李保军 - 郑州大学

个人简介

教育背景 1998年9月至2002年7月，郑州大学，化学学院，本科/学士，化学 2002年9月至2005年7月，郑州大学，化学学院，研究生/硕士，物理化学 2006年9月至2009年8月，南京大学，化学与化工学院，研究生/博士，无机化学 2009年9月至2011年8月，清华大学，化学系，博士后出站。工作履历 2011年8月至今，郑州大学，化学学院，工业催化研究所，研究教学工作

研究领域

能源催化课题组面向可持续能源获取及高效利用中关键制约性问题，以催化为导向，在原子-分子水平上精确调控凝聚态物质结构，监控和揭示纳米体系表面动态变化，结合实验观测和理论计算，理性设计具有特殊结构-性质-性能关系的材料和过程。近期，着重氢能源、生物质资源转化和空气污染控制关键催化材料和过程强化研究

近期论文

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Baojun Li and Zheng Xu*, A Nonmetal Catalyst for Molecular Hydrogen Activation with Comparable Catalytic Hydrogenation Capability to Noble Metal Catalyst. Journal of the American Chemical Society 2009, 131 (45), 16380–16382. Baojun Li, Man Ai and Zheng Xu*, Mesoporous β-Ni(OH)2: Synthesis and Enhanced Electrochemical Performance. Chemical Communications 2010, 46 (34), 6267–6269. Baojun Li, Huaqiang Cao*, Jin Shao, He Zheng and Meizhen Qu, Improved Performances of β-Ni(OH)2@reduced-graphene-oxide in Ni-MH and Li-ion Batteries. Chemical Communications 2011, 47 (11), 3159–3161. Baojun Li, Huaqiang Cao*, Jin Shao and Meizhen Qu, Enhanced Anode Performances of Fe3O4-Carbon-rGO Three Dimensional Composite in Lithium Ion Batteries. Chemical Communications 2011, 47 (37), 10374–10376. Baojun Li, Huaqiang Cao*, Jin Shao, Guoqiang Li, Meizhen Qu* and Gui Yin, Co3O4@graphene Composites as Anode Materials for High-performance Lithium-ion Batteries. Inorganic Chemistry 2011, 50 (5), 1628–1632. Baojun Li and Huaqiang Cao*, ZnO@graphene Composite with Enhanced Performance in Removal of Dye from Water. Journal of Materials Chemistry 2011, 21 (10), 3346–3349. Baojun Li, Huaqiang Cao*, Jin Shao, Meizhen Qu, and Jamie H. Warner, Superparamagnetic Fe3O4 Nanocrystals@Graphene Composites for Energy Storage Devices. Journal of Materials Chemistry 2011, 21 (13), 5069–5075. Baojun Li, Huaqiang Cao*, Gui Yin, Yuexiang Lu, and Jiefu Yin, Cu2O@reduced Graphene Oxide Composite for Removal of Contaminants from Water and Supercapacitor. Journal of Materials Chemistry 2011, 21 (29), 10645–10648. Baojun Li, Huaqiang Cao* and Gui Yin, Mg(OH)2@Reduced Graphene Oxide Composite for Removal of Dyes from Water. Journal of Materials Chemistry 2011, 21 (36), 13765–13768. Baojun Li, Huaqiang Cao*, Jiefu Yin, Yimin A. Wu and Jamie H. Warner, Synthesis and Separation of Dyes via Ni@reduced Graphene Oxide Nanostructures. Journal of Materials Chemistry 2012, 22 (5), 1876–1883. Baojun Li, Huaqiang Cao*, Jingxian Zhang, Meizhen Qu, Fang Lian and Xianghua Kong, SnO2–carbon–RGO Heterogeneous Electrode Materials with Enhanced Anode Performances in Lithium Ion Batteries. Journal of Materials Chemistry 2012, 22 (7), 2851–2854. Baojun Li, Hongbian Li and Zheng Xu*, Experimental Evidence for the Interface Interaction in Ag/C60 Nano Composite Catalyst and Its Crucial Influence on Catalytic Performance. The Journal of Physical Chemistry C 2009, 113 (52), 21526–21530. Huijuan Wei, Hongbian Li, Yangqing Liu, Peng