Milner, Phillip J. - Cornell University - Department of Chemistry and Chemical Biology

个人简介

Phill was born a stone’s throw from Ithaca in Towanda, PA and grew up near Rochester, NY. Phill attended Hamilton College near Utica, NY, where his love of synthetic organic chemistry was born while working on radical cyclizations with Prof. Ian Rosenstein. Phill graduated from Hamilton College in 2010 with B.A.s in Chemistry and Mathematics, and went on to pursue his Ph.D. in Chemistry with Prof. Stephen Buchwald at the Massachusetts Institute of Technology (MIT). In the Buchwald group, Phill carried out extensive mechanistic studies of the Pd-catalyzed fluorination of aryl (pseudo)halides, a reaction of importance due to the prevalence of aryl fluorides in pharmaceuticals and agrochemicals. Phill also developed the nearly instantaneous 11C-cyanation of aryl halides for the synthesis of PET radiotracers. Phill joined the group of Prof. Jeffrey Long at the University of California, Berkeley upon graduating from MIT in 2015. As a post-doctoral Fellow in the Long group, Phill designed amine-functionalized metal–organic frameworks for the removal of CO2 from the flue gas emissions of power plants. In 2018, Phill joined the Department of Chemistry and Chemical Biology at Cornell University, where his research is focused broadly at the intersection of organic, inorganic, and materials chemistry. Phill is a member of the Cornell Center for Materials Research (CCMR) and the Cornell Energy Systems Institute (CESI), a Cornell Atkinson Center for Sustainability Faculty Fellow, and a field member in the Department of Chemical and Biomolecular Engineering. Phill’s independent awards and honors include: Camille Dreyfus Teacher-Scholar Award (2023), NSF CAREER Award (2021), Robert A. and Donna B. Paul Award for Excellence in Advising (2021), Scialog Fellowship (2020), Department of Energy Early Career Award (2020), and NIH Maximizing Investigator’s Research Award (2020). PROFESSIONAL ASSOCIATIONS Faculty Fellow, Cornell Atkinson Center for Sustainability Cornell University, 2020− Field Member, Department of Chemical and Biomolecular Engineering Cornell University, 2020− Member, Cornell Center for Materials Research Cornell University, 2019− Member, Cornell Energy Systems Institute Cornell University, 2019− EDUCATION Postdoctoral Fellow (Advisor: Jeffrey Long) University of California, Berkeley 2015–2018 Ph.D. Chemistry (Advisor: Stephen Buchwald) Massachusetts Institute of Technology, 2015 B.A. Chemistry and Mathematics, with honors Hamilton College, 2010 ADDITIONAL RESEARCH EXPERIENCE Undergraduate Research Assistant (Advisor: Ian Rosenstein) Hamilton College, 2006–2010 NSF REU Fellow (Advisor: Scott Snyder) Columbia University, 2009 Undergraduate Research Assistant (Advisor: Gary Molander) University of Pennsylvania, 2008

研究领域

We develop porous framework, including organic-inorganic materials called metal–organic frameworks (MOFs) and organic materials called porous organic polymers (POPs) and covalent organic frameworks (COFs), for applications relevant to human health, medicine, energy, and the environment. MOFganic Chemistry: MOFs in Organic Synthesis Reactivity-Based Chemical Separations Redox-Active Organic Materials

