付年凯 - 中国科学院化学研究所 -

个人简介

学术经历 2005-2009 湖北大学，化学生物学，学士学位 2009-2014 中国科学院化学研究所，有机化学，博士学位 2014-2016 中国科学院化学研究所，助理研究员 2016-2019 美国康奈尔大学，博士后 2019.11-至今中国科学院化学研究所，研究员荣誉与奖励 Blavatnik Regional Awards for Young Scientists Finalist in Chemistry，The New York Academy of Sciences (2018) Reaxys PhD Prize Finalist (2012)

研究领域

有机电化学合成是一门涉及电化学、有机合成及化学工程的交叉学科，被称为"古老的方法，崭新的技术"。有机电化学合成作为一种"绿色合成"手段，极好地符合了当前"原子经济"及"绿色合成"的要求。它以"电子"替代化学反应中的氧化还原剂，从源头上避免了昂贵甚至是具有一定毒性的氧化还原剂的使用及相应污染物的产生，一直以来都是学术界、工业界、尤其是制药行业备受关注的研究方向。我们在传统的电化学合成中引入现代有机合成新方法，为挑战性成键反应搭建更高效、更绿色、更适合工业生产的合成平台。 1. 不对称电化学催化与合成 2. 工业易得化学原料及高分子的电化学催化转化

