Gabbaï, François - Texas A&M University

个人简介

Educational Background Ph. D., 1994, University of Texas at Austin Alexander von Humboldt Postdoctoral Fellow, 1994-1996, Technical University of Munich European Community Research Fellow (Habilitation), 1996-1998, Technical University of Munich Awards & Honors Associate Editor for Chemical Science, 2019-present Distinguished Achievement Award in the category of Research University Distinguished Professor, 2019-present Third Annual Anton B. Burg Memorial Lecturer, University of Southern California, 2017 The James A. Ibers Summer Lectures, Northwestern University, 2017 Boulder Scientific Innovation Lecturer, Colorado State University, 2016 F. Albert Cotton Award in Synthetic Inorganic Chemistry, 2016 Editorial Board Member of Chemistry Select, 2016-present Editorial Board Member of Chem, 2016-present Vice-Chair (2014) and Chair (2016) of the Inorganic Chemistry Gordon Conference Appointed as Arthur E. Martell Chair of Chemistry, 2014 Member of the Inorganic Syntheses board, 2013-present Fellow of the Royal Society of Chemistry, 2013 Associate Editor for Organometallics, 2011-2019 Fellows of the American Chemical Society, 2011 Dalton Transactions North American Lectureship, 2009) NSF CAREER Award, 2001 TMR European Commission Research Fellow, 1996 Alexander von Humbodlt Fellow, 1994

研究领域

Main group-based Lewis acids: Application in anion capture and catalysis Exploiting the non-innocence of antimony ligands: From organometallic catalysis to the photoreductive elimination of halogens

