陈祥雨 - 中国科学院大学

个人简介

University of Chinese Academy of Sciences Since 2020.11 University of Chinese Academy of Sciences Associate Professor 2020 – 2016 RWTH Aachen University Post-Doc 2016 – 2014 Institute of Chemistry, Chinese Academy of Sciences University of Vienna Post-Doc 2014 – 2009 Institute of Chemistry, Chinese Academy of Sciences Ph.D. 2009 – 2005 Xiangtan University B.S.

研究领域

Our group aims to develop novel methodologies that provide a new platform for the photoreactions. Current areas of interest include:

近期论文

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Radical Replacement Process for Ligated Boryl Radical-Mediated Activation of Unactivated Alkyl Chlorides for C(sp³)-C(sp³) Bond FormationFang, C.-Z.; Zhang, B.-B.; Tu, Y.-L.; Liu, Q.; Wang, Z.-X.; Chen, X.-Y. UCAS J. Am. Chem. Soc. 2024, ASAP Photoinduced Single Electron Reduction of the 4-O-5 Linkage in Lignin Models for C-P Coupling Catalyzed by Bifunctional N-Heterocyclic CarbenesLiu, Q.; Ren, Y.-Z.; Zhang, B.-B.; Tang, W.-X.; Wang, Z.-X.; Chen, X.-Y. UCAS Adv. Sci. 2024, 2406095. Recent advances in combining photo- and N-heterocycle nitrenium catalysisLi, X.; Tu, Y.-L.; Chen, X.-Y. UCAS Synthesis, 2024, ASAP (Invited Review). Near-Infrared-Light-Induced Iron(I) Dimer-Enabled Radical Cascade Reaction of Fluoroalkyl Bromides for the Synthesis of Ring-Fused QuinazolinonesSu, X.-D.; Liu, Q.; Cheng, J.-T.; Wang, Z.-X.; Chen, X.-Y. UCAS Org. Lett. 2024, 10.1021/acs.orglett.4c03087. Organocatalyzed Iodine-Mediated Reversible-Deactivation Radical Polymerization via Photoinduced Charge Transfer Complex CatalysisLi, X.; Zhang, B.-B.; Wang, Z.-X.; Chen, X.-Y. UCAS Chin. Chem. Lett. 2024, ASAP. Achieving Nickel-Catalyzed Reductive C(sp2)–B Coupling of Bromoboranes via Reversing the Activation SequenceMeng, C.-F.; Zhang, B.-B.; Liu, Q.; Chen, K.-Q.; Wang, Z.-X.; Chen, X.-Y. UCAS J. Am. Chem. Soc. 2024, 146, 17210–7215. Charge transfer complex enabled photoreduction of ether phosphonium salts for the selective oxyalkylation of enamidesQiao, S.; Chen, K.; Liu, Q.; Wang, Z.; Chen, X. Y. UCAS Chin. Chem. Lett. 2024, 35, 108979. Reduction of unactivated alkyl chlorides enabled by light-induced single electron transferDai, L.; Zhang, Z.-F.; Chen, X.-Y. UCAS Sci. China: Chem., 2024, 67, 471–481. N-Heterocyclic Nitrenium Charge Transfer Catalysis via Inner-Sphere Electron Transfer Concerted with Halogen-Atom DissociationZhang, C.; Fang, C.-Z.; Yi, L.; Zhu, C.; Wang, Z.-X.; Chen, X.-Y.; Rueping, M. UCAS Org. Chem. Front. 2024, 11, 673-683. Chalcogen bonding enabled photosynthesis of aryl selenides from aryl sulfonium saltsTan, F.; Su, X.-D.; Zhang, Q.-S.; Zhang, B.-B.; He, L.; Liu, Q.; Chen, X.-Y. UCAS Org. Chem. Front. 2024, 11, 654-660. N-heterocyclic nitrenium-catalyzed photoreductive radical-polar crossover for alkene dicarbofunctionalizationHan, Y.-F.; Zhang, B.-B.; Sun, N.-N.; Wang, Z.-X.; Chen, X.-Y. UCAS Green Synth. Catal. 2024, 10.1016/j.gresc.2024.03.002. Photoinduced N-heterocyclic nitrenium-catalyzed single electron reduction of Se–Se bond for the generation of nucleophilic selenolatesZhang, C.