近期论文

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Tristan A. Pitt, Tyler J. Azbell, Jaehwan Kim, Matthew A. Addicoat, Phillip J. Milner*. “A Strongly Reducing sp2 Carbon-Conjugated Covalent Organic Framework Formed by N-Heterocyclic Carbene Dimerization.” In review. Arjun Halder, David C. Bain, Tristan A. Pitt, Zixiao Shi, Julia Oktawiec, Jung-Hoon Lee, Stavrini Tsangari, Marcus Ng, José J. Fuentes-Rivera, Alexander C. Forse, Tomče Runčevski, David A. Muller, Andrew J. Musser, Phillip J. Milner*. “Trapping of Photoluminescent Kinetic Intermediates During High-Concentration Synthesis of Non-Emissive Metal–Organic Frameworks.” In review. Huaiguang Li, Mary E. Zick, Teedhat Trisukhon, Xinyu Liu, Helen Eastmond, Shivani Sharma, Tristan Spreng, Jack Taylor, Jamie Gittins, Cavan Farrow, Phillip J. Milner, Alexander C. Forse*. “Capturing Carbon Dioxide from Air with Charged Sorbents.” In review. Reum N. Scott*, Claire E. Frank, Maya M. Martirossyan, Phillip J. Milner*, Julia Dshemuchadse*. “Two-Dimensional Metal–Organic Framework Self-Assembly and Defect Engineering Studied via Coarse-Grained Simulations.” Chem. Mater. 2023, Accepted. Tyler J. Azbell,‡ Tristan A. Pitt,‡ Ronald T. Jerozal, Ruth M. Mandel, Phillip J. Milner*. “Simplifying the Synthesis of Metal–Organic Frameworks.” Acc. Mater. Res. 2023, Accepted. ‡Contributed equally. Kaitlyn T. Keasler, Mary E. Zick,‡ Emily E. Stacy,‡ Jung-Hoon Lee, Jaehwan Kim, Lida Aeindartehran, Tomče Runčevski, Phillip J. Milner*. “Handling Fluorinated Gases as Solid Reagents using Metal–Organic Frameworks.” Science 2023, 381, 1455-1461. ‡Contributed equally. Jaehwan Kim, Yogita Shirke, Phillip J. Milner*. “Flexible Backbone Effects on the Redox Properties of Perylene Diimide-Based Polymers.” ACS Appl. Mater. Interfaces, 2023, Accepted. Yihuan Lai, Arjun Halder, Jaehwan Kim, Thomas J. Hicks, Phillip J. Milner*. “Electroreductive Borylation of Unactivated (Hetero)Aryl Chlorides Without Light by Using Cumulene-Based Redox Mediators.” Angew. Chem. Int. Ed., 2023, e202310246. Jaehwan Kim,‡ Minh H. Le,‡ Makayla C. Spicer, Casandra M. Moisanu, Suzi M. Pugh, Phillip J. Milner*. “Zinc Bromide: A General Mediator for the Ionothermal Synthesis of Microporous Polymers via Cyclotrimerization Reactions.” J. Mater. Chem. A, 2023, 11, 17159-17166. ‡Contributed equally. Bayu I. Z. Ahmad,‡ Kaitlyn T. Keasler,‡ Emily E. Stacy,‡ Sijing Meng, Thomas J. Hicks, Phillip J. Milner*. “MOFganic Chemistry: Challenges and Opportunities for Metal–Organic Frameworks in Synthetic Organic Chemistry.” Chem. Mater. 