Ye, Qing - Julius-Maximilians-Universität Würzburg - Institute for Inorganic Chemistry

个人简介

Qing Ye is Professor of Inorganic Molecular Chemistry at the University of Würzburg since January 2022. After receiving his B.S. degree in chemistry from the Fudan University in 2004, he went to the University of Würzburg (JMU) where he completed Diplom and graduate studies in borylene chemistry under the supervision of Prof. H. Braunschweig (Ph.D. 2012), with the highest mark (summa cum laude). After his graduate work he was further appointed as a postdoctoral research fellow (2012-4). During this period, he developed the chemistry of boron-centered Lewis bases. In 2015 he was appointed as a DFG-sponsored postdoctoral fellow to work on two-coordinate transition metal complexes with Prof. T. Don Tilley at the University of California at Berkeley (2015). In 2016, he received a DFG Return Fellowship and joined the research group of Prof. T. B. Marder at JMU. In 2017, he began his independent research career as an Associate Professor at the Southern University of Science and Technology (2017-22). In 2022, Ye accepted appointment as Professor of Inorganic Chemistry at the University of Würzburg. Ye's research interests at JMU include the synthesis and investigation of highly strained heterocyclic molecules, the development of boron cluster-functionalized Lewis superacids and their application in catalysis and optoelectronic materials, and the use of boron in secondary coordination sphere engineering. While at JMU, Prof. Ye received the national scholarship for outstanding self-funded international students (2012), the Preis der Unterfränkischen Gedenkjahrstiftung für Wissenschaft und die JMU (2013). At UC Berkeley, Ye received a DFG reserach fellowship (2015). He was the recipient of the National Young Talent Program of China (2016), Peacock Plan Awardee-Category B by Shenzhen Municipal Government (2017).

研究领域

The current research topics in the Ye group are based on three molecular systems: bis(alkynyl)boranes as a new class of acyclic π-ligands boron-containing fused polycyclic π-systems and the three-dimensional analogues boron-based super electron donors (SEDs) We are not noly interested in the fundamental aspects (blue), but wll also be devoted to the development of their applications (green).

