当前位置: X-MOL首页全球导师 国内导师 › 徐超

个人简介

教育背景 理学学士 200407 北京大学 化学与分子工程学院 应用化学 理学博士 200907 北京大学 化学与分子工程学院 应用化学 工作履历 200908 - 201411 清华大学 核能与新能源技术研究院 助理研究员 201110 - 201309 美国劳伦斯伯克利国家实验室 博士后/访问科学家 201412 - 201911 清华大学 核能与新能源技术研究院 副研究员/准聘副教授 201912 – 至今 清华大学 核能与新能源技术研究院 长聘副教授/研究室副主任 奖励与荣誉 2019 中国化学会青年化学家元素周期表Am元素代言人 2017 国防科学技术进步奖 二等奖 生产堆高放废液萃取法全分离技术

研究领域

放射性废物高效分离和处理技术(溶剂萃取、功能材料吸附等) 锕系及镧系离子基础配位化学(侧重配位热力学) 环境放射化学(锕系离子在环境中的络合、氧化还原及迁移行为)

近期论文

查看导师新发文章 (温馨提示:请注意重名现象,建议点开原文通过作者单位确认)

Lei Xu, Ning Pu, Gaoyang Ye, Chao Xu*, Jing Chen, Xingwang Zhang, Lecheng Lei, Chengliang Xiao. Unraveling the complexation mechanism of actinide(III) and langthanide(III) with a new tetradentate phenanthroline-derived phosphonate ligand. Inorgnic Chemistry Frontiers, 2020, 7: 1726-1740. 董雪,徐超*,陈靖。核燃料循环中镅的氧化分离研究进展。化学通报,2020, 83(4):289-295。 Youzhen Li, Xue Dong, Jianhua Yuan, Ning Pu, Pingping Wei, Taoxiang Sun, Weiqun Shi, Jing Chen, Jianchen Wang*, Chao Xu*. Performance and Mechanism for the Selective Separation of Trivalent Americium from Lanthanides by a Tetradentate Phenanthroline Ligand in Ionic Liquid. Inorganic Chemistry, 2020, 59(6): 3905-3911. Lei Xu#, Ning Pu#, Jianhua Yuan, Pingping Wei, Xue Dong, Yingcai Wang, Jing Chen, Chao Xu*. Ligand rigidity and electronic effect on the complexation of hexavalent plutonyl with three dicarboxylic acids: a combined spectrophotometric and computational study. New Journal of Chemistry, 2020, 44: 3998-4003. Ning Pu, Jing Su, Lei Xu, Taoxiang Sun, Enrique R. Batista, Jing Chen, Ping Yang*, Jenifer C. Shafer*, Chao Xu*. “Sweeping” Ortho Substituents Drive Desolvation and Overwhelm Electronic Effects in Nd3+ Chelation: A Case of Three Aryldithiophosphinates. Inorganic Chemistry, 2020, 59(1): 161-171. Pingping Wei#, Ning Pu#, Xue Dong, Jianhua Yuan, Youzhen Li, Jing Chen, Lei Xu*, Chao Xu*. Structural and Stability Trends of the Complexation of Hexavalent Actinides and Two Dipicolinic Acid Derivatives: An Experimental and Theoretical Study. Inorganic Chemistry, 2019, 58(17): 11664-11671. Xinrui Zhang, Qunyan Wu, Jianhui Lan, Liyong Yuan, Chao Xu*, Zhifang Chai, Weiqun Shi*. Highly Selective Extraction of Pu (IV) and Am (III) Actinides by N,N’-diethyl-N,N’-ditolyl-2,9-diamide-1,10-phenanthroline Ligand: An Experimental and Theoretical Study. Separation and Purification Technology, 2019, 223: 274-281. Yanqiu Yang, Zhicheng Zhang, Liang Yang, Jun Liu, Chao Xu*, Shunzhong Luo, Linfeng Rao*. Complexation of U(VI) with BiPDA, DmBiPDA and PhenDA: Comparison on Structures and Binding Strengths in Aqueous and DMSO/20%(v)H2O Solutions. Inorganic Chemistry, 2019, 58(9): 6064-6074. Ning Pu, Lei Xu, Taoxiang Sun, Jing Chen*, Chao Xu*.Tremendous impact of substituent group on the extraction and