周锋 - 华东师范大学 - 化学与分子工程学院

个人简介

教育经历 2005.9–2009.6, 四川师范大学, 材料化学, 学士 2009.9–2014.6, 华东师范大学, 有机化学, 博士, 导师: 周剑 2014.7-2017.12, 华东师范大学, 化学与分子工程学院, 讲师 2017.12-2021.12, 华东师范大学, 化学与分子工程学院, 副教授 2021.12-今，华东师范大学, 化学与分子工程学院, 教授（破格晋升）荣誉及奖励 2016年6月，上海市优秀博士学位论文 2014年5月，上海市优秀毕业生 2013年12月，华东师范校长奖学金 2013年12月，博士研究生国家奖学金 2012年12月，华东师范大学校长奖学金一等奖

研究领域

主要围绕化学固定二氧化碳开展研究工作，探索二氧化碳参与的不对称催化新反应，通过开发更为高效的催化体系，基于电化学或不对称串联反应等策略，实现手性环碳酸酯或羧酸等系列高附加值化合物的高选择性合成

近期论文

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Z. Zhang, Y. Sun, Y. Gong, D. Tang, H. Luo, Z. Zhao, F. Zhou,* X. Wang* and J. Zhou* Enantioselective propargylic amination and related tandem sequences to α-tertiary ethynylamines and azacycles. Nat. Chem. 2024, 10.1038/s41557-024-01479-z. P.-W. Xu, F. Zhou,* Lei Zhu* and J. Zhou*,Catalytic desymmetrization reactions to synthesize all-carbon quaternary stereocentres. Nat. Synth. 2023, 2, 1020–1036. Y. Gong, C. Wang, F. Zhou,* K. Liao, X.-Y. Wang, Y. Sun, Y.-X. Zhang, Z. Tu, X. Wang,* and J. Zhou*, Sulfonyl-PYBOX Ligands Enable Kinetic Resolution of α-Tertiary Azides by CuAAC. Angew. Chem. Int. Ed.2023, 62, e202301470. X.-Y. Cui, Z.-T. Ye, H.-H. Wu,* C.-G. Ji,* F. Zhou* and J. Zhou, Au(I)-Catalyzed Formal Intermolecular Carbene Insertion into Vinylic C(sp2),H Bonds and Allylic C(sp3),H Bonds. ACS Catal.2023, 13, 1554,1561. Z.-P. Zhao, H.-R. Lin, Z. Zhang, X.-T. Gao, C.-B. Ji,* J. Zhou, and F. Zhou*, A Highly Stereoselective Redox Isomerization-Reductive Deuteration Sequence of Propargyl Amines to α,Deuterated Amino Acids.Org. Lett.2023, 25, 7895,7899. H. Luo, J. Ren, Y. Sun, Y.-L. Liu, F. Zhou,* G.-Y. Shi,* and Jian Zhou, Recent advances in chemical fixation of CO2 based on flow chemistry. Chin. Chem. Lett.2023, 34, 107782. X.-Y. Cui, F. Zhou,* H.-H. Wu* and J. Zhou*, Asymmetric Tandem Reactions Achieved by Chiral Amine & Gold(I) Cooperative Catalysis. Chin. J. Org. Chem.2022, 42, 3033-3050. B.-W. Pan, Y. Shi, S.-Z. Dong, J.-X. He, B.-S. Mu, W.-B. Wu, Y. Zhou,* F. Zhou* and J. Zhou*, Highly stereoselective synthesis of spirocyclopropylthiooxindoles and biological evaluation. Org. Chem. Front., 2022, 9, 2640–2646. Z. Zhang, Z.-H. Zhang, F. Zhou,* and Jian Zhou, Catalytic Enantioselective Transfer Hydrogenation,Carboxylative Cyclization to 4,Fluoroalkyl 2,Oxazolidinone with CO2 as the C1 Synthon. Org. Lett. 2021, 23, 2726,2730. C.-W. Lei, B.-S. Mu, F. Zhou,* J.-S. Yu,* Y. Zhou* and J. Zhou, Organocatalytic enantioselective reactions involving prochiral carbocationic intermediates. Chem. Commun.,2021, 57, 9178. K. Liao, Y. Gong, R.-Y. Zhu, C. Wang, F. Zhou* and J. Zhou* Highly Enantioselective CuAAC of Functional Tertiary Alcohols Featuring an Ethynyl Group and Their Kinetic Resolution. Angew. Chem. Int. Ed.,2021, 60, 8488–8493. X.-T. Gao, Z. Zhang, X. Wang, J.-S. Tian, S.-L. Xie, F. Zhou* and J. Zhou, Direct electrochemical defluorinative carboxylation of alpha-CF3 alkenes with carbon dioxide. Chem. Sci., 2020, 11, 10414-10420. F. Zhou,* L. Zhu,* B.-W. Pan, Y. Shi, Y.