-S.; Chen, K.-Q.; Zhou, L.; Yang, Z.-S.; Wang, Z.-X.; Chen, X.-Y. UCAS Org. Chem. Front. 2024, 11, 2070-2074. Bio-inspired Halogen Bonding-Promoted Cross Coupling for the Synthesis of Organoselenium CompoundsLi, B.; Yi, L.; Maity, B.; Jia, J.; Shen, Y.; Chen, X.-Y.; Cavallo, L.; Rueping, ACS Catal. 2023, 13, 15194–15202. Photoinduced Single-Electron Reduction of Alkenes ( invited review)Li, X.; Tu, Y.-L.; Chen, X. -Y. UCAS Eur. J. Org. Chem. 2023, e202301060. Cross-Electrophile C-PIII Coupling of Chlorophosphines with Organic Halides: Photoinduced PIII and Aminoalkyl Radical Generation Enabled by Pnictogen BondingTu, Y.-L.; Zhang, B.-B.; Qiu, B.-S.; Wang, Z.-X.; Chen, X. Y. UCAS Angew. Chem. Int. Ed. 2023, e202310764. Visible-Light-Induced Photoreduction of Carborane Phosphonium Salts: Efficient Synthesis of Carborane-Oxindole-Pharmaceutical HybridsLiu, Q.; Zhang, B.-B.; Sheng, H.; Qiao, S.; Wang, Z.-X.; Chen, X.-Y. UCAS Angew. Chem. Int. Ed. 2023, e202305088. Near-infrared-light-induced iron(I) dimer-enabled halogen atom transfer for rapid iodoperfluoroalkylation of alkenesSu, X.-D.;+ L, Q.;+ Li X.-N.;+ Zhang B.-B.; Wang Z.-X.; Chen X.-Y. UCAS Chem Catal. 2023, 3, 100710. Charge Transfer Complex-Enabled Synthesis of (Hetero)arylated m-Carboranes from m-Carborane Phosphonium SaltsZhang, Q.-S.; He, L.; Liu, Q.; Chen, X.-Y. UCAS Org. Lett. 203, 25, 5768–5773. N-Heterocyclic Nitrenium-Catalyzed Photohomolysis of CF3SO2Cl for Alkene TrifluoromethylationRen, X.-J.; Liao, P.-W.; Sheng, H.; Wang, Z.-X.; Chen, X.-Y. UCAS Org. Lett. 2023, 25, 6189–6194. Pnictogen Bonding Enabled Photosynthesis of Chiral Selenium-Containing Pyridines from Pyridylphosphonium SaltsLiu, Q.; Zhang, B.-B.; Zhang, C.-S.; Han, J.-N.; Wang, Z.-X.; Chen, X.-Y. UCAS Fundam. Res. 2023, 10.1016/j.fmre.2023.03.013 Photoinduced N-Heterocyclic Nitrenium-Catalyzed Single Electron Reduction of Acyl Fluorides for Phenanthridine SynthesisBao, L.; Wang, Z.-X.; Chen, X.-Y. UCAS Org. Lett. 2023, 25, 565-568. Visible-Light-Induced N-Heterocyclic Carbene-Catalyzed Single Electron Reduction of Mono-FluoroarenesSheng, H.; Liu, Q.; Zhang, B.-B.; Wang, Z.-X.; Chen, X.-Y. UCAS Angew. Chem. Int. Ed. 2023, e202218468. Photocatalytic Charge Transfer Complex Enables Hydroarylation of Alkenes for Heterocycle SynthesisRen, Y.-Z.; Fang, C.-Z.; Zhang, B.-B.; He, L.; Tu, Y.-L.; Chen, X.-Y. UCAS Org. Lett. 2023, 25, 3585–3589. Additive Free, N-Heterocyclicerocyclic Nitrenium Catalyzed Photoreduction of Cycloketone Oxime EstersSu, X.-D.; Yang, Z.; Gong, W.; Wang, Z.-X.; Chen, X.-Y. UCAS Org. Chem. Front. 2023, 10, 1160-1165 . Photocatalytic dehydrations for Ritter reactionBao, L.; Zhang, B.-B.; Wang, Z.-X.; Chen, X.-Y. UCAS Org. Chem. Front. 2023, 10, 1375-1379. Electron donor–acceptor complex enabled cascade reaction of unprotected o-anilide aryl chlorides for heterocycle synthesisYang, Z.-S., Tang, W.-X., Zhang, B.-B., Sun, D.-Q., Chen, K.-Q., Chen, X.-Y. UCAS Org. Chem. Front. 