Jin, Xiangyu Wang* and Baojun Li*, Oxidation-Resistant Acidic Resins Prepared by Partial Carbonization as Cocatalysts in Synthesis of Adipic Acid. ACS Appl. Mater. Interfaces 2012, 4 (8), 4106−4112. Yiqiang Wen, Xiangyu Wang*, Huijuan Wei, Baojun Li*, Peng Jin and Limin Li, A large-scale continuous-flow process for the production of adipic acid via catalytic oxidation of cyclohexene with H2O2. Green Chem. 2012, 14, 2868–2875. Yameng Ren, Juan Zhang, Yanyan Liu, Hongbian Li, Huijuan Wei, Baojun Li* and Xiangyu Wang*, Synthesis and Superior Anode Performances of TiO2-Carbon-rGO Composites in Lithium Ion Batteries. ACS Appl. Mater. Interfaces 2012, 4, 4776–4780. Changming Ye, Peng Jin, Junxia Liu, Yiqiang Wen, Huijuan Wei, Xiaoguang Zheng*, Xiangyu Wang* and Baojun Li*, Process for Recycling Tungsten from the Leach Solution of Organic Oxidation Reaction Systems. Ind. Eng. Chem. Res. 2013, 52 (10), 3600–3606. Yanyan Liu, Juan Zhang, Xiujun Zhang, Baojun Li*, Xiangyu Wang, Huaqiang Cao, Di Wei, Zhongfu Zhou and Tony Cheetham, Magnetic catalysts as nanoactuator achieve simultaneously momentum-transfer and continuous-flow hydrogen production. J. Mater. Chem. A, 2016, 4 (11), 4280–4287. Shasha Duan, Guosheng Han, Yongheng Su, Xiaoyu Zhang, Yanyan Liu, Xianli Wu* and Baojun Li*, Magnetic Co@g-C3N4 Core-Shells on rGO Sheets for Momentum Transfer with Catalytic Activity toward Continuous-Flow Hydrogen Generation. Langmuir, 2016, 32 (25), 6272–6281. Congcong Xing, Yanyan Liu, Yongheng Su, Yinghao Chen, Shuo Hao, Xianli Wu, Xiangyu Wang, Huaqiang Cao and Baojun Li*, Structural Evolution of Co-Based Metal Organic Frameworks in Pyrolysis for Synthesis of Core–Shells on Nanosheets: Co@CoOx@Carbon-rGO Composites for Enhanced Hydrogen Generation Activity. ACS Appl. Mater. Interfaces, 2016, 8 (24), 15430–15438. Zhikun Peng, Xu Liu, Huinan Lin, Zhuo Wang, Zhongjun Li, Baojun Li*, Zhongyi Liu* and Shouchang Liu, Surface engineering on a nanocatalyst: basic zinc salt nanoclusters improve catalytic performances of Ru nanoparticles. J. Mater. Chem. A, 2016, 4 (45), 17694–17703. Zhikun Peng, Xu Liu, Shuaihui Li, Zhongjun Li, Baojun Li*, Zhongyi Liu* and Shouchang Liu, Heterophase-structured nanocrystals as superior supports for Ru-based catalysts in selective hydrogenation of benzene. Scientific Reports, 2017, 7, Article number: 39847, doi: 10.1038/srep39847. Zhikun Peng, Xu Liu, Huan Meng, Zhongjun Li, Baojun Li*, Zhongyi Liu* and Shouchang Liu, Design and Tailoring of the 3D Macroporous Hydrous RuO2 Hierarchical Architectures with a Hard-Template Method for High-Performance Supercapacitors. ACS Appl. Mater. Interfaces, 2017, 9 (5), 4577–4586. Yanyan Liu, Guosheng Han, Xiaoyu Zhang, Congcong Xing, Chenxia Du,* Huaqiang Cao, and Baojun Li,* Co-Co3O4@carbon core-shells derived from metal−organic framework nanocrystals as efficient catalyst for hydrogen evolution. Nano Research, 2017, 10 (9), 