个人简介
汤浩，博士，教授。2014年硕博连读毕业于吉林大学，期间在中国科学院化学所光化学实验室姚建年院士和陈辉研究员课题组联合培养1年。2014-2021年在美国Texas A&M University化学系从事博士后研究工作。2021年4月加入温州大学化学与材料工程学院从事教学科研工作。主要从事理论与计算化学研究，研究领域包括无机电催化、有机过渡金属催化、仿生酶催化机理。近年来已在仿生镍铁氢化酶质子还原机理、复杂过渡金属复合物电子结构分析及其氢气氧化和析氢反应机制等氢能源研究方面取得了一些创新性成果，得到了国内外同行的认可和好评。目前已在国际学术期刊发表SCI 论文17篇，其中以第一作者身份发表学术论文12篇，ESI高被引论文1篇， 包括J. Am. Chem. Soc.、ACS Catalysis、Inorganic Chemistry、J. Org. Chem.、Dalton Transactions、Physical Chemistry Chemical Physics、Journal of Computational Chemistry等 。曾参加了多次美国化学会年会和美国高登学术会议等国际学术会议并做了相关工作报告，与国际氢化酶领域顶级实验课题组有深厚的合作基础。
曾荣获吉林大学“唐敖庆化学”奖学金、“博士研究生杰出人才培育资助计划”、连续两年博士研究生国家奖学金、吉林大学优秀博士毕业论文、温州大学2021年“教师课堂教学竞赛”一等奖。
教育及工作经历
2021.04 ― 至今 教授，温州大学，化学与材料工程学院
2014.09 ― 2021.03 博士后，美国Texas A&M University 化学系，合作导师：Michael B. Hall
2013.03 ― 2014.06 中国科学院化学所，光化学实验室，姚建年院士、陈辉研究员课题组联合培养
2009.09 ― 2014.06 博士，吉林大学理论化学研究所、理论化学计算国家重点实验室硕博连读 ，导师：孙家钟院士、黄旭日教授
2005.09 ― 2009.07 理学学士，辽宁师范大学，化学化工学院
近期论文
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Sam Yruegas, Hao Tang, Gayle Z. Bornovski, Xiaojun Su, Siyoung Sung, Michael B. Hall,* Michael Nippe,* Caleb D. Martin.* Nickel−Borolide Complexes and Their Complex Electronic Structure. Inorganic Chemistry, 2021, 60, 16160–16167. doi.org/10.1021/acs.inorgchem.1c01845.
Hao Tang, Tyler M. Porter, Clifford P. Kubiak, Michael B. Hall.* Full Conformational Analyses of the Ultrafast Isomerization in Penta-coordinated Ru(S2C2(CF3)2)(CO)(PPh3)2: One Compound, Two Crystal Structures, Three CO Frequencies, 24 Stereoisomers, and 48 Transition States. Inorganic Chemistry, 2020, 59, 11757–11769.
Hao Tang, Edward N. Brothers, Craig A. Grapperhaus,* Michael B Hall.* Electrocatalytic Hydrogen Evolution and Oxidation with Rhenium Tris(thiolate) Complexes: A Competition between Rhenium and Sulfur for Electrons and Protons. ACS Catalysis, 2020, 10, 3778–3789. DOI: 10.1021/acscatal.9b04579.
Deborah Brazzolotto,† Lianke Wang,† Hao Tang,† Marcello Gennari, Nicolas Queyriaux, Christian Philouze, Serhiy Demeshko, Franc Meyer, Maylis Orio, Vincent Artero,* Michael B. Hall,* Carole Duboc.* Tuning Reactivity of Bioinspired [NiFe]-Hydrogenase Models by Ligand Design and Modeling the CO Inhibition Process. ACS Catalysis, 2018, 8, 10658–10667. DOI: 10.1021/acscatal.8b02830. (†共同一作)
Hao Tang, Michael B Hall.* Biomimetics of [NiFe]-Hydrogenase: Nickel- or Iron-Centered Proton Reduction Catalysis? J. Am. Chem. Soc., 2017, 139, 18065–18070. DOI: 10.1021/jacs.7b10425.
