孙涛祥 - 清华大学 - 核能与新能源技术研究院

个人简介

教育背景学士 200807 北京大学化学博士 201307 北京大学化学工作履历 201307 - 201807 清华大学核研院助理研究员 201808 - 至今清华大学核研院副研究员 201908 - 202008 美国劳伦斯伯克利国家实验室访问学者学术兼职 201808 – 至今中国化学会核化学与放射化学专业委员会委员 201808 – 至今《核化学与放射化学》第九届编辑委员会委员研究概况 202001 –202312 二硫代次膦酸与镧系和锕系化合物的成键共价性研究国家自然科学基金面上项目 201901 –202212 离子液体中镧系元素的配位化学及其痕量离子的萃取研究国家自然科学基金NSAF联合基金重点项目 201801 –202106 乏燃料后处理高放废液分离技术研究（工艺研究）（第一阶段）子课题四国家国防科技工业局 201601 –201812 中国科协军民融合学会联合体青年人才托举工程中国科协 201510 –201809 高放废液蒸发浓缩脱硝过程中关键锕系元素与裂片元素的化学行为研究清华大学自主科研 201501 –201712 二(2,4,4-三甲基戊基)二硫代次膦酸萃取镧锕体系中的反相微乳液现象研究国家自然科学基金青年项目

研究领域

乏燃料后处理和高放废液分离中的流程工艺优化和相关萃取分离化学基础研究镧系和锕系化合物的成键共价性研究，采用同步辐射X射线谱学和量子化学计算相结合的方法研究f轨道参与成键行为

近期论文

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Taoxiang Sun*, Chao Xu, Xiaofeng Xie, Jing Chen, Xuegang Liu*. Quantum chemistry study on the extraction of trivalent lanthanide series by Cyanex301: Insights from formation of inner- and outer-sphere complexes. ACS Omega, 2018, 3: 4070-4080. Rong Yi, Chao Xu, Taoxiang Sun*, Yaxing Wang, Gang Ye, Shuao Wang, Jing Chen*. Improvement of the extraction ability of bis(2-propyloxy)calix[4]arene-crown-6 toward cesium cation by introducing an intramolecular triple cooperative effect. Separation and Purification Technology, 2018, 199: 97-104. Wenbing Li, Wuhua Duan, Taoxiang Sun*, Changjian Liu, Jianchen Wang, Jing Chen. Denitration of simulated high-level liquid waste by formic acid for the connection of PUREX process with TRPO process. Journal of Radioanalytical and Nuclear Chemistry, 2017, 314: 199-209. Taoxiang Sun*, Chao Xu, Jing Chen, Wuhua Duan*. Formation of W/O microemulsions in the extraction of the lanthanide series by purified Cyanex 301. Solvent Extraction and Ion Exchange, 2017, 35: 199-209. Taoxiang Sun*, Chao Xu, Jing Fu, Qingde Chen, Xinghai Shen*. Extraction of U(VI) by the ionic liquid hexyltributylphosphonium bis (trifluoromethylsulfonyl)imides: An experimental and theoretical study. Separation and Purification Technology, 2017, 188: 386-393. Taoxiang Sun*, Wuhua Duan, Yaxing Wang, Shaowen Hu, Shuao Wang, Jing Chen, Xinghai Shen*. DFT calculation and experimental validation on the interactions of bis(trifluoromethylsulfonyl)imide and hexafluorophosphate with cesium. Journal of Molecular Structure, 2017, 1148: 206-212. Taoxiang Sun*, Chao Xu, Jing Chen. Formation of W/O microemulsions in the extraction of Nd(III) by bis(2,4,4-trimethylpentyl)dithiophosphinic acid and its effect on Nd(III) coordination. Dalton Transactions, 2016, 45: 1078-1084. Taoxiang Sun*, Wuhua Duan, Jinghui Wang, Jianchen Wang, Jing Chen. Hydraulic and mass-transfer performance of a 20-mm-diameter annular centrifugal contactor for the solvent extraction of cesium by bis(2-propyloxy)calix[4]-crown-6 in n-octanol. Solvent Extraction and Ion Exchange, 2015, 33: 75-90.