张正彪 - 苏州大学 - 材料与化学化工学部

个人简介

教育经历博士（2003年9月~2007年12月）苏州大学，高分子化学与物理硕士（1997年9月~2000年6月）苏州大学，高分子化学与物理本科（1993年9月~1997年6月）苏州大学，化学工程工作经历 2000年8月~现在苏州大学，材料与化学化工学部 2007年8月~2008年8月，新加坡国立大学，博士后 2012年2月~2013年2月，美国阿克伦大学，访问学者 2015年6月~2015年8月，日本名古屋大学，访问教授荣誉教育部自然科学二等奖，排五，2010；江苏省自然科学进步二等奖，排五，2010；苏州大学优秀博士论文，2008；苏州大学苏鑫科研奖，2008；指导国家级大学生创新性实验计划（2010）和校级大学生创新性计划（2009）各1项，结题均为优秀。主讲《化工原理》课程获苏州大学精品课程。

研究领域

1.可控聚合机理及新方法开发 2.序列可控聚合物的合成； 3.拓扑结构聚合物的设计与合成 4.功能大分子的精密设计与合成

近期论文

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Yuxuan Ji, Liuqiao Zhang, Xue Gu, Wei Zhang, Nianchen Zhou, Zhengbiao Zhang,* and Xiulin Zhu. Sequence-Controlled Polymers with Furan-Protected Maleimide as a Latent Monomer. Angew. Chem. Int. Ed. 2017, DOI: 10.1002/anie.201610305. Zhihao Huang, Yanyan Zhou, Zimu Wang, Ying Li, Wei Zhang, Nianchen Zhou, Zhengbiao Zhang* and Xiulin Zhu*. Recent Advances of CuAAC Click Reaction In Building Cyclic Polymer. Chinese Journal of Polymer Science 2017, 35, 317-341. Review article. Zhaoxiong Cai, Weihong Lu, Feng Gao, Xiangqiang Pan, * Jian Zhu, Zhengbiao Zhang* Xiulin Zhu*. Diselenide-Labeled Cyclic Polystyrene with Multiple Responses: Facile Synthesis, Tunable Size, and Topology. Macromol. Rapid Commun. 2016, 37, 865-871. Wei Chen, Yanyan Zhou, Ying Li, Jun Sun, Xiangqiang Pan, Qian Yu, Nianchen Zhou, Zhengbiao Zhang* and Xiulin Zhu. Shape-memory and self-healing polyurethanes based on cyclic poly(ε-caprolactone). Polym. Chem., 2016, 7, 6789-6797. Junfei Zhao, Yanyan Zhou, Yu Zhou, Nianchen Zhou, Xiangqiang Pan, Zhengbiao Zhang* and Xiulin Zhu. A straightforward approach for the one-pot synthesis of cyclic polymers from RAFT polymers via thiol–Michael addition. Polym. Chem., 2016, 7, 1782-1791. Shuangshuang Zhang, Lu Yin, Wei Zhang*, Zhengbiao Zhang* and Xiulin Zhu*. Synthesis of Diverse Cyclic-Brush Polymers with Cyclic Polystyrene as Universal Template via Grafting-from Approach. Polym. Chem., 2016, 7, 2112-2120. Qingqing Liu, Huaqiao Wu, Liuqiao Zhang, Yu Zhou, Wei Zhang, Xiangqiang Pan, Zhengbiao Zhang* and Xiulin Zhu. RAFT polymerization of N-vinylpyrrolidone mediated by cyanoprop-2-yl-1-dithionaphthalate in the presence of a fluoroalcohol: the possibility of altering monomer properties by hydrogen bonding? Polym. Chem., 2016, 7, 2015-2021. Chunlai Ding, Caiwei Fan, Ganquan Jiang, Xiangqiang Pan, Zhengbiao Zhang*, Jian Zhu* and Xiulin Zhu. Photocatalyst-Free and Blue Light-Induced RAFT Polymerization of Vinyl Acetate at Ambient Temperature. Macromolecular Rapid Communications. 2015, 36, 2181-2185. Yunshu Wang, Shuangshuang Zhang, Laibing Wang, Wei Zhang*, Nianchen Zhou, Zhengbiao Zhang* and Xiulin Zhu*. The Suzuki coupling reaction as a post-polymerization modification: a promising protocol for construction of cyclic-brush and more complex polymers. Polym. Chem., 2015, 6, 4669-4677. Feng Gao, Xiangqiang Pan,* Jian Zhu, Zhengbiao Zhang*, Wei Zhang and Xiulin Zhu. Facile synthesis of well-defined redox responsive diselenide-labeled polymers via organoseleniummediated CRP and aminolysis. Polym. Chem., 2015, 6, 1367-1372. Caiwei Fan, Chunlai Ding, Xiangqiang Pan, Zhengbiao Zhang*, Jian Zhu*, and Xiulin Zhu. A Straightforward Method For Preparing Well-Defined Responsive Diselenide-containing Polymers Based on ATRP. Macromolecular Rapid Communications. 