selectivity to Am(III) over Eu(III) by diaryldithiophosphinic acids: experimental and DFT analysis. Journal of Radioanalytical and Nuclear Chemistry, 2019, 320: 219-226. Lei Xu#, Ning Pu#, Youzhen Li, Pingping Wei, Taoxiang Sun, Chengliang Xiao*, Jing Chen*, Chao Xu*. Selective Separation and Complexation of Trivalent Actinide and Lanthanide by a Tetradentate Soft–Hard Donor Ligand: Solvent Extraction, Spectroscopy, and DFT Calculations. Inorganic Chemistry, 2019, 58(7): 4420-4430. Zhipeng Wang#, Ning Pu#, Yin Tian*, Chao Xu*, Fang Wang, Ying Liu, Lirong, Zhang, Jing Chen, Songdong Ding*. Highly selective separation of actinides from lanthanides by dithiophosphinic acids: an in-depth investigation on extraction, complexation and DFT calculations. Inorganic Chemistry, 2019, 58(9): 5457-5467. Jiahao Dang, Wuhua Duan, Wenchao Wu, Taoxiang Sun, Youzhen Li, Ning Pu, Lei Xu, Jing Chen, Chao Xu*. Coordination of Nd(III) and Eu(III) with monodentate organophosphorus ligands in ionic liquids: spectroscopy and thermodynamics. New Journal of Chemistry, 2019, 43: 3866-3873. Lina Lv, Baihua Chen, Jun Liu, Jing Chen, Chao Xu*, Yanqiu Yang*. A Structural and Thermodynamic Study of the Complexes of U(VI) with Azinecarboxylates. Dalton Transactions, 2019, 48: 566-577. 张利荣,王志鹏,刘莹,徐超*,陈靖,丁颂东*. 二(2-乙基己基)二硫代次膦酸对硝酸溶液中Am3+和Eu3+的萃取. 高等学校化学学报, 2019, 40(1): 1-10. Lirong Zhang, Zhipeng Wang, Ying Liu, Chao Xu*, Jing Chen, Songdong Ding*. Extraction of trivalent americium and europium from nitric acid solution with Di(2-ethylhexyl) dithiophosphinic acid. Chemical Journal of Chinese Universities-Chinese. 2019, 40(1): 1-10. Lei Xu, Anyun Zhang*, Ning Pu, Chao Xu, Jing Chen. Development of Two novel silica based symmetric triazine-ring opening N-donor ligands functional adsorbents for highly efficient separation ofpalladium from HNO3 solution. Journal of Hazardous Materials. 2019, 376: 188-199. Zhe Wang, Yu Xie, Zhen Lei, Yuexiang Lu*, Guoyu Wei, Shuang Liu, Chao Xu, Zhicheng Zhang, Xiangke Wang, Linfeng Rao*, Jing Chen*. Quantitative Analysis of Surface Sites on Carbon Dots and Their Interaction with Metal Ions by a Potentiometric Titration Method. Analytical Chemistry. 2019, 91, 9690-9697. Francesco Endrizzi*, Xavier Gaona*, Zhicheng Zhang, Chao Xu, Linfeng Rao, Carmen Garcia-Perez, Marcus Altmaier. Thermodynamic description of U(VI) solubility and hydrolysis in dilute to concentrated NaCl solutions at T = 25, 55 and 80 °C. Radiochimica Acta. 2019, 107(8): 663-678. Jipan Yu#, Liyong Yuan#, Shuai Wang#, Jianhui Lan, Lirong Zheng, Chao Xu, Jing Chen, Lin Wang, Zhiwei Huang, Wuqing Tao, Zhirong Liu, Zhifang Chai, John K. Gibson and Weiqun Shi*. Phosphonate Decorated Covalent Organic Frameworks for Actinide Extraction: a Breakthrough under Highly Acidic Conditions. CCS Chemistry. 