, 11550–11559.
Takanori Shima, Shaowei Hu, Gen Luo, Xiaohui Kang, Yi Luo, Zhaomin Hou,* Dinitrogen cleavage and hydrogenation by a trinuclear titanium polyhydride complex, Science 2013, 340, 1549–1552.