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个人简介

Kavli Fellow, 2012 SEAC Young Investigator, 2006 CSGS New Scholar Award, 2004 NSF CAREER Award, 2002

研究领域

Our research is broadly focused in the areas of analytical chemistry, electrochemistry, and surface chemistry, specifically to investigate structure-property relationships in mesoscopic systems (structures and phenomena having spatial dimensions ranging from nanometer to micrometer scale). Driving our fundamental interest is the need to understand the intricate relationships between mass transport (e.g., diffusion and convection), surface reactivity (e.g., adsorption, dissolution, and passivation) and interfacial structure (e.g., composition, crystalline orientation, and heterogeneity). The physical methods used for such studies include scanning probe microscopies (e.g., AFM, TUNA, EFM, SSPM, MFM), optical microscopies, electrochemical methods, UV-vis, fluorescence and Raman spectroscopies, and other surface analysis techniques (e.g. XPS and EDS). The information from these studies will help us understand how materials behave so as to best apply existing materials to various technologies as well as to design novel, improved materials/systems.

近期论文

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Lui, H.; Robinson, D. A. Stevenson, K. J.; Wang, G. “Electronic Coupling between Ligand and Core Energy States in Dithiolate-Monothiolate Stabilized Au Clusters,” Chem. Sci. submitted. Membreno, N.; Park, K.; Goodenough, J. B.; Stevenson, K. J. “Electrode/Electrolyte Interface of Composite α-Li3V2(PO4)3 Cathodes in a Non-Aqueous Electrolyte for Lithium Ion Batteries and the Role of the Carbon Additive,” Chem. Mater. submitted. Goran, J. M. ; Phan, E. N. H.; Favela, C. A. ; Stevenson, K. J. “H2O2 Detection at Carbon Nanotubes and Nitrogen-Doped Carbon Nanotubes: Oxidation, Reduction, or Disproportionation?,” Anal. Chem. submitted. Schroder, K. W; Dylla, A. G.; Harris, S. J. ; Webb, L. J. ; Stevenson, K. J. “The Role of Surface Oxides in the Formation of Solid Electrolyte Interphases at Silicon Electrodes for Lithium-ion Batteries,” ACS Appl. Mater. Interfaces 2014, 6(23), 21510-21524. DOI: 10.1021/am506517j Alligrant, T. M.; Anderson, M. J.; Dasari, R.; Stevenson, K. J.; Crooks, R. M. “Single Nanoparticle Collisions at Microfluidic Microband Electrodes: the Effect of Electrode Material and Mass Transfer,” Langmuir 2014, 30(44), 13462-13469. DOI: 0.1021/la503628h Charlton, M. R.; Suhr, K. J.; Holliday, B. J.; Stevenson, K. J. “Electrochemical Modification of Indium Tin Oxide Using Di(4-Nitrophenol) Iodonium Tetrafluoroborate,” Langmuir 2015, 31(2), 695-702. DOI: 10.1021/la503522c Goran, J. M.; Favela, C. A.; Rust, I. M.; Stevenson, K. J.“Enhanced Electrochemical Oxidation of NADH at Carbon Nanotube Electrodes using Methylene Green: Is Polymerization Necessary?,” J. Electrochem. Soc. 2014, 161(13), H3042-H3048. DOI: 10.1149/2.0091413jes Duay, J.; Goran, J. M.; Stevenson, K. J. “Facile Fabrication of Carbon Ultramicro- to Nano-electrode Arrays with Tunable Voltammetric Response,” Anal. Chem. 2014, 86(23), 11528-11532. DOI: 10.1021/ac503296x Goran, J.; Favela, C.; Stevenson, K. J. “Investigating the Electrocatalytic Oxidation of Dihydronicotinamide Adenine Dinucleotide at Nitrogen-Doped Carbon Nanotube Electrodes: Implications to Electrochemically Measuring Dehydrogenase Enzyme Kinetics,” ACS Catal. 2014, 4, 2969-2976. DOI: 10.1021/cs5006794 Stevenson, K. J.; Veneman, P. A.: Gearba, R. I.; Mueller, K. M.; Holliday, B. J.; Ohta. T.; Chan, C. K. “Controlled Covalent Modification of Epitaxial Single Layer Graphene on 6H-SiC (0001) with Aryliodonium Salts using Electrochemical Methods,” Farad. Disc. 2014, 172, 273-291. DOI: 10.1039/C4FD00038B Mueller, K. M.; Gearba, R. I.; Veneman, P. A.; Holliday, B. J.; Stevenson, K. J.; Ohta, T.; Chan, C. K. “Atom-Scale Covalent Electrochemical Modification of Single-Layer Graphene on SiC Substrates by Diaryliodonium Salts,” J. Electroanal. Chem. Soc. submitted. Dasari, R.; Tai, K.; Robinson, D. A.; Stevenson, K. J. “Electrochemical Monitoring of Single Nanoparticle Collisions at Mercury Modified Platinum Ultramicroelectrodes,”ACS Nano 2014, 8(5), 4539-4546. DOI: 10.1021/nn500045m Dylla, A.; Stevenson, K. J. “Electrochemical and Raman Spectroscopy Identification of Architectural and Morphological Transformations in Nanostructured TiO2(B),” J. Mater. Chem. A 2014, 2, 20331-20337. DOI: 10.1039/C4TA04394D Hardin, W. G.; Mefford, J. T.; Wang, X.; Dai, S.; Ruoff, R. S.; Johnston, K. P.; Stevenson, K. J. “Tuning the Electrocatalytic Activity of Perovskites Through Active Site Variation and Support Interactions,” Chem. Mater. 2014, 26, 3368−3376. DOI: 10.1021/cm403785q Lytwak, L. A.; Schroder, K. W.; Mitchell, L. A.; Stanley, J. M.; Webb, L. J.; Stevenson, K. J.; Holliday, B. J. “Electronic Properties of Alkylated and Polyfluoroalkylated Oligothiophenes as Models for Buried Electronic Interfaces in Photovoltaic Devices,” J. Amer. Chem. Soc. submitted. Long, S. R.; Ghanem, E.; Rodenbusch, S. R.; Beckham, J. T.; Shear, R. I.; Anslyn, E. V.; Robertus, J. D.; Stevenson, K. J.; Simmons, S. L. ”Teaching Through Research: Revolutionizing the Freshman Experience,” J. Chem. Ed submitted. Redman, D. W.; Murugesan, S.; Stevenson, K. J. “Cathodic Electrodeposition of Amorphous Elemental Selenium From an Air- and Water-stable Room Temperature Ionic Liquid,” Langmuir 2014, 30(1), 418-425. DOI: 10.1021/la403178j Goran, J.; Stevenson, K. J. “Electrochemical Behavior of Flavin Adenine Dinucleotide Adsorbed onto Carbon Nanotube and Nitrogen-Doped Carbon Nanotube Electrodes,” Langmuir 2013, 29(44), 13605-13613. DOI: 10.1021/la403020y Robinson, D. A.; Stevenson, K. J. “Uniform Epitaxial Growth of Pt on Fe3O4 Nanoparticles: Synergetic Enhancement of Pt Activity for the Oxygen Reduction Reaction,” J. Mater. Chem. A 2013, 1, 13443-13453. [Cover Feature] DOI: 10.1039/C3TA12987J Dasari, R.; *Walther, B.; Robinson. D. A.; Stevenson, K. J. “Influence of the Redox Indicator Reaction on Single Nanoparticle Collisions at Mercury and Bismuth Modified Platinum Ultramicroelectrodes,” Langmuir 2013, 29(48), 15100-15106. DOI: 10.1021/la402818g

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