近期论文

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L. Xiang, J. Wang, I. Krummenacher, K. Radacki, H. Braunschweig, Z. Lin, Q. Ye*, Persistent and Predominantly Localized Boron Radical from the Reduction of a Three-dimensional Analogue of NHC-Stabilized Borafluorenium, Chem. Eur. J. accepted (2023). J. Wang, S. Zhu, W. Ma, Z. Lin*, Q. Ye*, BN-Butafulvenes and Their Application in the Synthesis of Highly Substituted BN-9,1-Naphthalenes, Angew. Chem. Int. Ed. accepted (2023). Y. Wei#, J. Wang#, W. Yang, Z. Lin*, Q. Ye*, Boosting Ring Strain and Lewis Acidity of Borirane: Synthesis, Reactivity and Density Functional Theory Studies of an Uncoordinated Arylborirane Fused to o-Carborane, Chem. Eur. J. 29, e202203265 (2022). (# equal contribution) C. Zhang#, J. Wang#, Z. Lin, Q. Ye*, Synthesis, Characterization, and Properties of Three-Dimensional Analogues of 9-Borafluorenes, Inorg. Chem. 61, 18275 (2022). (# equal contribution) W. Su, T. Rajeshkumar, L. Xiang, L. Maron*, Q. Ye*, Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2-Insertion of CO into a U-N Bond, Angew. Chem. Int. Ed. e202212823 (2022). C. Zhang, X. Liu, J. Wang, Q. Ye*, A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene – A Lewis Superacidic Azido Borane with Reactivity and Stability,Angew. Chem. Int. Ed. 61, e202205506 (2022). J. Wang, P. Jia, W. Sun, Y. Wei, Z. Lin, Q. Ye*, Synthesis of Iminoboryl o-Carboranes by Lewis Base Promoted Aminoborirane-to-Iminoborane Isomerization, Inorg. Chem. 61, 8879 (2022). Y. Dai, X. Zhang, Y. Liu, H. Yu, W. Su, J. Zhou, Q. Ye*, Z. Huang*, 1,6;2,3-Bis-BN-cyclohexane: Synthesis, structure and hydrogen release, J. Am. Chem. Soc. 144, 8434 (2022). L. Xiang, J. Wang, W. Su, Z. Lin, Q. Ye*, Facile Access to Halogenated Cationic B=C-centered Organoboron Isoelectronic with Alkenyl Halides, Dalton Trans. 50, 17491 (2021). C. Zhang, J. Wang, W. Su, Z. Lin*, Q. Ye*, Synthesis, Characterization and Density Functional Theory Studies of Three-Dimensional Inorganic Analogues of 9,10-Diboraanthracene – a New Class of Lewis Superacids, J. Am. Chem. Soc. 143, 8552 (2021). Highlighted as "Supplementary Cover" W. Su, Y. Ma, L. Xiang, J. Wang, S. Wang, L. Zhao*, G. Frenking*, Q. Ye*, Isolation of a Uranium(III)‐Carbon Multiple Bond Complex, Chem. Eur. J. 27, 10006 (2021). Highlighted as "Hot Paper" W. Ming, X. Liu, L. Mao, X. Gu, Q. Ye*, Transition-Metal-Catalyzed Synthesis of Chiral Allylboronates, Chin. J. Chem. 39, 1716 (2021). H. Zhang,# J. Wang,# W. Yang,# L. Xiang, W. Sun, W. Ming, Y. Li, Z. Lin*, Q. Ye*, Solution-Phase Synthesis of a Base-Free Benzoborirene and a Three-Dimensional Inorganic Analogue, J. Am. Chem. Soc. 142, 17243 (2020). (# equal contribution) W. Ma, I. Douair, L. Maron*, Q. Ye*, Incorporation of Boron into Uranium Metallacycles: Synthesis, Structure and Reactivity of Boron‐containing Uranacycles Derived from Bis(alkynyl)boranes, Chem. Eur. J. 26, 13573 (2020). Highlighted as "Cover Feature". J. Maier, M. Deutsch, J. Merz, Q. Ye, O. Diamond, M.-T. Schilling, A. Friedrich, B. Engels*, T. B. Marder*, Highly Conjugated π‐Systems Arising from Cannibalistic Hexadehydro‐Diels‐Alder Couplings: Cleavage of C‒C Single and Triple Bonds, Chem. Eur. J. 26, 15989 (2020). L. Ma,# X. Zhang,# W. Ming,# S. Su, X. Chang, Q. Ye*, Reactions of Dihaloboranes with Electron-Rich 1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadienes, invited paper for Todd B. Marder 65th birthday issue, Molecules 25, 2857 (2020). (# equal contribution) Y. Cui,# L. Xiang,# J. Wang, C. Li, W. Hao, Q. Ye*, Storage and release of two electrons from an electron-rich carbon-carbon bond: boron mediated reversible coupling of DMAP and 9-azajulolidine, Chem. Commun. 