-L. Liu and J. Zhou* Catalytic enantioselective construction of vicinal quaternary carbon stereocenters. Chem. Sci., 2020, 11, 9341-9365. S.-L. Xie, X.-T. Gao, H.-H. Wu,* F. Zhou,* and J. Zhou, Direct Electrochemical Defluorinative Carboxylation of gemDifluoroalkenes with Carbon Dioxide. Org. Lett., 2020, 22, 8424-8429. C. Wang, R.-Y. Zhu, K. Liao, F. Zhou,* and J. Zhou*, Enantioselective Cu(I)-Catalyzed Cycloaddition of Prochiral Diazides with Terminal or 1-Iodoalkynes, Org. Lett., 2020, 22, 1270-1274. C. Wang, F. Zhou,* J. Zhou,* Recent Advances in the Enantioselective Copper(I)-Catalyzed Azide-Alkyne Cycloaddition Reaction. Chin. J. Org. Chem.,2020, 40, 3065-3077. Y. Shi, B.-W. Pan, Y. Zhou,* J. Zhou, Y.-L. Liu and F. Zhou* Catalytic enantioselective synthesis using carbon dioxide as a C1 synthon. Org. Biomol. Chem., 2020, 18, 8597-8619. S. Xie, X. Gao, F. Zhou*, H. Wu*, J. Zhou*, Enantioselective carboxylative cyclization of propargylic alcohol with carbon dioxide under mild conditions. Chin. Chem. Lett. 2020, 31, 324-328. X.-T. Gao, S.-L. Xie, F. Zhou*, H.-H. Wu*, J. Zhou*, Multifunctional 1,3-diphenylguanidine for the carboxylative cyclization of homopropargyl amines with CO2 under ambient temperature and pressure.Chem. Commun.2019, 55, 14303-14306. S.-L. Xie, X.-Y. Cui, X.-T. Gao, F. Zhou*, H.-H. Wu*, J. Zhou, Stereoselective defluorinative carboxylation of gem-difluoroalkenes with carbon dioxide. Org. Chem. Front. 2019, 6, 3678-3682. P.-W. Xu,C. Chen,J.-K. Liu,Y.-T. Song,F. Zhou*, J. Yan*, J. Zhou*, One-Pot Sequential [3 + 3] Dipolar Cycloaddition of Aldehyde or Ketone and Hydroxylamine with Spirocyclopropyl Oxindole. J. Org. Chem.2018, 83, 12763,12774. P.-G. Ding, X.-S. Hu,F. Zhou*, J. Zhou*, Catalytic enantioselective synthesis of α-chiral azides. Org. Chem. Front., 2018, 5, 1542-1559. X.-T. Gao, C.-C. Gan, S.-Y. Liu, F. Zhou*, H.-H. Wu*, J. Zhou*, Utilization of CO2 as a C1 Building Block in a Tandem Asymmetric A3 Coupling-Carboxylative Cyclization Sequence to 2,Oxazolidinones. ACS Catal.2017, 7, 8588-8593. F. Zhou*, S.-L. Xie, X.-T. Gao, R. Zhang,* C.-H. Wang, G.-Q. Yin, J. Zhou* Activation of (salen)CoI complex by phosphorene for carbon dioxide transformation at ambient temperature and pressure. Green Chem., 2017, 19, 3908-3915. J.-S. Yu, W.-B. Wu, F. Zhou*, The first catalytic asymmetric thioacetalization by chiral phosphoric acid catalysis, Org. Biomol. Chem.2016, 14, 2205-2209. K. Liao, F. Zhou*, J.-S. Yu, W.-M. Gao, J. Zhou, Catalytic asymmetric sulfenylation to structurally diverse dithioketals, Chem. Commun.2015, 51, 16255-16258. Z.-Y. Cao, W. D. G. Brittain, J. S. Fossey, F. Zhou* Recent advances in the use of chiral metal complexes with achiral ligands for application in asymmetric catalysis. Catal. Sci. Technol. 2015, 5, 3441-3451 研究生期间发表论文 F. Zhou, F.-M. Liao, J.-S. Yu, J. Zhou,* Catalytic Asymmetric Electrophilic Amination Reactions To Form Nitrogen-Bearing Tetrasubstituted Carbon Stereocenters. Synthesis, 2014, 46, 2983-3003. F. Zhou, C. Tan, J. Tang, Y.-Y. Zhang, W.-M. Gao, H.-H. Wu, Y.