近期论文

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Jiaqing Lu, Yan Yao, Liubo Li, and Niankai Fu*. Dual Transition Metal Electrocatalysis: Direct Decarboxylative Alkenylation of Aliphatic Carboxylic Acids. J. Am. Chem. Soc. 2023. Liubo Li, Yan Yao, Niankai Fu*. Free Carboxylic Acids: The Trend of Radical Decarboxylative Functionalization. Eur. J. Org. Chem. 2023, 26, e202300166. Ruipu Zhang, Liubo Li, Kehan Zhou, Niankai Fu*. Radical-Based Convergent Paired Electrolysis. Chem. Eur. J. 2023, 29, e202301034. Liubo Li, Niankai Fu*. Electrochemical N-heteroarene carboxylation: Reactor-dependent site selectivity. Chem 2023, DOI:10.1016/j.chempr.2023.02.001.(Preview) Liubo Li, Niankai Fu*. Taming Challenging Radical-Based Convergent Paired Electrolysis with Dual-Transition-Metal Catalysis. Synlett 2023, DOI: 10.1055/a-2033-8632. Kai Yang, Yukang Wang, Sanzhong Luo, Niankai Fu*. Electrophotochemical Metal-Catalyzed Enantioselective Decarboxylative Cyanation. Chem. Eur. J. 2023, e202203962.(VIP) Kehan Zhou, Chenglei Lv, Niankai Fu*.Electrochemical Metal-Catalyzed Azidoesterification of Alkenes. Eur. J. Org. Chem. 2023, 26, e202200977. (Organic Electrocatalysis Special Collection) Peng, Xue, Liubo Li, and Niankai Fu*. Pairing Iron and Nickel Catalysis for Electrochemical Esterification of Aryl Halides with Carbazates. Org. Lett. 2022, 24, 7595-7599. Kai Yang, Jiaqing Lu, Liubo Li, Sanzhong Luo, Niankai Fu*. Electrophotochemical Metal-Catalyzed Decarboxylative Coupling of Aliphatic Carboxylic Acids. Chem. Eur. J. 2022, e202202370. Yukang Wang, Liubo Li, and Niankai Fu*. Electrophotochemical Decarboxylative Azidation of Aliphatic Carboxylic Acids. ACS Catal. 2022, 12, 10661–10667. Lu Song, and Niankai Fu*. Single-Electron Strategies in Organometallic Methods: Photoredox, Electrocatalysis, Radical Relay, and Beyond. Comprehensive Organometallic Chemistry IV (Fourth Edition), 2022, 13, 339–403. Wenzhao Zhang, Nianmin Hong, Lu Song*, and Niankai Fu*. Reaching the Full Potential of Electroorganic Synthesis by Paired Electrolysis. Chem. Rec. 2021, 21, 2574–2584 (Invited Review). Jiaqing Lu, Yukang Wang, Terry McCallum*, and Niankai Fu*. Harnessing Radical Chemistry via Electrochemical Transition Metal Catalysis. iScience 2020, 23, 101796 (Invited Perspective). Niankai Fu, Yingnan Hou, Kun Li, Mengying Li, Shuang Tang, Chao Yu. A time of transition: Stories from starting a new research program in 2020, iScience, 2021, 24, 2589-0042. Luiz F. T. Novaes, Yi Wang, Jinjian Liu, Xavier Riart-Ferrer, Wan-Chen Cindy Lee, Niankai Fu, Justin S. K. Ho, X. Peter Zhang*, Song Lin*. Electrochemical Diazidation of Alkenes Catalyzed by Manganese Porphyrin Complexes with Second-Sphere Hydrogen-Bond Donors, ACS Catal. 2022, 14106-14112. Longji Li, Yao Li, Niankai Fu, Long Zhang, and Sanzhong Luo*. Catalytic Asymmetric Electrochemical α-Arylation of Cyclic β-Ketocarbonyls with Anodic Benzyne Intermediates. Angew. Chem. Int. Ed. 2020, 59, 14347–14351. Lu Song, Niankai Fu, Brian G. Ernst, Wai Hang Lee, Michael O. Frederick, Robert A. DiStasio Jr. *, and Song Lin*. Dual Electrocatalysis Enables Enantioselective Hydrocyanation of Conjugated Alkenes. Nat. Chem. 2020, 12, 747–754. Juno C. Siu, Niankai Fu, and Song Lin*. Catalyzing Electrosynthesis: A Homogeneous Electrocatalytic Approach to Reaction Discovery. Acc. Chem. Res. 2020, 53, 547–560. Niankai Fu, Lu Song, Jinjian Liu, Yifan Shen, Juno C. Siu, and Song Lin*. New Bisoxazoline Ligands Enable Enantioselective Electrocatalytic Cyanofunctionalization of Vinylarenes. J. Am. Chem. Soc. 2019, 141, 14480–14485. Lingxiang Lu, Niankai Fu, and Song Lin*. Three-Component Chlorophosphinoylation of Alkenes via Anodically Coupled Electrolysis. Synlett. 2019, 30, 1199–1203. Niankai Fu, Yifan Shen, Anthony R. Allen, Lu Song, Atsushi Ozaki, and Song Lin*. Mn-catalyzed Electrochemical Chloroalkylation of Alkenes. ACS Catal. 2019, 9, 746–754. Juno C. Siu, Gregory S. Sauer, Ambarneil Saha, Reed L. Macey, Niankai Fu, Timothée Chauviré, Kyle M. Lancaster*, and Song Lin*. Electrochemical Azidooxygenation of Alkenes Mediated by a TEMPO–N3 Charge-Transfer Complex. J. Am. Chem. Soc. 2018, 40, 12511–12520. Niankai Fu, Gregory S. Sauer, and Song Lin*. A general, electrocatalytic approach to the synthesis of vicinal diamines. Nat. Protoc. 2018, 13, 1725–1743. Ke-Yin Ye, Zhidong Song, Gregory S. Sauer, Johannes H. Harenberg, Niankai Fu, and Song Lin*. Synthesis of Chlorotrifluoromethylated Pyrrolidines by Electrocatalytic Radical Ene-Yne Cyclization. Chem. Eur. J. 2018, 24, 12274–12279. Ke-Yin Ye, Gisselle Pombar, Niankai Fu, Gregory S. Sauer, Ivan Keresztes, and Song Lin*. Anodically Coupled Electrolysis for the Heterodifunctionalization of Alkenes. J. Am. Chem. Soc. 2018, 140, 2438–2441. Joseph B. Parry, Niankai Fu, and Song Lin*. Electrocatalytic Difunctionalization of Olefins as a General Approach to the Synthesis of Vicinal Diamines. Synlett 2018, 29, 257–265. Niankai Fu, Long Zhang, and Sanzhong Luo*. Catalytic asymmetric enamine protonation reaction. Org. Biomol. Chem., 2018, 16, 510–520.