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Water-soluble Bioisosteres of the ortho-substituted Phenyl Ring A. Denisenko, P. Garbuz, N. M. Voloshchuk, Y. Holota, P. K. Mykhailiuk* Nat. Chem. 2023,
General Synthesis of 3-Azabicyclo[3.1.1]heptanes and Evaluation of Their Properties as Saturated Bioisosteres D. Dibchak, M. Snisarenko, A. Mishuk, O. Shablykin, L. Bortnichuk, O. Klymenko-Ulianov, Y. Kheylik, I. V. Sadkova, H. S. Rzepa, P. K. Mykhailiuk* Angew. Chem. Int. Ed. 2023, e202304246
Catalytic undirected borylation of tertiary C–H bonds in bicyclo[1.1.1]pentanes and bicyclo[2.1.1]hexanes I. F. Yu, J. L. Manske, A. Diéguez-Vázquez, A. Misale, A. E. Pashenko, P. K. Mykhailiuk, S. V. Ryabukhin, D. M. Volochnyuk, J. F. Hartwig Nat. Chem. 2023, 15, 685-693
C−H Activation of Unbiased C(sp3)−H Bonds: Gold(I)-Catalyzed Cycloisomerization of 1-Bromoalkynes R. Miguélez, N. Semleit, C. Rodríguez-Arias, P. Mykhailiuk, J. M. González, G. Haberhauer, P. Barrio* Angew. Chem. Int. Ed. 2023, e202305296
Rapid and scalable halosulfonylation of strain-release reagents H. D. Pickford, V. Ripenko, R. E. McNamee, S. Holovchuk, A. L. Thompson, R. C. Smith, P. K. Mykhailiuk,* E. A. Anderson* Angew. Chem. Int. Ed. 2023, 62, e202213508
General and Scalable Approach to Trifluoromethyl-Substituted Cyclopropanes V. Ahunovych, A. A. Klipkov, M. Bugera, K. Tarasenko, S. Trofymchuk, O. Stanko, A. Boretskyi, M. Zheludenko, I. V. Sadkova, P. K. Mykhailiuk* J. Org. Chem. 2023, 88, 3859-3870
Fluorinated Aliphatic Diazirines: Preparation, Characterization, and Photolabeling Studies U. Kornii, O. Shablykin, T. Tarasiuk, O. Stepaniuk, V. Matvienko, D. Aloshyn, N. Zahorodniuk, P. K. Mykhailiuk* J. Org. Chem. 2023, 88, 1-17
Arylboration of Enecarbamates for the Synthesis of Borylated Saturated N-Heterocycles G. L. Trammel, P. B. Kannangara, D. Vasko, O. Datsenko, P. Mykhailiuk, M. K. Brown* Angew. Chem. Int. Ed. 2022, 61, e202212117
A Practical and Scalable Approach to Fluoro-Substituted Bicyclo[1.1.1]pentanes R. Bychek, P. K. Mykhailiuk* Angew. Chem. Int. Ed. 2022, 61, e202205103
Overcoming Limitations in Decarboxylative Arylation via Ag–Ni Electrocatalysis M. D. Palkowitz, G. Laudadio, S. Kolb, J. Choi, M. S. Oderinde, T. El-Hayek Ewing, P. N. Bolduc, T. Chen, H. Zhang, P. T. W. Cheng, B. Zhang, M. D. Mandler, V. D. Blasczak, J. M. Richter, M. R. Collins, R. L. Schioldager, M. Bravo, T. G. M. Dhar, B. Vokits, Y. Zhu, P.-G. Echeverria, M. A. Poss, S. A. Shaw, S. Clementson, N. N. Petersen, P. K. Mykhailiuk, P. S. Baran* J. Am. Chem. Soc. 2022, 121, 17709-17720
Unexpected Isomerization of Oxetane-Carboxylic Acids B. Chalyk, A. Grynyova, K. Filimonova, T. V. Rudenko, D. Dibchak, P. K. Mykhailiuk* Org. Lett. 2022, 24, 4722-4728