3035–3048. Xinwen Zhang,# Yanyan Liu,# Jie Gao, Guosheng Han, Meifang Hu, Xianli Wu,* Huaqiang Cao, Xiangyu Wang, and Baojun Li,* Defects-rich (Co-CoS2)x@Co9S8 Nanosheets Derived from Monomolecular Precursor Pyrolysis with Excellent Catalytic Activity for Hydrogen Evolution Reaction. J. Mater. Chem. A, 2018, 2018, 6 (17), 7977–7987. Xianli Wu, Xiaoyu Zhang, Guosheng Han, Yanyan Liu, Baozhong Liu, Jie Gao, Yanping Fan,* and Baojun Li,* Reaction of Co3O4 Nanocrystals on Graphene Sheets to Fabricate Excellent Catalysts for Hydrogen Generation. ACS Sustainable Chem. Eng., 2018, 6 (7), 8427–8436. Zhikun Peng, Weidong Li, Yalei Miao, Sheng Chen, Guoji Liu, Shouchang Liu, Jie Gao,* Baojun Li,* and Zhongyi Liua,* Ru Nanospheres in Water Drops for Enhanced Catalytic Performances in Selective Hydrogenation. ACS Applied Energy Materials, 2018, 1, 4277−4284. Guosheng Han, Yanyan Liu, Jie Gao, Lei Han, Huaqiang Cao, Xiangyu Wang,* Xianli Wu,* and Baojun Li,* Local Plant-Derived Carbon Sheets as Sustainable Catalysts for Efficient Oxygen Reduction Reaction. ACS Sustainable Chem. Eng., 2019, 7 (2), 2107–2115. DOI: 10.1021/acssuschemeng.8b04705. Zhihong Wei, Yuan Liu, Zhikun Peng, Haoqiang Song, Zhongyi Liu, Baozhong Liu,* Baojun Li,* Bai Yang and Siyu Lu,* Cobalt-ruthenium nanoalloys parceled in porous nitrogendoped graphene as highly efficient difunctional catalysts for hydrogen evolution reaction and hydrolysis of ammonia borane. ACS Sustainable Chem. Eng., 2019, 7 (7), 7014–7023. DOI: 10.1021/acssuschemeng.8b06745. Zhikun Peng, Haiyang Wang, Leilei Zhou, Yibo Wang, Jie Gao, Guoji Liu, Simon A. T. Redfern, XiaoLei Feng, Siyu Lu,* Baojun Li,* and Zhongyi Liu,* Hollow carbon shells enhanced by confined ruthenium for cost-efficient and superior catalysts in alkaline hydrogen evolution reaction. J. Mater. Chem. A, 2019, 7 (12), 6676–6689. DOI: 10.1039/c8ta09136f. Peizhen Liu,# Yanyan Liu,# Jianchun Jiang* Saima Ashraf, Xianli Wu, Guosheng Han, Jie Gao, Ke Zhang,* and Baojun Li,* Co-, Fe-, and N-Modified Carbon Composites for Excellent Catalytic Performances toward Electrochemical Reduction Reaction. ACS Sustainable Chem. Eng., 2019, 7 (9), 8744–8754. DOI: 10.1021/acssuschemeng.9b00652. Huanhuan Zhang, Yanping Fan, Baozhong Liu,* Yanyan Liu,* Saima Ashraf, Xianli Wu, Guosheng Han, Jie Gao, and Baojun Li,* Birdcage-Type CoOx-Carbon Catalyst Derived from Metal Organic Frameworks for Enhanced Hydrogen Generation. ACS Sustainable Chem. Eng., 2019, 7 (11), 9782–9792. DOI: 10.1021/acssuschemeng.8b06660. Zhihao Chen, Haijie Sun, Zhikun Peng*, Jie Gao, Baojun Li*, Zhongyi Liu*, and Shouchang Liu, Selective Hydrogenation of Benzene: Progress of Understanding for the Ru-Based Catalytic System Design. Industrial & Engineering Chemistry Research, 2019, 58 (31), 13794–13803. DOI: 10.1021/acs.iecr.9b01475. Yanyan Liu,# Zhaorui Min,# Jianchun Jiang,* Kang Sun, Jie Gao, Yuan Shang,* and Baojun