个人简介
1999-2003武汉大学化学系学习,获理学学士学位
2003-2008中国科学院化学研究所硕博研究生,获理学博士学位
2008-2013美国堪萨斯大学(UniversityofKansas)化学系,博士后
2014-2015荷兰阿姆斯特丹大学范特霍夫分子科学研究所(Van'tHoffInstituteforMolecularSciences,UniversityofAmsterdam),博士后
2015-至今中国科学院化学研究所,研究员
研究领域
超分子化学是研究以非共价键弱相互作用力键合起来的有序、并具有特定功能的分子集合体的化学,得益于诺贝尔奖得主Pedersen,Cram和Lehn的开拓性研究工作,超分子化学已成为一门普遍受到关注的热点学科,并渗透和融合到生命科学、材料科学、催化科学等领域。本课题组围绕超分子化学中的核心问题,开展以新型的作用模式为理念、新型的大环主体分子为基础的超分子识别、组装与催化研究。
研究领域包括:
阴离子-π作用
超分子催化
生物催化
近期论文
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Inherently chiral cages via hierarchical desymmetrization Hao Zhou, Yu-Fei Ao, De-Xian Wang, Qi-Qiang Wang* J. Am. Chem. Soc. 2022, 144, 16767-16772.
Thiazole boron difluoride dyes with large Stokes shift, solid state emission and room-temperature phosphorescence Wei Wang, Shuo Tong,* Qi-Qiang Wang, Yu-Fei Ao, De-Xian Wang,* Jieping Zhu* Chem. Eur. J. 2022, 28, e202202507.
π-pimer, π-dimer, π-trimer, and 1D π-stacks in a series of benzenetriimide radical anions: Substituent-modulated π interactions and physical properties in crystalline state De-Hui Tuo, Shuxuan Tang, Pengfei Jin, Jikun Li, Xinping Wang,* Chuang Zhang,* Yu-Fei Ao, Qi-Qiang Wang, De-Xian Wang* CCS Chem. 2022, DOI: 10.31635/ccschem.022.202202167
Supramolecular approaches to mediate chemical reactivity Pablo Ballester,* Qi-Qiang Wang,* Carmine Gaeta* Beilstein J. Org. Chem. 2022, 18, 1463-1465.
Bioinspired tetraamino-bisthiourea chiral macrocycles in catalyzing decarboxylative Mannich reactions Hao Guo, Yu-Fei Ao, De-Xian Wang, Qi-Qiang Wang* Beilstein J. Org. Chem. 2022, 18, 486-496.
Chirality gearing in an achiral cage through adaptive binding Qi-Ping Hu, Hao Zhou, Teng-Yu Huang, Yu-Fei Ao, De-Xian Wang, Qi-Qiang Wang* J. Am. Chem. Soc. 2022, 144, 6180-6184.
Triazine- and binaphthol-based chiral macrocycles and cages: Synthesis, structure, and solid-state assembly Huan Zhang, Yu-Fei Ao, De-Xian Wang, Qi-Qiang Wang* J. Org. Chem. 2022, 87, 3491-3497.
Putting anion–π interactions at work for catalysis Na Luo, Yu-Fei Ao, De-Xian Wang, Qi-Qiang Wang* Chem. Eur. J. 2022, 28, e202103303.
Naphthalene-pillared benzene triimide cage: An efficient receptor for polyhedral anions and a general tool for probing theoretically-existing anion–π binding motifs De-Hui Tuo, Yu-Fei Ao, Qi-Qiang Wang,* De-Xian Wang* CCS Chem. 2022, 4, 2806-2815
Chiral macrocycle-induced circularly polarized luminescence of a twisted intramolecular charge transfer dye Tiejun Li, Hao Guo, Yuan Wang, Guanghui Ouyang,* Qi-Qiang Wang, Minghua Liu* Chem. Commun. 2021, 57, 13554-13557.
Cation-chloride cotransport mediated by an ion pair transporter Jun Zhu, Xu-Dong Wang,* Jian Luo, Yu-Fei Ao, Qi-Qiang Wang, De-Xian Wang* Org. Biomol. Chem. 2021, 19, 8586-8590.
π-Face promoted catalysis in water: From electron-deficient molecular cages to single aromatic slides Na Luo, Yu-Fei Ao, De-Xian Wang, Qi-Qiang Wang* Chem Asian J. 2021, 16, 3599-3603.
Enantioselective biocatalytic desymmetrization for synthesis of enantiopure cis-3,4-disubstituted pyrrolidines Hui-Juan Hu, Qi-Qiang Wang, De-Xian Wang, Yu-Fei Ao* Green Synth. Catal. 2021, 2, 324-327.
Modification of the enantioselectivity of biocatalytic meso-desymmetrization for synthesis of both enantiomers of cis-1,2-disubstituted cyclohexane by Amidase engineering Hui-Juan Hu, Qi-Qiang Wang, De-Xian Wang, Yu-Fei Ao* Adv. Synth. Catal. 2021, 363, 4538-4543.
Exploiting anion–π interactions for efficient and selective catalysis with chiral molecular cages Na Luo, Yu-Fei Ao, De-Xian Wang, Qi-Qiang Wang* Angew. Chem. Int. Ed. 2021, 60, 20650-20655.
Reversal and amplification of the enantioselectivity of biocatalytic desymmetrization toward meso heterocyclic dicarboxamides enabled by rational engineering of Amidase Yu-Fei Ao,* Hui-Juan Hu, Cheng-Xin Zhao, Peng Chen, Tingting Huang, Hui Chen,* Qi-Qiang Wang, De-Xian Wang, Mei-Xiang Wang ACS Catal. 2021, 11, 6900-6907.
Xenon binding by a tight yet adaptive chiral soft capsule Shi-Xin Nie, Hao Guo, Teng-Yu Huang, Yu-Fei Ao, De-Xian Wang, Qi-Qiang Wang* Nature Commun. 2020, 11, 6257.
Enhancement of ion pairing of Sr(II) and Ba(II) salts by a tritopic ion-pair receptor in solution Bence Kutus, Jun Zhu, Jian Luo, Qi-Qiang Wang, Alexandru Lupan, Amr A. A. Attia, De-Xian Wang,* Johannes Hunger* ChemPhysChem 2020, 21, 1957-1965.
Artificial chloride-selective channel: Shape and function mimic of the ClC channel selective pore Wen-Long Huang, Xu-Dong Wang, Yu-Fei Ao, Qi-Qiang Wang,* De-Xian Wang* J. Am. Chem. Soc. 2020, 142, 13273-13277.
Magnetic multistability in an anion radical pimer De-Hui Tuo, Chao Chen, Huapeng Ruan, Qi-Qiang Wang, Yu-Fei Ao, Xinping Wang,* De-Xian Wang* Angew. Chem. Int. Ed. 2020, 59, 14040-14043.