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个人简介

2013 Office of Naval Research Young Investigator Award 2013 Ralph Powe Junior Faculty Award 2010-2012 NSF ACC-F Postdoctoral Fellow 2009-2010 CCI Solar Postdoctoral Scholar 2008 UCSC Chancellor's Dissertation Award

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K. A. Thomas Muthiah, G. Durgaprasad, Z.-L. Xie, O. M. Williams, C. Joseph, V. M. Lynch and M. J. Rose. Mononuclear Iron(II) Dicarbonyls Derived from NNS Ligands: Structural Models Related to a Possible “Pre-Acyl” Active Site of Mono-Iron (Hmd) Hydrogenase. Eur. J. Inorg. Chem. 2015. Accepted. J. Seo, H. J. Kim, R. T. Pekarek and M. J. Rose. Hybrid Organic/Inorganic Band-Edge Modulation of p-Si(111) Photoelectrodes: Effects of R, Metal Oxide, and Pt on H2 Generation. J. Am. Chem. Soc. 2015, ASAP. F. Li, V. M. Basile, R. T. Pekarek and M. J. Rose. Steric Spacing of Molecular ers on Si(111) Photoelectrodes. ACS Appl. Mater. Interfaces, 2014, 6, 20557-20568. DOI: 10.1021/am506244m J. Seo, A. Ali and M. J. Rose. Novel Ligand Architectures for Metalloenzyme Modeling: Anthracene-Based Ligands for Synthetic Modeling of Mono-[Fe] Hydrogenase. Comments Inorg. Chem. 2014, 34, 103-114. DOI: 10.1080/02603594.2014.961062 S. E. A. Lumsden, G. Durgaprasad, K. A. Thomas Muthiah and M. J. Rose. Tuning Coordination Modes of Pyridine/Thioether Schiff Base (NNS) Ligands to Mononuclear Manganese Carbonyls. Dalton Trans. 43, 2014, 10725-10738. DOI: 10.1039/c4dt00600c Y. I. Cho, D. M. Joseph, M. J. Rose. ‘Criss-Crossed’ Dinucleating Behavior of an N4 Schiff Base Ligand: Formation of a mu-O2, mu-OH Dicobalt(III) Core via O2 Activation. Inorg. Chem. 2013, 52, 13298. DOI: 10.1021/ic402391f J. R. McKone, S. Ardo, J. D. Blakemore, P. J. Bracher, J. L. Dempsey, T. V. Darnton, M. C. Hansen, W. H. Harman, M. J. Rose, M. G. Walter, S. Dasgupta, J. R. Winkler, and H. B. Gray. The Solar Army: A Case Study in Outreach Based on Solar Photoelectrochemistry. Rev. Adv. Sci. Eng. 2014, 3, 288-303. DOI: http://dx.doi.org/10.1166/rase.2014.1076 L. E. O’Leary, M. J. Rose, T. Ding, E. Johansson, B. S. Brunschwig, N. S. Lewis, Nathan. Heck Coupling of Olefins to Mixed Methyl/Thienyl Monolayers on Si(111) Surfaces. J. Am. Chem. Soc. 2013, 135, 10081. DOI: 10.1021/ja402495e M. J. Rose, H. B. Gray and J. R. Winkler. Hydrogen Generation Catalyzed by Perfluorinated Diglyoxime-Iron Complexes at Low Overpotentials. J. Am. Chem. Soc. 2012, 134, 8310. DOI: 10.1021/ja300534r M. J. Rose, J. R. Winkler and H. B. Gray. Four-Iron Cluster and a Buckled Macrocycle Complex from Reduction of [(dmgBF2)Fe(L)2] (L=MeCN, tBuiNC). Inorg. Chem. 2012, 51, 1980. DOI: 10.1021/ic202253v M. J. Rose, D. E. Bellone and H. B. Gray. Spectroscopic and Magnetic Characterization of an Iodo Co(I) Tripodal Phosphine Complex. Dalton Trans. 2012, 41, 11788. DOI: 10.1039/C2DT31229H Q. Dong, M. J. Rose, W.-Y. Wong and H. B. Gray. Dual Coordination Modes of Ethylene ed NP2 Ligands with Cobalt(II) and Nickel(II) Iodides. Inorg. Chem. 2011, 50, 10213. DOI: 10.1021/ic201213c M. J. Rose, N. M. Betterley, A. Oliver, and P. K. Mascharak. Binding and Photorelease of Nitric Oxide (NO) to a Synthetic Model of Iron-Containing Nitrile Hydratase (Fe-NHase). Inorg. Chem. 2010, 49, 1854-1864. DOI: 10.1021/ic902220a M. J. Rose, A. K. Patra, M. M. Olmstead and P. K. Mascharak. Structural and Spectroscopic Evidence for age Isomerism of Bound Nitrite in a {Fe-NO}6 Nitrosyl derived from a Tetradentate Dicarboxamide Ligand: More Parallels between Heme and Non-heme Systems. Inorg. Chim. Acta 2010, 363, 2715. N. Fry, M. J. Rose, David L. Rogow, C. Nyitray, Manpreet Kaur and P. K. Mascharak. Ruthenium Nitrosyls Derived from Tetradentate Ligands containing Carboxamido-N and Phenolato-O Donors: Syntheses, Structures, Photolability and Time-Dependent Density Functional Studies. Inorg. Chem. 2010, 49, 1487. DOI: 10.1021/ic9017129 M. J. Rose, N. M. Betterley, P. K. Mascharak. Thiolate S-Oxygenation Controls Nitric Oxide (NO) Photolability of a Synthetic Iron Nitrile Hydratase (Fe-NHase) Model Derived from Mixed Carboxamide/Thiolate Ligand. J. Am. Chem. Soc. 2009, 131, 8340-8341. DOI: 10.1021/ja9004656 M. J. Rose, P. K. Mascharak. Photosensitization of Ruthenium Nitrosyls to Visible Light with an Isoelectronic Series of Heavy-Atom Chromophores: Experimental and DFT Studies on the Effects of O-, S- and Se-Substituted Coordinating Dyes. Inorg. Chem. 2009, 48, 6904-6917. DOI: 10.1021/ic900899j N. Fry, M. J. Rose, C. Nyitray, and P. K. Mascharak. Metal Nitrosyls with Phosphine Ligation: Unexpected Ligand Oxidation and Ring Nitration. Inorg. Chem. 2008, 47, 11604-11610. DOI: 10.1021/ic801243a M. J. Rose and P. K. Mascharak. A Photosensitive {Ru-NO}6 Nitrosyl Bearing Dansyl Chromophore: Novel NO Donor with a Fluorometric On/Off Switch. Chem. Commun. 2008, 3933-3935. DOI: 10.1039/B805332D M. J. Rose, N. Fry, R. Marlow, L. Hinck and P. K. Mascharak. Ruthenium Nitrosyls bearing Coordinated Fluorophores as NO Donors: a Novel Mode of Fluorometric Delivery of NO to Cells with Visible Light. J. Am. Chem. Soc. 2008, 130, 8834-8846. DOI: 10.1021/ja801823f

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