Li,* Molybdenum, Cobalt Sulfide-Modified N‑, S‑Doped Graphene from Low-Temperature Molecular Pyrolysis: Mutual Activation Effect for Hydrogen Evolution. ACS Sustainable Chem. Eng., 2019, 7 (24), 19442–19452. DOI: 10.1021/acssuschemeng.9b04219. Haiyang Wang, Caiyan Gao, Rui Li, Zhikun Peng*, Jinghe Yang, Jie Gao, Yongpeng Yang, Shuaihui Li*, Baojun Li*, Zhongyi Liu, Ruthenium-Cobalt nanoalloy embedded within hollow carbon spheres as bifunctionally robust catalyst for hydrogen generation from water splitting and ammonia borane hydrolysis. ACS Sustainable Chem. Eng., 2019, 7 (23), 18744–18752. DOI: 10.1021/acssuschemeng.9b02126. Cancan Cui, Yanyan Liu,* Sehrish Mehdi, Hao Wen, Benji Zhou, Jinpeng Li, and Baojun Li,* Enhancing effect of Fe-doping on the activity of nano Ni catalyst towards hydrogen evolution from NH3BH3. Appl. Catal. B, 2020, 265, 118612. DOI: 10.1016/j.apcatb.2020.118612. Shuyan Guan,# Lulu An,# Saima Ashraf, Lina Zhang, Baozhong Liu,* Yanping Fan,* and Baojun Li,* Oxygen vacancy excites Co3O4 nanocrystals embedded into carbon nitride for accelerated hydrogen generation. Appl. Catal. B, 2020, 269, 118775. DOI: 10.1016/j.apcatb.2020.118775. Guang Yang, Shuyan Guan, Sehrish Mehdi, Yanping Fan, Baozhong Liu,* and BaojunLi,* Co-CoOx Supported onto TiO2 Coated with Carbon as a Catalyst for Efficient and Stable Hydrogen Generation from Ammonia Borane. Green Energy & Environment, 2020, DOI: 10.1016/j.gee.2020.03.012. Mengmeng He,# Linchao Zhu,# Yanyan Liu, Hao Wen, Yunxia Hu* and Baojun Li,* Interfacial Effect of Co4S3-Co9S8 Nanoparticles Hosted onto rGO Sheets Derived from Molecular Precursor Pyrolysis on Enhancing Electrochemical Behaviour. Catal. Sci. Technol., 2020, 10, 3622–3634. DOI: 10.1039/d0cy00564a. Daijuan Zhou, Xiaoyan Huang, Hao Wen, Ruofan Shen, Yanyan Liu, Xianji Guo* and Baojun Li,* Ru-Fe Nanoalloys Supported on N-Doped Carbon as Efficient Catalysts for Hydrogen Generation from Ammonia Borane. Sustainable Energy & Fuels, 2020, 4, 3677–3686. DOI: 10.1039/d0se00660b. Zhongshuang Li, Mengmeng He, Bing Bo, Huijuan Wei, Yanyan Liu, Hao Wen, Yushan Liu, Ke Zhang, Panke Zhang,* Baojun Li,* Bi2S3 Nanorods Hosted on rGO Sheets from Pyrolysis of Molecular Precursors for Efficient Li‐Ion Storage. Energy & Environmental Materials, 2020, DOI: 10.1002/eem2.12138. Xiaoyan Huang, Yanyan Liu, Hao Wen, Ruofan Shen, Sehrish Mehdi, Xianli Wu, Erjun Liang, Xianji Guo,* Baojun Li,* Ensemble-boosting effect of Ru-Cu alloy on catalytic activity towards hydrogen evolution in ammonia borane hydrolysis. Appl. Catal. B, 2021, 287, 119960. DOI: 10.1016/j.apcatb.2021.119960. Yanyan Liu, Hao Wen, Daijuan Zhou, Xiaoyan Huang, Xianli Wu, Jianchun Jiang, Xianji Guo,* Baojun Li,* Tuning surface d charge of Ni-Ru alloys for unprecedented catalytic activity towards hydrogen generation from ammonia borane hydrolysis. Appl. Catal. B, 2021, Volume 291, 120094. DOI: 10.1016/j.apcatb.2021.120094.