Fluorine-Containing Prolines: Synthetic Strategies, Applications, and Opportunities P. K. Mykhailiuk* J. Org. Chem. 2022, 87, 6961-7055
When SF5 outplays CF3: Effects of pentafluorosulfanyl decorated scorpionates on copper A. Noonikara Poyil, A. Muñoz-castro, A. Boretskyi, P. K. Mykhailiuk,* R. Dias* Chem. Sci. 2021, 12, 14618-14623
Oxa-spirocycles: synthesis, properties and applications K. Fominova, T. Diachuk, D. Granat, T. Savchuk, V. Vilchynskyi, O. Svitlychnyi, V. Meliantsev, I. Kovalchuk, E. Litskan, V. V. Levterov, V. R. Badlo, R. I. Vaskevych, A. I. Vaskevych, A. V. Bolbut, V. V. Semeno, R. Iminov, K. Shvydenko, A. S. Kuznetsova, Y. V. Dmytriv, D. Vysochyn, V. Ripenko, A. A. Tolmachev, O. Pavlova, H. Kuznietsova, I. Pishel, P. Borysko, P. K. Mykhailiuk* Chem. Sci. 2021, 12, 11294-11305
Fluorinated Pyrazoles: From Synthesis to Applications P. K. Mykhailiuk* Chem. Rev. 2021, 121, 1670-1715
Large-Scale Synthesis and Modifications of Bicyclo[1.1.1]pentane-1,3-dicarboxylic Acid (BCP) V. Ripenko, D. Vysochyn, I. Klymov, S. Zhersh, P. K. Mykhailiuk* J. Org. Chem. 2021, 86, 14061-14068
Bicyclic Pyrrolidines for Medicinal Chemistry via [3 + 2]-Cycloaddition V. I. Savych, V. L. Mykhalchuk, P. V. Melnychuk, A. O. Isakov, T. Savchuk, V. M. Timoshenko, S. A. Siry, S. O. Pavlenko, D. V. Kovalenko, O. V. Hryshchuk, V. A. Reznik, B. A. Chalyk, V. S. Yarmolchuk, E. B. Rusanov, P. K. Mykhailiuk* J. Org. Chem. 2021, 86, 13289-13309
Phosphine Oxides (−POMe2) for Medicinal Chemistry: Synthesis, Properties, and Applications M. V. Stambirskyi, T. Kostiuk, S. I. Sirobaba, A. Rudnichenko, D. L. Titikaiev, Y. V. Dmytriv, H. Kuznietsova, I. Pishel, P. Borysko, P. K. Mykhailiuk* J. Org. Chem. 2021, 86, 12783-12801
Scalable Approach to Fluorinated Heterocycles with Sulfur Tetrafluoride (SF4) S. Trofymchuk, M. Bugera, A. A. Klipkov, V. Ahunovych, B. Razhyk, S. Semenov, A. Boretskyi, K. Tarasenko, P. K. Mykhailiuk* J. Org. Chem. 2021, 86, 12181-12198
Bicyclic Piperidines via [2 + 2] Photocycloaddition V. Shcherbakova, D. Dibchak, M.Snisarenko, Y. Skalenko, A. V. Denisenko, A. S. Kuznetsova, P. K. Mykhailiuk* J. Org. Chem. 2021, 86, 2200-2209
2,2,2-Trifluorodiazoethane (CF3CHN2): A Long Journey since 1943 P. K. Mykhailiuk* Chem. Rev. 2020, 120, 22, 12718-12755
Saturated Bioisosteres of ortho‐Substituted Benzenes A. Denisenko, P. Garbuz, S. V. Shishkina, N. M. Voloshchuk, P. K. Mykhailiuk* Angew. Chem. Int. Ed. 2020, 59, 46, 20515-20521
Water‐soluble non‐classical benzene mimics V. Levterov, Y. Panasyuk, V. Pivnytska, P. K. Mykhailiuk* Angew. Chem. Int. Ed. 2020, 59, 18, 7161-7167
Deoxofluorination of (Hetero)aromatic Acids S. Trofymchuk, M. Ya. Bugera, A. A. Klipkov, B. Razhyk, S. Semenov, K. Tarasenko, V. S. Starova, O. A. Zaporozhets, O. Yu. Tananaiko, A. N. Alekseenko, Y. Pustovit, O. Kiriakov, I. I. Gerus, A. A. Tolmachev, P. K. Mykhailiuk* J. Org. Chem. 2020, 85, 5, 3110-3124
