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E.A. Chulanova, E.A Radiush, N.A. Semenov, E. Hupf, I.G Irtegova, Y.S Kosenkova, I.Y.Bagryanskaya, L.A Shundrin, J. Beckmann, A.V. Zibarev Tuning Molecular Electron Affinities against Atomic Electronegativities by Spatial Expansion of a p-System. Chem.Phys.Chem. 202352,5918-5925 F. Feige, L.A. Malaspina, F. Kleemiss, J.F. Kögel, S. Ketkov, E. Hupf,S. Grabowsky, J. Beckmann An investigation into the Brønsted acidity of the perfluorinated alkoxy silanes {(F3C)3CO}3SiH and {(F6C5)3CO}2Si(Cl)H. Dalton Trans. 202352,5918-5925 P. Komorr, M. Olaru, E. Hupf, S. Mebs, J. Beckmann Donor Acceptor Complexes between the Chalcogen Fluorides SF2, SeF2, SeF4 and TeF4 and an N-Heterocyclic Carbene. Chem. Eur. J. 2022, 28,Article number e202201023. D. Duvinage, P. Puylaert, E.K. Wieduwilt, A.L. Malaspina, A. J. Edwards, E. Lork, S. Mebs, E. Hupf, S. Graboswky, J. Beckmann Nickel and Palladium Complexes of a PP(O)P Pincer Ligand Based upon a peri-Substituted Acenaphthyl Scaffold and a Secondary Phosphine Oxide. Inorg. Chem. 2022, 61,8406-8418. S. Furan, M. Molkenthin, K. Winkels, E. Lork, S. Mebs, E. Hupf, J. Beckmann Tris(6-diphenylphosphinoacenaphth-5-yl)gallium: Z-Type Ligand and Transmetalation Reagent. Organometallics 2021, 40,3785-3796. F. Feige, L.A. Malaspina, E. Rychagova, S. Ketkov, S. Grabowsky, E. Hupf, J. Beckmann Perfluorinated Trialkoxysilanol with Dramatically Increased Brønsted Acidity. J. Organomet. Chem. 2021, 27,15898-15902. S. Holsten, A.L. Malaspina, F. Kleemiss, S. Mebs, E. Hupf, S. Grabowsky, Beckmann Different Reactivities of (5-Ph2P-Ace-6-)2MeSiH toward the Rhodium(I) Chlorides [(C2H4)2RhCl]2and [(CO)2RhCl]2. Hirshfeld Atom Refinement of a Rh-H···Si Interaction. Organometallics 2021, 40,2027-2038. S. Furan, M. Vogt, K. Winkels, E. Lork, S. Mebs, E. Hupf, J. Beckmann (6-Diphenylphosphinoacenaphth-5-yl)indium and -nickel Compounds: Synthesis, structure, transmetalation, and cross-coupling reactions. Z. Anorg. Allg. Chem. 2021, 40,1284-1295. S. Furan, E. Hupf, E. Lork, J. Beckmann Synthesis and Structure of 5-Diphenylphosphino- acenaphth-6-yl Boronic Acid, Related Dialkyl Esters and Boroxine Rings. Z. Anorg. Allg. Chem . 2021, 647,507-512. F. Meyer, E. Hupf, E. Lork, S. Grabowsky, S. Mebs, J. Beckmann Bis(6-diphenylphosphino-acenaphth-5-yl)sulfoxide: A New Ligand for Late Transition Metal Complexes. Eur. J. Inorg. Chem.2020, 2020, 3829–3836 . S. Furan, E. Lork, S. Mebs, E. Hupf, J. Beckmann Transmetallation of Bis(6-diphenylphosphinoacenaphth-5-yl)-Mercury and -Tributyltin with Precious Metal Chlorides. Z. anorg. allg. Chem.2020, 646, 856–865 . S. Furan, E. Hupf, E. Lork, J. Beckmann Synthesis and structure of 6-diphenylphosphinoacenaphth-5-yl bismuth compounds. Revue Roumaine de Chimie2020, 65, 673–676 . R.S. Markl, N. Hohn, E. Hupf, L. Bießmann, V. Korstgens, L.P. Kreuzer, G. Mangiapia, M. Pomm, A. Kriele, E. Rivard, P. Muller-Buschbaum Comparing the backfilling of mesoporous titania thin films with hole conductors of different sizes sharing the same mass density. IUCrJ2020, 7, 268–275 . S. Holsten, E. Hupf, E. Lork, S. Mebs, J. Beckmann Proximity enforced oxidative addition of a strong unpolar σ-Si-Si bond at rhodium(i). Dalt. Trans.2020, 49, 1731–1735 . E. Hupf, F. Kaiser, P.A. Lummis, M.M.D. Roy, R. McDonald, M.J. Ferguson, F.E. Kühn, E. Rivard Linking Low-Coordinate Ge(II) Centers via Bridging Anionic N-Heterocyclic Olefin Ligands. Inorg. Chem.2020, 59, 1592–1601 . F. Kleemiss, E.K. Wieduwilt, E. Hupf, M.W. Shi, S.G. Stewart, D. Jayatilaka, M. J. Turner, K, Sugimoto, E. Nishibori, T. Schirmesiter, T.C. Schmidt, B. Engels, S. Grabowsky Similarities and Differences between Crystal and Enzyme Environmental Effects on the Electron Density of Drug Molecules. Chem. Eur. J.2020, im Druck, . E. Hupf, L.A. Malaspina, S. Holsten, F. Kleemiss, J. Beckmann, A.J. Edwards; J.R. Price, V. Kozich, K. Heyne, S. Mebs, S. Grabowsky, J. Beckmann Proximity Enforced Agostic Interactions Involving Closed-Shell Coinage Metal Ions. Inorg. Chem.2019, 58, 16372–16378. L.A. Malaspina, E.K. Wieduwilt, J. Bergmann, F. Kleemiss, B. Meyer, M.F. Ruiz-López, R. Pal, E. Hupf, J. Beckmann, R.O Piltz, A.J. Edwards, S. Grabowsky, A. Genoni Fast and Accurate Quantum Crystallography: From Small to Large, from Light to Heavy. J. Phys. Chem. Lett.2019, 10, 6973–6982. S.M. Parke, S. Tanaka, H. Yu, E. Hupf, M.J. Ferguson,Y. Zhou, K. Naka, E. Rivard Highly Fluorescent Benzophosphole Oxide Block-Copolymer Micelles. Macromolecules2019, 52, 7477–7488. E. Hupf, Y. Tsuchiya, W. Moffat, L. Xu, M. Hirai, Y. Zhou, M.J. Ferguson, R. McDonald, T. Murai, G. He, E. Rivard A Modular Approach to Phosphorescent π-Extended Heteroacenes. Inorg. Chem.2019, 58, 13323–13336. K. Takahashi, S. Shimo, E. Hupf, J. Ochiai, C.A. Braun, W. Torres Delgado, L. Xu, E. Rivard, N. Iwasawa Self-Assembly of Macrocyclic Boronic Esters Bearing Tellurophene Moieties and Their Guest-Responsive Phosphorescence. Chem. Eur. J.2019, 25, 8479–8483. T.G. Do, E. Hupf, E. Lork, J.F. Kögel, F. Mohr, A. Brown, R. Toyoda, R. Sakamoto, H. Nishihara, S. Mebs, J. Beckmann Aurophilicity and Photoluminescence of (6-Diphenylpnicogenoacenaphth-5-yl)gold Compounds. Eur. J. Inorg. Chem.2019, 2019, 647–659. T.G. Do, E. Hupf, E. Lork, S. Mebs, J. Beckmann Bis(6-diphenylphosphinoacenaphth-5-yl)telluride as a ligand toward coinage metal chlorides. Dalt. Trans.2019, 48, 2635–2645. S. Furan, E. Hupf, J. Boidol, J. Brünig, E. Lork, S. Mebs, J. Beckmann Transition metal complexes of antimony centered ligands based upon acenaphthyl scaffolds. Coordination non-innocent or not?. Dalt. Trans.2019, 48, 4504–4513.

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