2023, 35, 4883-4896. ‡Contributed equally. Ronald T. Jerozal, Tristan A. Pitt, Samantha N. MacMillan, Phillip J. Milner*. “High-Concentration Self-Assembly of Zirconium- and Hafnium-Based Metal–Organic Materials.” J. Am. Chem. Soc. 2023, 145, 13273-13283. Yelin Ko, Tyler J. Azbell, Phillip J. Milner, Juan Hinestroza*. “Upcycling of Dyed Polyester Fabrics into Copper-1,4-Benzenedicarboxylate (CuBDC) Metal–Organic Frameworks.” Ind. Eng. Chem. Res. 2023, 62, 5771–5781. Tyler J. Azbell, Tristan A. Pitt, Melissa M. Bollmeyer, Christina Cong, Kyle M. Lancaster, Phillip J. Milner*. “Ionothermal Synthesis of Metal–Organic Frameworks Using Low-Melting Metal Salt Precursors.” Angew. Chem. Int. Ed., 2023, 62, e202218252. Abigail K. Nason, Ronald T. Jerozal, Phillip J. Milner, Jin Suntivich*. “Reactive Crystallization via Metal–Organic Framework Formation Enables Separation of Terephthalic Acid from Textile Impurities.” ACS Sustainable Chem. Eng. 2023, 11, 18-22. Christina Cong,‡ Jaehwan Kim,‡ Cara N. Gannett, Héctor D. Abruña, Phillip J. Milner*. “Unexpected Direct Synthesis of Tunable Redox-Active Benzil-Linked Polymers via the Benzoin Reaction.” ACS Appl. Polym. Mater. 2023, 5, 1056-1066. ‡Contributed equally. Arjun Halder, David C. Bain, Julia Oktawiec, Matthew A. Addicoat, Stavrini Tsangari, José J. Fuentes-Rivera, Tristan A. Pitt, Andrew J. Musser,* Phillip J. Milner*. “Enhancing Dynamic Spectral Diffusion in Metal–Organic Frameworks Through Defect Engineering.” J. Am. Chem. Soc. 2023, 145, 1072-1082. Sayan Maiti, Jatan Sharma,‡ Jianheng Ling,‡ Dylan Tietje-Mckinney, Matthew P. Heaney, Tomče Runčevski, Matthew A. Addicoat,* Francis D’Souza,* Phillip J. Milner,* Anindita Das*. “Emissive Substoichiometric Covalent Organic Frameworks for Water Sensing and Harvesting.” Macromol. Rapid Commun. 2023, 44, 2200751. ‡Contributed equally. [Link] Invited submission. Mary E. Zick, Donovan Cho,‡ Jianheng Ling,‡ Phillip J. Milner*. “Carbon Capture Beyond Amines: CO2 Sorption at Nucleophilic Oxygen Sites in Materials.” ChemNanoMat 2023, 9, e202200436. ‡Contributed equally. Tyler J. Azbell,‡ Ruth M. Mandel,‡ Jung-Hoon Lee, Phillip J. Milner*. “Reactive Chlorine Capture by Dichlorination of Alkene Linkers in Metal–Organic Frameworks.” ACS Appl. Mater. Interfaces, 2022, 14, 53928-53935. ‡Contributed equally. Cara N. Gannett,‡ Jaehwan Kim,‡ Dave Tirtariyadi, Phillip J. Milner*, Héctor D. Abruña*. “Investigation of Ion-Electrode Interactions of Linear Polyimides and Alkali Metal Ions for Next Generation Alternative-Ion Batteries.” Chem. Sci. 2022, 13, 9191-9201. ‡Contributed equally. Elena Y. Chen,‡ Ruth M. Mandel,‡ Phillip J. Milner*. “Evaluating Solvothermal and Mechanochemical Routes towards the Metal–Organic Framework Mg2(m-dobdc).” CrystEngComm, 2022, 24, 7292-7297. ‡Contributed equally. Mary E. Zick, Suzi M. Pugh, Jung-Hoon Lee, Alexander C. Forse, Phillip J. Milner*. “Carbon Dioxide Capture at Nucleophilic Hydroxide Sites in Oxidation-Resistant Cyclodextrin-Based Metal–Organic Frameworks.” Angew. Chem. Int. Ed. 2022, 61, e202206718. Faith E. Chen,‡ Tristan A. Pitt,‡ Diane J. Okong’o, Luc G. Wetherbee, Jose J. Fuentes-Rivera, Phillip J. Milner*. “A Structure-Activity Study of Aromatic Acid Modulators for the Synthesis of Zirconium-Based Metal–Organic Frameworks.” Chem. Mater. 2022, 34, 3383-3394. ‡Contributed equally. Jaehwan Kim,‡ Casandra M. Moisanu,‡ Cara N. Gannett, Arjun Halder, José J. Fuentes-Rivera, Sean H. Majer, Kyle M. Lancaster, Alexander C. Forse, Héctor D. Abruña, Phillip J. Milner*. “Conjugated Microporous Polymers via Solvent-Free Ionothermal Cyclotrimerization of Methyl Ketones.” Chem. Mater. 