2015, 36, 903-908. Junfei Zhao, Yanyan Zhou, Yiwen Li, Xiangqiang Pan, Wei Zhang, Nianchen Zhou, Ke Zhang, Zhengbiao Zhang* and Xiulin Zhu*, Modular Construction of Macrocycle-based Topological Polymers via High-Efficient Thiol Chemistry, Polym. Chem., 2015, 6, 2879–2891. Huaqiao Wu, Yingbo Wan, Wenxiang Wang, Yong Wang, Nianchen Zhou, Wei Zhang, Xiaohong Li,* Zhengbiao Zhang,* Xiulin Zhu, Hydrogen Bonding Promoting Controlled Radical Polymerization of 2-Vinyl Pyridine: Supramonomer for A Better Control, Polymer Chemistry, 2015, 6, 2620-2625. Feng Gao, Xiangqiang Pan, Jian Zhu, Zhengbiao Zhang, Wei Zhang, Xiulin Zhu Diselenocarbamates, Novel Initiators in ATRP of Styrene, J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 1927-1933. Yuwei Gu, Junfei Zhao, Qingqing Liu, Xiangqiang Pan, Wei Zhang, Zhengbiao Zhang*, Xiulin Zhu*, Zero valent metal/RAFT agent mediated CRP of functional monomers at room temperature: a promising catalyst system for CRP. Polym. Chem., 2015, 6, 359-363. Yiwen Li, Hao Su, Xueyan Feng, Kan Yue, Zhao Wang, Zhiwei Lin, Xiulin Zhu, Qiang Fu, Zhengbiao Zhang*, Stephen Z. D. Cheng*, Wen-Bin Zhang*. Precision synthesis of macrocyclic giant surfactants tethered with two different polyhedral oligomeric silsesquioxanes at distinct ring locations via four consecutive "click" reactions. Polym. Chem., 2015, 6, 827-837. Zhiwei Lin, Pengtao Lu, Xinfei Yu, Wen-Bin Zhang, Mingjun Huang, Kan Wu, Kai Guo, Chrys Wesdemiotis, Xiulin Zhu, Zhengbiao Zhang*, Kan Yue* and Stephen Z. D. Cheng*. Sequential “Click” Synthesis of “Nano-Diamond-Ring-like” Giant Surfactants Based on Functionalized Hydrophilic POSS/C60 Tethered with Cyclic Polystyrenes. Macromolecules 2014, 47, 4160-4168. Yang Wu, Yanyan Zhou, Jian Zhu, Wei Zhang, Xiangqiang Pan, Zhengbiao Zhang*, Xiulin Zhu*. Fast conversion of terminal thiocarbonylthio group of RAFT polymer to "clickable" thiol group via the versatile sodium azide. Polym. Chem., 2014, 5, 5546-5550. Wenxiang Wang, Junfei Zhao, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiangqiang Pan, Zhengbiao Zhang* and Xiulin Zhu* Reversible Deactivation Radical Polymerization in the Presence of Zero-Valent Metals: from Components to Precise Polymerization. Polym. Chem. 2014, 5, 3533-3546. Review Article. Yang Wu, Junfei Zhao, Xiaofei Zhang, Jian Zhu, Wei Zhang, Zhengbiao Zhang* and Xiulin Zhu* Zero-valent metal catalyzed removal of thiocarbonylthio end groups from RAFT-made polystyrene: producing controllable bimodal molecular weight distribution. Polym. Chem. 2014, 5, 1992-1998.