Clever, Guido - Georg-August-Universitäten Göttingen

研究领域

Chemistry inside Molecular Cages: Molecular cages and capsules provide nanoscopic environments which can be used as the smallest imaginable reaction flasks. Immobilization of catalytically active entities such as transition metals inside these engineered cavities is envisioned to lead to a promising new class of catalysts on the long way to artificial systems with enzyme-like substrate specificity, selectivity and turn-over. DNA-Supramolecular Hybrid Structures: In recent years, DNA has become popular as a programmable building material in bottom-up nanotechnology. DNA origami and Metal DNA are prominent examples. In combination with the various techniques of the supramolecular chemistry toolbox (host-guest binding, metal-coordination, aggregation of amphiphilic residues...) new functional systems with a focus on nano-mechanical devices are being developed.

近期论文

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"Triggered Exchange of Anionic for Neutral Guests inside a Cationic Coordination Cage" S. Löffler, J. Lübben, L. Krause, D. Stalke, B. Dittrich, G. H. Clever, J. Am. Chem. Soc. 2015, accepted, DOI: 10.1021/ja5130379. "Modular synthesis of linear bis- and trismonodentate fused [6]polynorbornane-based ligands and their assembly into coordination cages" M. D. Johnstone, E. K. Schwarze, G. H. Clever and F. M. Pfeffer, Chem. Eur. J. 2015, accepted, DOI: 10.1002/chem.201405037. "Stepwise Halide-triggered Double- and Triple-Catenation of Self-Assembled Coordination Cages" R. Zhu, J. Lübben, B. Dittrich, G. H. Clever, Angew. Chem. Int. Ed. 2014, accepted, DOI: 10.1002/anie.201408068R1. "Molecular topology: Star-crossed self-assembly" (News &Views) G. H. Clever, Nature Chem. 2014, 6, 950. "SERS spectroscopic evidence for the integrity of surface-deposited self-assembled coordination cages" M. Frank, S. Funke, H. Wackerbarth, G. H. Clever, Phys. Chem. Chem. Phys. 2014, 16, 21930. "Subtle backbone modifications control the interpenetration of dibenzosuberone-based coordination cages" T. Schulte, M. Krick, C. I. Asche, S. Freye, G. H. Clever, RSC Adv. 2014, 4, 29724. "Self-Assembled Coordination Cages based on Banana-shaped Ligands" M. Han, D. M. Engelhard, G. H. Clever, Chem. Soc. Rev. 2014, 43, 1848. "Narcissistic self-sorting vs. statistic ligand shuffling within a series of phenothiazine-based coordination cages" M. Frank, L. Krause, R. Herbst-Irmer, D. Stalke, G. H. Clever, Dalton Trans. 2014, 43, 4587. "Rational Design of a Face-Centred Square-Cuboid Coordination Cage" M. Han, R. Michel, G. H. Clever, Chem. Eur. J. 2014, 20, 10640. "Reversible Stabilization of Transition Metal-binding DNA G-Quadruplexes" D. M. Engelhard, R. Pievo, G. H. Clever, Angew. Chem. Int. Ed. 2013, 52, 12843. "Relative Anion Binding Affinity in a Series of Interpenetrated Coordination Cages" M. Frank, J. M. Dieterich, S. Freye, R. A. Mata, G. H. Clever, Dalton Trans. 2013, 42, 15906. "Rapid, solvent-free, synthesis of pyridyl-functionalised [5]polynorbornane-based ligands for metal-organic rings and cages" M. D. Johnstone, M. Frank, G. H. Clever, F. M. Pfeffer, Eur. J. Org. Chem. 2013, 26, 5848. "Assembly and Stepwise Oxidation of Interpenetrated Coordination Cages based on Phenothiazine" M. Frank, J. Hey, I. Balcioglu, Y.-S. Chen, D. Stalke, T. Suenobu, S. Fukuzumi, H. Frauendorf, G. H. Clever, Angew. Chem. Int. Ed. 2013, 52, 10102. "Template Control over Dimerization and Guest Selectivity of Interpenetrated Coordination Cages" S. Freye, R. Michel, D. Stalke, M. Pawliczek, H. Frauendorf, G. H. Clever, J. Am. Chem. Soc. 2013, 135, 8476. (Highlighted in the ACS Virtual Issue on "Synthetic Inorganic Chemistry" 2013). "Stable and Metastable Self-Assembled Rings based on trans-chelated Pd(II)" F. A. Pereira, T. Fallows, M. Frank, A. Chen, G. H. Clever, Z. Anorg. Allg. Chem. 2013, 639, 1598–1605. "Counter Ion Dynamics in an Interpenetrated Coordination Cage Capable of Dissolving AgCl" S. Freye, D. M. Engelhard, M. John, G. H. Clever, Chem. Eur. J. 2013, 19, 2114. "Light-triggered Guest Uptake and Release by a Photochromic Coordination Cage" M. Han, R. Michel, B. He, Y.-S. Chen, D. Stalke, M. John, G. H. Clever, Angew. Chem. Int. Ed. 2013, 52, 1319. ("Hot Paper") "Artificial DNA directed toward synthetic Metallo-Foldamers" G. H. Clever and M. Shionoya, in "Metallofoldamers: Supramolecular Architectures from Helicates to Biomimetics" G. Maayan, M Albrecht (Eds.), Wiley-VCH, Weinheim, 2013, ISBN: 978-0-470-97323-3