2019, 1(3): 286-295. Lei Mei, Feize Li, Jianhui Lan, Congzhi Wang, Chao Xu, Hao Deng, Qunyan Wu, Kongqiu Hu, Lin Wang, Zhifang Chai, Jing Chen, John K. Gibson, Weiqun Shi*. Anion-Adaptive Crystalline Cationic Material for 99TcO4- Trapping. Nature Communications. 2019, 10: 1532. Qi Sun, Lin Zhu, Briana Aguila, Praveen K. Thallapally, Chao Xu, Jing Chen, Shuao Wang*, David Rogers, Shengqian Ma*. Optimizing Radionuclide Sequestration in Anion Nanotraps with Record Pertechnetate Sorption. Nature Communications. 2019, 10: 1646. Daopeng Sheng#, Lin Zhu#, Xing Dai#, Chao Xu, Peng Li, Carolyn I. Pearce, Chengliang Xiao*, Jing Chen, Ruhong Zhou, Tao Duan, Omar K. Farha, Zhifang Chai, Shuao Wang*. Successful Decontamination of 99TcO4- in Groundwater at Legacy Nuclear Sites by a Cationic Metal-Organic Framework with Hydrophobic Pockets. Angewandte Chemie International Edition. 2019, 58(15): 4968-4972. Fangli Fan, Zhi Qin*, Shiwei Cao, Cunmin Tan, Qinggang Huang, Desheng Chen, Jieru Wang, Xiaojie Yin, Chao Xu, Xiaogui Feng. Highly Efficient and Selective Dissolution Separation of Fission Products by an Ionic Liquid [Hbet][Tf2N]: A New Approach to Spent Nuclear Fuel Recycling. Inorganic Chemistry. 2019, 58(1): 603-609. Hele Liang, Qingde Chen*, Chao Xu, Xinghai Shen*. Selective cloud point extraction of uranium from thorium and lanthanides using Cyanex 301 as extractant. Separation and Purification Technology. 2019, 210: 835-842. Lei Xu#, Ning Pu#, Taoxiang Sun, Youzhen Li, Pingping Wei, Jing Chen*, Chao Xu*. Complexation of Pu(VI) with N,N,N’,N’-tetramethyl-3-oxa-glutar-amide (TMOGA) and related ligands: optical properties and coordination modes. Dalton Transactions, 2018, 47: 15246-15253. Lei Mei#, Chao Xu#, Qunyan Wu, Kongqiu Hu, Liyong Yuan, Jing Chen, Chengliang Xiao, Shuao Wang, Zhifang Chai, Weiqun Shi*. A neptunium(V)-mediated interwoven transuranium-rotaxane network incorporating a mechanically interlocked [c2]daisy chain unit. Chemical Communications, 2018, 54: 8645-8648. (# equal contributions) Wenchao Wu, Taoxiang Sun, Ning Pu, Dechao Meng, Youzhen Li, Jiahao Dang, Ying Yang, Jing Chen, Chao Xu*. Thermodynamic and spectroscopic study on the solvation and complexation behavior of Ln(III) in ionic liquids: binding of Ln(III) with CMPO in C4mimNTf2. New Journal of Chemistry, 2018, 42: 9098-9109. Dechao Meng, Ning Pu, Lei Mei, Taoxiang Sun, Lei Xu, Weiqun Shi, Jing Chen, Chao Xu*. Complexation of U(VI) with diphenyldithiophosphinic acid: spectroscopy, structure and DFT calculations. Journal of Radioanalytical and Nuclear Chemistry, 2018, 317: 121-129. Taoxiang Sun, Zhiyang Zheng, Jing Chen, Jianchen Wang, Chao Xu*. Efficient co-extraction of strontium