King, Philip J. - University of Hull - Department of Chemistry

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Formation of an allylic cluster in the reactions of [Ru-3(CO)(12)] with diethylamino-propyne and trimethylsilyl propargyl alcohol. Crystal structure of [(mu-H)Ru-3(CO)(9)(mu(3)-eta(3)-C3H3)], G. Gervasio, D. Marabello, P. J. King, E. Sappa, and A. Secco, J. Organomet. Chem., 2003, 671, 137-44. doi: 10.1016/s0022-328x(03)00094-9 Transition metal carbonyl clusters with ene-yne ligands, G. Gervasio, P. J. King, D. Marabello, and E. Sappa, Inorg. Chim. Acta, 2003, 350, 215-44. doi: 10.1016/s0020-1693(02)01571-2 Surface organometallic chemistry: reaction of alkyne vapours with [Ru-3(CO)(12)] supported on inorganic oxides, P. J. King, E. Sappa, and C. Sciacca, Inorg. Chim. Acta, 2002, 334, 131-41. doi: Reactivity of multi-site bound allenylidene towards alkynes and silica gel, J. P. H. Charmant, P. J. King, R. Q. Pato, E. Sappa, and C. Schaefer, J. Chem. Soc., Dalton Trans., 2001, 46-51. doi: Synthesis and reactivity of dimetallacyclopentenone complexes [Ru-2(CO)(mu-CO){mu-C(O)(CRCR2)-C-1}(eta-C5H5)(2)] (R-1 = Me or Ph; R-2 = CO2Me), P. J. King, S. A. R. Knox, G. J. McCormick, and A. G. Orpen, J. Chem. Soc., Dalton Trans., 2000, 2975-82. doi: Transformation of dimethyl acetylenedicarboxylate to bis(methylcarboxylate)vinylidene at a diruthenium centre: unprecedented 1,2-migration of a CO2Me group, P. J. King, S. A. R. Knox, M. S. Legge, A. G. Orpen, J. N. Wilkinson, and E. A. Hill, J. Chem. Soc., Dalton Trans., 2000, 10, 1547-8. doi: Reactivity of a triruthenium acetylide complex toward alkynes and the silica-mediated dehydration of cluster-bound alkynols: X-ray crystal structures of the novel butadienyl species [Ru-3(CO)(8){mu(3)-eta(8)-C(Bu-t)=CC(Ph)=C(H)Ph}] and the unusual complex [Ru-3(CO)(5)(mu-CO){mu(3)-eta(5)-CC(Bu-t)-OC(Ph)(2)CCH}{mu(3)-eta(6)-CHC (CPh2OH)COC(CPh2)CH}], J. P. H. Charmant, G. Davies, P. J. King, J. R. Wigginton, and E. Sappa, Organometallics, 2000, 19, 2330-40. doi: Acid promoted formation of tri- and penta-ruthenium allenylidene complexes, J. P. H. Charmant, P. Crawford, P. J. King, R. Quesada-Pato, and E. Sappa, J. Chem. Soc., Dalton Trans., 2000, 4390-7. doi: 10.1039/b006146h Dehydration, hydration and substitution reactions of the hydrido acetylide complexes HRu3(CO)(9){C2CR(OH)R '}. X-ray structures and NMR fluxionality of HRu3(CO)(7)(dppm) {C2CMe(OH)Ph} and HRu3(CO)(7)(dppm) {C2C(=CH2)Ph}, G. Gervasio, R. Gobetto, P. J. King, D. Marabello, and E. Sappa, Polyhedron, 1998, 17, 2937-55. doi: Homogeneous hydrogenation of alkynes and of 1,4-cyclohexadiene in the presence of the clusters Ru-3(CO)(7)(mu-PPh2)(2)(C6H4), Ru-4(CO)(11)(mu(4)-PPh)(C6H4), Ru-3(CO)(7)(mu-PPh2)(2)(HC2Ph) and Ru-4(CO)(11)(mu(4)-PPh)(C2Ph2), M. Castiglioni, S. Deabate, R. Giordano, P. J. King, S. A. R. Knox, and E. Sappa, J. Organomet. Chem., 1998, 571, 251-60. doi: Solid-gas reactions of metal carbonyl clusters. Hydrogenation of 1,4-cyclohexadiene and hex-3-yne in the presence of H4Ru4(CO)(12), Ru-3(CO)(12) or Ru-3(CO)(3)(mu-CO)(mu(3)-CO)(mu(3)-parallel to-C2Ph2)(eta-C5H5)(2), D. Campagnola, M. Castiglioni, W. Dastru, S. Deabate, R. Giordano, P. J. King, and E. Sappa, Inorg. Chim. Acta, 1997, 262, 157-65. doi: An Unprecedented Tridentate Mode of Coordination of a Binap Ligand - Synthesis and Crystal-Structures of [Ru(Eta-5-C5h5)((R)-(Binap))]+Cf3so3- and Ru(Eta-5-C5h5)((R)-(Binap))I, D. D. Pathak, H. Adams, N. A. Bailey, P. J. King, and C. White, J. Organomet. Chem., 1994, 479, 237-45.

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