2023, 10, 1219-1223. Direct photolysis of N-methoxypyridiniums for the pyridylation of carbon/heteroatom-hydrogen bondsSheng, H.; Zhang, B.-B.; Liu, Q.; Yang, Z.-S.; Wang, Z.-X.; Chen, X.-Y. UCAS Sci. China: Chem. 2022, 65, 2494–2499. N-Heterocyclic Nitreniums Can Be Employed as Photoredox Catalysts for the Single-Electron Reduction of Aryl Halides (most downloaded articles for the previous 30 days)Kun-Quan Chen, Bei-Bei Zhang, Zhi-Xiang Wang*, and Xiang-Yu Chen* UCAS Org. Lett. 2022, 24, 25, 4598–4602 Charge Transfer Complex Enabled Photoreduction of Wittig Phosphonium SaltsTan, F.; Zheng, P.; Liu, Q.*; Chen, X.-Y.* UCAS Org. Chem. Front. 10.1039/D2QO01079H. Visible-light-induced direct hydrodifluoromethylation of alkenes with difluoromethyltriphenylphosphonium iodide saltRen, X.; Liu, Q.; Wang, Z.*; Chen, X.-Y.* UCAS Chin. Chem. Lett. 2022. 10.1016/j.cclet.2022.04.071 Catalytic charge transfer complex enabled difluoromethylation of enamides with difluoromethyltriphenylphosphonium bromideLi, P.; Liu, Q.; Sun, D.-Q.; Chen, X.-Y. UCAS Org. Biomol. Chem., 2022, 20, 7599 Additive-Free Generation of Cyanoalkyl Radicals via Photoinduced Single Electron Transfer from Dichalcogenides to Cycloketone Oxime EstersSu, X.-D.; Zhang, B.-B.; Liu, Q.; Yang, Z.-S.; Wang, Z.-X.; Chen, X.-Y. UCAS Eur. J. Org. Chem. Alkynyl Sulfonium Salts Can Be Employed as Chalcogen-Bonding Catalysts and Generate Alkynyl Radicals under Blue-Light IrradiationLu, Y.; Liu, Q.; Wang, Z.-X.*; Chen, X.-Y.* UCAS Angew. Chem. Int. Ed. 2022, 61, e202116071. Aryldiazonium salts can serve as nitrogen-based Lewis acid catalysts and their applications in the formation of photoactive charge transfer complexesRen, X.; Liu, Q.; Yang, Z.-S.; Wang, Z.; Chen, X.-Y. UCAS Chin. Chem. Lett. 2022. Metal-Free Generation of Acyl Radical via Photoinduced SingleElectron Transfer from Lewis Base to Acyl ChlorideBao, L.; Wang, Z.-X.; Chen, X.-Y. UCAS Org. Lett. 2022. doi: 10.1021/acs.orglett.2c03339 Photoinduced Halogen-Bonding Enabled Synthesis of Oxindoles and Isoindolinones from Aryl IodidesTang, W.-X.; Chen, K.-Q.; Sun, D.-Q.; Chen, X.-Y. UCAS Org. Biomol. Chem., 2022. DOI: 10.1039/D2OB01818G Water Facilitated Photolysis of Perfluoroalkyl Iodides via Halogen BondingFang, C.-Z.; Zhang, B.-B.; Li, B.; Wang, Z.-X.*; Chen, X.-Y.* UCAS Org. Chem. Front. 2022. 10.1039/D2QO00056C. Visible-light-induced N-heterocyclic carbene mediated cascade transformation of N-alkenoxypyridinium saltsSheng, H.; Liu, Q.; Chen, F.; Wang, Z*.; Chen, X.-Y.* UCAS Chin. Chem. Lett. 2022. 10.1016/j.cclet.2022.01.028. Pyrylium salts acting as both energy transfer and electron transfer photocatalysts for E → Z isomerization of activated alkenes and cyclization of cinnamic or biaryl carboxylic acids.Bao, L.; Cheng, J.-T.; Wang, Z.-X.*; Chen, X.-Y.* UCAS Org. Chem. Front. 2022. 10.1039/D1QO01623G. DFT insight into asymmetric alkyl–alkyl bond formation via nickel-catalysed enantioconvergent reductive coupling of racemic electrophiles with olefinsZhang, C.-S.; Zhang, B.-B.; Zhong, L.; Chen, X.-Y.*; Wang, Z.-X.* UCAS Chem. Sci. 2022. 10.1039/D1SC05605K.