2021, 33, 8334-8342. ‡Contributed equally. Faith E. Chen,‡ Ruth M. Mandel,‡ Joshua J. Woods, Jung-Hoon Lee, Jaehwan Kim, Jesse H. Hsu, José J. Fuentes-Rivera, Justin J. Wilson, Phillip J. Milner*. “Biocompatible Metal–Organic Frameworks for the Storage and Therapeutic Delivery of Hydrogen Sulfide.” Chem. Sci. 2021, 12, 7848-7857. ‡Contributed equally. Zihao Wang, Arvin Bilegsaikhan, Ronald T. Jerozal, Tristan A. Pitt, Phillip J. Milner*. “Evaluating the Robustness of Metal–Organic Frameworks for Synthetic Chemistry.” ACS Appl. Mater. Interfaces, 2021, 13, 17517-17531. Jonathan B. Lefton, Kyle B. Pekar, Uroob Haris, Mary E. Zick, Phillip J. Milner, Alexander R. Lippert, Ljupčo Pejov, Tomče Runčevski*. “Defect Formation and Amorphization of Zn-MOF-74 Crystals by Post-Synthetic Interactions with Bidentate Adsorbates.” J. Mater. Chem. A 2021, 9, 19698-19704. Mary E. Zick, Jung-Hoon Lee, Miguel I. Gonzalez, Ever O. Valasquez, Adam A. Uliana, Jaehwan Kim, Jeffrey R. Long, Phillip J. Milner*. “Fluoroarene Separations in Metal–Organic Frameworks with Two Proximal Mg2+ Coordination Sites.” J. Am. Chem. Soc. 2021, 143, 1948-1958. Jen-Yu Huang, Yuanze Xu, Phillip J. Milner, Tobias Hanrath*. “Processing-structure-performance relationships of microporous metal-organic polymers for size-selective separations.” ACS Appl. Mater. Interfaces, 2021, 13, 3521-3527. Alexander C. Forse*, Phillip J. Milner*. “New Chemistry for Enhanced Carbon Capture: Beyond Ammonium Carbamates.” Chem. Sci. 2021, 12, 508-516. Zihao Wang, Zongzhe Li, Marcus Ng, Phillip J. Milner*. “Rapid Mechanochemical Synthesis of Metal–Organic Frameworks using Exogenous Organic Base.” Dalton Trans. 2020, 49, 16238-16244. José J. Fuentes-Rivera, Mary E. Zick, M. Alexander Düfert*, Phillip J. Milner*. “Overcoming Halide Inhibition of Suzuki-Miyaura Couplings with Biaryl Monophosphine-Based Catalysts.” Org. Proc. Res. Dev. 2019, 23, 1631-1637. [Link] Invited submission to the “Honoring 25 Years of the Buchwald-Hartwig Amination” special issue. Ziting Zhu, Hsinhan Tsai, Surya T. Parker, Jung-Hoon Lee, Henry Jiang, Hao Zhuang, Alexander C. Forse, Adrian Huang, Shuoyan Xiong, Chaochao Dun, Phillip J. Milner, Jeffrey Urban, Jeffrey A. Reimer, Jeffrey B. Neaton, Jeffrey R. Long. “Cooperative Physisorption and Chemisorption of a Diamine-Appended Framework.” In preparation. Ziting Zhu, Surya T. Parker, Alexander C. Forse, Jung-Hoon Lee, Rebecca L. Siegelman, Phillip J. Milner, Hsinhan Tsai, Mengshan Ye, Maria Paley, Adam A. Uliana, Julia Oktawiec, Bhavish Dinakar, Stephanie A. Didas, Katie R. Meihaus, Jeffrey A. Reimer, Jeffrey B. Neaton, Jeffrey R. Long*. “Cooperative Carbon Dioxide Capture in Diamine-Appended Magnesium-Olsalazine Frameworks.” J. Am. Chem. Soc. 2023, 145, 17151-17163. Bhavish Dinakar, Alexander C. Forse, Henry Z. H. Jiang, Ziting Zhu, Jung-Hoon Lee, Eugene J. Kim, Surya T. Parker, Connor J. Pollak, Rebecca L. Siegelman, Phillip J. Milner, Jeffrey A. Reimer*, Jeffrey R. Long*. “Overcoming Metastable CO2 Adsorption in a Bulky Diamine-Appended Metal–Organic Framework.” J. Am. Chem. Soc. 2021, 143, 12528-15270.