Hao Tang, Edward N. Brothers, Michael B Hall.* The Distinctive Electronic Structures of Rhenium Tris(thiolate) Complexes, an Unexpected Contrast to the Valence Isoelectronic Ruthenium Tris(thiolate) Complexes. Inorganic Chemistry, 2017, 56, 583–593. DOI: 10.1021/acs.inorgchem.6b02434.
Yihua Sun, Hao Tang, Kejuan Chen, Lianrui Hu, Jiannian Yao, Sason Shaik, Hui Chen.* Two-State Reactivity in low-Valent Iron-Mediated C-H Activation and the Implications for Other First-Row Transition Metals. J. Am. Chem. Soc., 2016, 138, 3715–3730. DOI: 10.1021/jacs.5b12150.
Hao Tang, Jia Guan, Michael B Hall.* Understanding the Radical Nature of an Oxidized Ruthenium Tris(thiolate) Complex and Its Role in the Chemistry. J. Am. Chem. Soc., 2015, 137, 15616–15619. DOI: 10.1021/jacs.5b09309. (ESI高被引论文)
Hao Tang, Xuri Huang,* Jiannian Yao, Hui Chen.* Understanding the Effects of Bidentate Directing Groups: A Unified Rationale for sp2 and sp3 C-H Bond Activations. J. Org. Chem., 2015, 80, 4672–4682. DOI: 10.1021/acs.joc.5b00580.
Hao Tang, Bingwei Zhou, Xuri Huang,* Congyang Wang,* Jiannian Yao, Hui Chen.* Origins of Selective C(sp2)-H Activation Using Transition Metal Complexes with N,N-Bidentate Directing Groups: A Combined Theoretical-Experimental Study. ACS Catalysis, 2014, 4, 649–656. DOI: 10.1021/cs401141k.
Yanwei Sun, Haiyang Jiang, Hao Tang, Haixia Xu, Huiling Liu,* Kai Sun, Xuri Huang. Theoretical Investigation on the Mechanism of FeCl3 Catalyzed Cross-Coupling Reaction of Alcohols with Alkenes. Molecular Physics, 2014, 112, 2107–2113. DOI: 10.1080/00268976.2014.886738.
Lili Zhang, Huiling Liu, Hao Tang, Xuri Huang. Theoretical investigation on the reaction of HS+ with CH3NH2. Chemical Papers, 2014, 68, 145–152. DOI: 10.2478/s11696-013-0412-y.
Hao Tang, Jia Guan, Huiling Liu,* Xuri Huang.* Comparative Insight into Electronic Properties and Reactivities toward C−H Bond Activation by Iron(IV)−Nitrido, Iron(IV)−Oxo, and Iron(IV)−Sulfido Complexes: A Theoretical Investigation. Inorganic Chemistry, 2013, 52, 2684–1696. DOI: 10.1021/ic302766f.
Hao Tang, Jia Guan, Huiling Liu,* Xuri Huang.* Analysis of an alternative to the H-atom abstraction mechanism in methane C−H bond activation by nonheme iron(IV)–oxo oxidants. Dalton Transactions, 2013, 42, 10260–10270. DOI: 10.1039/C3DT50866H.
Hao Tang, Zhuo Li, Yuhong Yang, Ying Zhao, Suqin Wan, Huiling Liu,* Xuri Huang.* Comparison of the FeO2+ and FeS2+ Complexes in the Cyanide and Isocyanide Ligand Environment for Methane Hydroxylation. Journal of Computational Chemistry, 2012, 33, 1448–1457. DOI: 10.1002/jcc.22978.
Hao Tang, Jia Guan, Lili Zhang, Huiling Liu,* Xuri Huang.*, The effect of the axial ligand on distinct reaction tunneling for methane hydroxylation by nonheme iron(IV)-oxo complexes. Physical Chemistry Chemical Physics, 2012, 14, 12863–12874. DOI: 10.1039/C2CP42423A.
Hongbo Xu, Huiling Liu, Jianchao Song, Yan Li, Yuhong Yang, Hao Tang, Xuri Huang. Theoretical Study on the Reaction of PH+ with H2O. Computational and Theoretical Chemistry, 2011, 966, 328–333. DOI: 10.1016/j.comptc.2011.03.031.
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