近期论文

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P. Castro Castro, F. P. Gabbaï "Pnictogen bonding at the core of carbene-stiborane gold complex: Impact on structure and reactivity" Organometallics, 2024, 43, 2334-2341 W. C. Liu, F. P. Gabbaï "Characterization of a Lewis adduct in its inner and outer forms" Science 2024, 385, 1184-1188 N. H. Hunter, F. P. Gabbaï "Bismuthenium Cations for the Transport of Chloride Anions via Pnictogen Bonding" Angew. Chem. Int. Ed. 2024, e202414699 C. R. Wade, B. L. Murphy, S. Bedajna, F. P. Gabbaï "Rh → Sb Interactions Supported by Tris (8-quinolyl)antimony Ligands" Organometallics 2024, 43, 1785-1788 L. Maltz, F. P. Gabbaï "Exploring the effects of Se basicity on a Te···Se interactions supported by a rigid indazolium backbone" Organometallics 2024, 43, 1246-1255. B. L. Murphy, F. P. Gabbaï, "Tunable pnictogen bonding at the service of hydroxide transport across phospholipid bilayers" J. Am. Chem. Soc. 2024, 146, 7146-7151 E. D. Litle, F. P. Gabbaï "Double axial stabilization of a carbenium ion via convergent P=O → C⁺ tetrel bonding" Chem. Commun. 2024, 60, 690-693. B. Zhou, S. Bedajna, F. P. Gabbaï "Pnictogen bonding at the service of gold catalysis: The case of a phosphinostiborane gold complex" Chem. Commun. 2024, 60, 192-195 A. Munawar, L. T. Maltz, W. C. Liu, F. P. Gabbaï "Synthesis of an Indazole/Indazolium Phosphine Ligand Scaffold and Its Application in Gold(I) Catalysis" Organometallics 2023, 42, 2742-2746. M. Karimi, E. Litle, F. P. Gabbai "Cationic Complexes with Au→Ge Bonds – Synthesis and Carbophilic Reactivity" Israel Journal of Chemistry, 2023, 63, e202200036. B. L. Murphy, F. P. Gabbaï "Binding, Sensing, And Transporting Anions with Pnictogen Bonds: The Case of Organoantimony Lewis Acids" J. Am. Chem. Soc. 2023, 145, 19458-19477. L. T. Maltz, F. P. Gabbaï "Analyzing Fluoride Binding by Group 15 Lewis Acids: Pnictogen Bonding in the Pentavalent State" Inorg. Chem. 2023, 62, 13566-13572. B. Zhou, F. P. Gabbaï "Four-Electron Reduction of O₂ Using Distibines in the Presence of ortho-Quinones" J. Am. Chem. Soc. 2023, 145, 13758-13767. J. E. Smith, F. P. Gabbaï "Are Ar₃SbCl₂ Species Lewis Acidic? Exploration of the Concept and Pnictogen Bond Catalysis Using a Geometrically Constrained Example" Organometallics 2023, 42, 240-245. A. Cataldo, M. Chvojka, G. Park, V. Sindelar, F. P. Gabbaï, S. J. Butler, H. Valkenier "Transmembrane transport of fluoride studied by time-resolved emission spectroscopy" Chem. Commun. 2023, 59, 4185-4188. (Pre-Print: ChemRxiv, 10.26434/chemrxiv-2023-b1780). E. D. Litle, F. P. Gabbaï "A cationic gold-fluorenyl complex with a dative Au → C+ bond: synthesis, structure, and carbophilic reactivity" Chem. Commun. 2023, 59, 603-606. W.-C. Liu, F. P. Gabbaï "Placing gold on a π⁺-surface: ligand design and impact on reactivity" Chem. Sci. 2023, 14, 277-283. W.-C. Liu, F. P. Gabbaï "Fluoride ion sensing with an acridinium borane" Can. J. Chem. 2023, 101, 154-162. V. M. Gonzalez, G. Park, M. Yang, F. P. Gabbaï "Fluoride anion complexation and transport using a stibonium cation stabilized by an intramolecular P=O→Sb pnictogen bond" Dalton Trans. 2021, 50, 17897-17900. J. E. Smith, H. Yang, F. P. Gabbaï "An Electrophilic, Intramolecularly Base-Stabilized Platinum–Antimony Complex" Organometallics 2021, 23, 3886-3892. J. Zhou, E. D. Litle, F. P. Gabbai "Isolation and reactivity of a gold(i) hydroxytrifluoroborate complex stabilized by anion-π⁺ interactions" Chem. Commun. 2021, 57, 10154-10157. M. Karimi, E. S. Tabei, R. Fayad, M. R. Saber, E. O. Danilov, C. Jones, F. N. Catellano, F. P. Gabbaï "Photodriven elimination of chlorine from germanium and platinum in a dinuclear Ptᴵᴵ→Geᴵⱽ complex" Angew. Chem. Int. Ed. 2021, 60, 22352-22358. G. Park, F. P. Gabbaï "The Elusive Au(I)···H–O Hydrogen Bond: Experimental Verification" J. Am. Chem. Soc. 2021, 143, 12494-12498. B. Zhou, F. P. Gabbaï "Lewis Acidic Telluronium Cations: Enhanced Chalcogen-Bond Donor Properties and Application to Transfer Hydrogenation Catalysis" Organometallics 2021, 40, 2371-2374. B. Zhou, F. P. Gabbai "Anion Chelation via Double Chalcogen Bonding: The Case of a Bis-telluronium Dication and Its Application in Electrophilic Catalysis via Metal–Chloride Bond Activation" J. Am. Chem. Soc. 2021, 143, 8625-8630. D. You, M. Hirai, B. Zhou, F. P. Gabbaï "Distiboranes based on ortho–phenylene backbones as bidentate Lewis acids for fluoride anion chelation" Org. Biomol. Chem. 2021, 19, 4949-4957. W.-C. Liu, Y. Kim, F. P. Gabbaï "Conformational Switching through the One-Electron Reduction of an Acridinium-based, γ-Cationic Phosphine Gold Complex" Chem. Eur. J. 2021, 27, 6701-6705. R. R. Rodrigues, F. P. Gabbaï "Structural Evidence for Pnictogen-Centered Lewis Acidity in Cationic Platinum-Stibine Complexes Featuring Pendent Amino or Ammonium Groups" Molecules 2021, 26, 1985. E. D. Litle, L. C. Wilkins, F. P. Gabbaï "Ligand-enforced intimacy between a gold cation and a carbenium ion: Impact on stability and reactivity" Chem. Sci. 2021, 12, 3929-3936. M. Piesch, F. P. Gabbaï, M. Scheer "Phosphino-Stibine Ligands for the Synthesis of Heterometallic Complexes" Z. Anorg. Allg. Chem. 2021, 647, 266-278. D. You, J. E. Smith, S. Sen, F. P. Gabbaï"A Stiboranyl Platinum Triflate Complex as an Electrophilic Catalyst" Organometallics 2020, 39, 4169-4173. G. Park, F. P. Gabbaï "Redox-controlled chalcogen and pnictogen bonding: the case of a sulfonium/stibonium dication as a preanionophore for chloride anion transport" Chem. Sci. 2020, 11, 10107-10112. M. Karimi, R. Borthakur, C. L. Dorsey, C.-H. Chen, S. Lajeune, F. P. Gabbaï "Bifunctional Carbenium Dications as Metal-Free Catalysts for the Reduction of Oxygen" J. Am. Chem. Soc. 2020, 142, 13651-13656. B. Zhou, F. P. Gabbaï "Redox-controlled chalcogen-bonding at tellurium: Impact on Lewis acidity and chloride anion transport properties" Chem. Sci. 2020, 11, 7495-7500. Y. H. Lo, F. P. Gabbaï "Cyclometalated Iridium Bipyridine Complexes with Peripheral Antimony Substituents" Z. Anorg. Allg. Chem. 2020, 646, 636-641. G. Park, F. P. Gabbaï "Phosphonium boranes for the selective transport of fluoride anions across artificial phospholipid membranes" Angew. Chem. Int. Ed. 2020, 59, 5298-5302.