Diazoacetonitrile (N2CHCN): a long forgotten but valuable reagent for organic synthesis P. K. Mykhailiuk,* R. M. Koenigs* Сhem. Eur. J. 2020, 26, 1, 89-101
Convenient Access to Conformationally Rigid Sultams D. Dibchak, V. Scherbacova, A. V. Denisenko, P. K. Mykhailiuk* Org. Lett. 2019, 21, 22, 8909-8914
Difluoro-Substituted bicyclo[1.1.1]pentanes as Novel Motifs for Medicinal Chemistry: Design, Synthesis and Characterization R. M. Bychek, V. Hutskalova, J. P. Bas, O. A. Zaporozhets, S. Zozulia, V. V. Levterov, P. K. Mykhailiuk* J. Org. Chem. 2019, 84, 23, 15106-15117
Deoxofluorination of Aliphatic Carboxylic Acids: A Route to Trifluoromethyl-Substituted Derivatives M. Bugera. S. Trofymchuk, K. Tarasenko, O. Zaporozhets, Y. Pustovit, P. K. Mykhailiuk* J. Org. Chem. 2019, 84, 26, 16105-16115
Hindered dialkyl ether synthesis via electrogenerated carbocations J. Xiang, M. Shang, Y. Kawamata, H. Lundberg, S. Reisberg, M. Chen, P. Mykhailiuk, G. Beutner, M. Collins, A. Davies, M. Del Bel, G. Gallego, J. Spangler, J. T. Starr, S. Yang, D. Blackmond, P. Baran Nature 2019, 573, 398-402
A radical approach to anionic chemistry: synthesis of ketones, alcohols, and amines S. Ni, N. M. Padial, C. Kingston, J. C. Vantourout, D. C. Schmitt, J. T. Edwards, M. M. Kruszyk, R. R. Merchant, P. K. Mykhailiuk, B. B. Sanchez, S. Yang, M. A. Perry, G. M. Gallego, J. J. Mousseau, M. R. Collins, R. J. Cherney, P. S. Lebed, J. S. Chen, T. Qin, P. S. Baran J. Am. Chem. Soc. 2019, 141, 6726-6739
Electrochemical C(sp3)–H Fluorination Y. Takahira, M. Chen, Y. Kawamata, P. Mykhailiuk, H. Nakamura, B. K. Peters, S. H. Reisberg, C. Li, L. Chen, T. Hoshikawa, T. Shibuguchi, P. S. Baran
Carbonyl complexes of copper(I) stabilized bybridging fluorinated pyrazolates and halide ions D. Parasar, N. B. Jayaratna, A. Muñoz-Castro, A. E. Conway, P. K. Mykhailiuk, H. V. R. Dias
Quaternary Centers via Ni-Catalyzed Cross-Coupling of Tertiary Carboxylic Acids and Aryl Zinc Reagents T. -G. Chen, H. Zhang, P. K. Mykhailiuk, R. R. Merchant, C. A. Smith, T. Qin, P. S. Baran Angew. Chem. Int. Ed. 2019, 59, 2454-2458
CH-Activation of Proline analogues V. Hutskalova, P. K. Mykhailiuk* Org. Biomol. Chem. 2019, 17, 4342-4349
Saturated Bioisosteres of Benzene: Where to go Next? P. K. Mykhailiuk* Org. Biomol. Chem. 2019, 17, 2839-2849
Difluorodiazoethane (CF2HCHN2): a new reagent for the introduction of the difluoromethyl group P. K. Mykhailiuk,* R. M. Koenigs* Chem. Eur. J. 2019, 25, 6053-6063
Practical synthesis of 2,2-disubstituted spirocyclic pyrrolidines by Dieckmann condensation K. Fominova, T. Diachuk, I. Sadkova, P. K. Mykhailiuk* Eur. J. Org. Chem. 2019, 22, 3553-3559