-H. Yu and J. Zhou,*Asymmetric Copper(I)-Catalyzed Azide–Alkyne Cycloaddition to Quaternary Oxindoles. J. Am. Chem. Soc. 2013, 135, 10994-10997 F. Zhou, X.-P. Zeng, C. Wang, X.-L. Zhao and J. Zhou*. Organocatalytic asymmetric synthesis of 3,3-disubstituted oxindoles featuring two heteroatoms at the C3 position. Chem. Commun., 2013, 49, 2022. F. Zhou, M. Ding, J. Zhou,*A Catalytic Metal-free Ritter Reaction to 3-Substituted 3-Aminooxindoles. Org. Biomol. Chem.2012, 10, 3178-3183. F. Zhou, Z.-Y. Cao, J. Zhang, H. B. Yang, J. Zhou,*A Highly Efficient Friedel–Crafts Reaction of 3-Hydroxyoxindoles and Aromatic Compounds to 3,3-Diaryl and 3-Alkyl-3-aryloxindoles Catalyzed by Hg(ClO4)2,3H2O. Chem. Asian J. 2012, 7, 233-241. F. Zhou, M. Ding, Y.-L. Liu, C.-H. Wang, C.-B. Ji, Y.-Y. Zhang, J. Zhou,*Organocatalytic Asymmetric α-Amination of Unprotected 3-Aryl and 3-Aliphatic Substituted Oxindoles using Di-tert-butyl Azodicarboxylate Adv. Syn. Catal. 2011, 353, 2945-2952. F. Zhou, Y.-L. Liu, J. Zhou,*Catalytic Asymmetric Synthesis of Oxindoles Bearing a Tetrasubstituted Stereocenter at the C-3 Position. Adv. Syn. Catal. 2010, 352, 1381-1407. Z.-Y. Cao, F. Zhou, Y.-H. Yu, J. Zhou,*A Highly Diastereo- and Enantioselective Hg(II)-Catalyzed Cyclopropanation of Diazooxindoles and Alkenes Org. Lett.2013, 15, 42-45. F. Zhu, F. Zhou, Z.-Y. Cao, C. Wang, Y.-X. Zhang, C.-H. Wang*, J. Zhou,*A Facile Method for the Synthesis of 3-Substituted 3-(Alkylthio)oxindoles or 3-Alkoxyoxindoles Synthesis, 2012, 44, 3129-3144. J.-S. Yu, F. Zhou, Y.-L. Liu, J. Zhou*, Organocatalytic asymmetric Michael addition of unprotected 3-substituted oxindoles to 1,4-naphthoquinone. Beilstein. J. Org. Chem. 2012, 8, 1360-1365. L. Chen, F. Zhou, T.-D. Shi, J. Zhou*,Metal-Free Tandem Friedel–Crafts/Lactonization Reaction to Benzofuranones Bearing a Quaternary Center at C3 Position J. Org. Chem. 2012, 77, 4354-4362. M. Ding, F. Zhou, Y.-L. Liu, C.-H. Wang, X.-L. Zhao, J. Zhou,* Cinchona alkaloid-based phosphoramide catalyzed highly enantioselective Michael addition of unprotected 3-substituted oxindoles to nitroolefinsChem. Sci. 2011, 2, 2035-2039. Y.-L. Liu, T.-D. Shi, F. Zhou, X.-L. Zhao, X. Wang,* J. Zhou,*Organocatalytic Asymmetric Strecker Reaction of Di- and Trifluoromethyl Ketoimines. Remarkable Fluorine Effect Org. Lett. 2011, 13, 3826-3829. Y.-L. Liu, F. Zhou, J.-J. Cao, C.-B. Ji, M. Ding, J. Zhou,*A facile method for the synthesis of oxindole based quaternary α-aminonitriles via the Strecker reactionOrg. Biomol. Chem. 2010, 8, 3847-3850. J.-J. Cao, F. Zhou,J. Zhou,*Improving the Atom Efficiency of the Wittig Reaction by a “Waste as Catalyst/Co-catalyst” Strategy Angew. Chem. Int. Ed. 2010, 49, 4976-4980. M. Ding, F. Zhou, Z.-Q. Qian, J. Zhou,*Organocatalytic Michael addition of unprotected 3-substituted oxindoles to nitroolefins. Org. Biomol. Chem. 2010, 8, 2912-1914. Z.-Q. Qian, F. Zhou, T.-P. Du, M. Ding, B.-L. Wang, X.-L. Zhao, J. Zhou,*Asymmetric construction of quaternary stereocenters by direct organocatalytic amination of 3-substituted oxindolesChem. Commun. 2009, 6753-6755.