56, 6794 (2020). (# equal contribution) L. Mao,# C. Li,# L. Xiang, D. Fu, W. Ma, Q. Ye*, Synthesis of Allenyl-Bdan via a Cu(I)-catalyzed Borylation of Propargylic Alcohols with the Unsymmetric Diboron Reagent (Bpin-Bdan), J. Org. Chem. 85, 2823 (2020). (# equal contribution) S. K. Mellerup, Y. Cui, F. Fantuzzi, P. Schmid, J. T. Goettel, G. Bélanger-Chabot, M. Arrowsmith, I. Krummenacher, Q. Ye, V. Engel, B. Engels, H. Braunschweig*, Lewis-Base Stabilization of the Parent Al(I) Hydride under Ambient Conditions, J. Am. Chem. Soc. 141, 16954 (2019). W. Ma, J.-X. Zhang, Z. Lin*, T. D. Tilley, Q. Ye*, Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium (II) complexes, Dalton. Trans. 48, 14962 (2019). J. Wang, Y. Cui, Q. Ye*, Bis(alkynyl)borane: A New Class of Acyclic Boron-Containing π Ligands in η5-Coordination Mode, Inorg. Chem. 58, 11279 (2019). Q. Ye, M. S. Ziegler, K. V. Lakshmi, T. D. Tilley*, Titanium Imido Complexes via Displacement of –SiMe3 and C–H Bond Activation in a Ti(III) Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC), Eur. J. Inorg. Chem. 18, 2484 (2017). H. Braunschweig*, I. Krummenacher, M.-A. Légaré, A. Matler, K. Radacki, Q. Ye, Main-Group Metallomimetics — Unprecedented Transition Metal-like Photolytic CO Substitution at Boron, J. Am. Chem. Soc.139, 1802 (2017). H. Braunschweig*, A. Damme, R. D. Dewhurst, K. Radacki, F. Weißenberger, B. Wennemann, Q. Ye, Fundamental differences between group 8 metals: divergent oxidation state preferences and mechanisms in Fe/Ru borylene formation, Chem. Eur. J. 8471 (2016). H. Braunschweig,* R. D. Dewhurst, L. Pentecost, K. Radacki, A. Vargas, Q. Ye, Dative Bonding Between Group 13 Elements Using a Boron-Centered Lewis Base, Angew. Chem. Int. Ed. 55, 436 (2016). H. Braunschweig*, R. D. Dewhurst, F. Hupp, M. Nutz, K. Radacki, C. W. Tate, A. Vargas, Q. Ye, Multiple complexation of CO and related ligands to a main-group element, Nature 522, 327 (2015). H. Braunschweig*, Q. Ye, M. A. Celik, K. Radacki, R. D. Dewhurst, Cyclization of a 1,4-Diborabutadiene Ligand with Both Atoms of CO, Angew. Chem. Int. Ed. 54, 5065 (2015). H. Braunschweig*, R. D. Dewhurst, K. Radacki, B. Wennemann, Q. Ye, 1,2-Halosilane vs. 1,2-alkylborane elimination from (boryl)(silyl) complexes of iron: switching between borylenes and silylenes just by changing the alkyl group, Chem. Commun. 51, 15468 (2015). H. Braunschweig*, A. Damme, R. D. Dewhurst, H. Kelch, B. B. Macha, K. Radacki, A. Vargas, Q. Ye, Platinum trans-Bis(borirene) Complexes Displaying Coplanarity and Communication Across a Platinum Metal Center, Chem. Eur. J. 21, 2377 (2015). Highlighted as "Front Cover" H. Braunschweig*, Q. Ye, A. Vargas, R. D. Dewhurst, F. Hupp, Complete and Partial 1,2-Additions Across Transition Metal-Boron Double Bonds, J. Am. Chem. Soc. 136, 9560 (2014). S. Bertsch, H. Braunschweig*, R. D. Dewhurst, K. Radacki, C. Saalfrank, B. Wennemann, Q. Ye, Partially and Fully Reversible Solvation-Controlled Borylene Swapping and Metal-Only Lewis Pair Formation, Organometallics, 33, 3649 (2014). H. Braunschweig*, R. D. Dewhurst, F. Hupp, C. Kaufmann, A. K. Phukan, C. Schneider, Q. Ye, Gauging Metal Lewis Basicity of Zerovalent Iron Complexes via Metal-Only Lewis Pairs, Chem. Sci. 5, 4099 (2014). S. Bertsch, R. Bertermann, H. Braunschweig*, A. Damme, R. D. Dewhurst, A. K. Phukan, C. Saalfrank, A. Vargas, B. Wennemann, Q. Ye, Metal-Only Lewis Pairs by Reversible Insertion of Ruthenium and Osmium Fragments into Metal-Boron Double Bonds, Angew. Chem. Int. Ed. 53, 4240 (2014).