and cesium from nitric acid medium by mixtures of di-tert-butylcyclohexano-18-crown-6 and 1,3-di(2-propoxy)calix[4]arene -crown-6 in n-octanol. Separation Science and Technology, 2018, 53(3): 503-512. Taoxiang Sun*, Chao Xu, Xiaofeng Xie, Jing Chen, Xuegang Liu*. Quantum Chemistry Study on the Extraction of Trivalent Lanthanide Series by Cyanex301: Insights from Formation of Inner- and Outer-Sphere Complexes. ACS Omega. 2018, 3: 4070?4080. Jie Li, Xing Dai, Lin Zhu, Chao Xu, Duo Zhang, Mark A. Silver, Peng Li, Lanhua Chen, Yongzhong Li, Douwen Zuo, Hui Zhang, Chengliang Xiao*, Jing Chen, Juan Diwu, Omar K. Farha, Thomas E. Albrecht-Schmitt, Zhifang Chai, Shuao Wang*. 99TcO4? remediation by a cationic polymeric network. Nature Communications. 2018, 9: 3007. Wen Yao, Xiangxue Wang, Yu Liang, Shujun Yu, Pengcheng Gu, Yubing Sun, Chao Xu, Jing Chen, Tasawar Hayat, Ahmed Alsaedi, Xiangke Wang. Synthesis of novel flower-like layered double oxides/carbon dots nanocomposites for U(VI) and 241Am(III) efficient removal: Batch and EXAFS studies. Chemical Engineering Journal. 2018, 332: 775-786. Zhe Wang, Chao Xu, Yuexiang Lu*, Guoyu Wei, Gang Ye, Taoxiang Sun, Jing Chen*. Microplasma electrochemistry controlled rapid preparation of fluorescent polydopamine nanoparticles and their application in uranium detection. Chemical Engineering Journal. 2018, 344: 480-486. Rong Yi, Chao Xu, Taoxiang Sun*, Yaxing Wang, Gang Ye, Shuao Wang, Jing Chen*, Improvement of the extraction ability of bis(2-propyloxy)calix[4]arenecrown-6 toward cesium cation by introducing an intramolecular triple cooperative effect, Separation and Purification Technology, 2018, 199: 97-104. Wen Yao, Xiangxue Wang, Yu Liang, Shujun Yu, Pengcheng Gu, Yubing Sun*, Chao Xu, Jing Chen, Tasawar Hayat, Ahmed Alsaedi, Xiangke Wang*. Synthesis of novel flower-like layered double oxides/carbon dots nanocomposites for U(VI) and 241Am(III) efficient removal: Batch and EXAFS studies. Chemical Engineering Journal, 2018, 332: 775–786. Chengliang Xiao, Zohreh Hassanzadeh Fard, Debajit Sarma, Tze-Bin Song, Chao Xu*, Mercouri G. Kanatzidis*. Highly Efficient Separation of Trivalent Minor Actinides by a Layered Metal Sulfide (KInSn2S6) from Acidic Radioactive Waste. Journal of the American Chemical Society, 2017, 139(46): 16494-16497. Lin Zhu#, Daopeng Sheng#, Chao Xu#, Xing Dai, Mark A. Silver, Jie Li, Peng Li, Yaxing Wang, Yanlong Wang, Lanhua Chen, Chengliang Xiao*, Jing Chen, Ruhong Zhou, Chao Zhang, Omar K. Farha, Zhifang Chai, Thomas E. Albrecht-Schmitt, Shuao Wang*. Identifying the Recognition Site for Selective Trapping of 99TcO4– in a Hydrolytically Stable and Radiation Resistant Cationic Metal–Organic Framework. Journal of the American Chemical Society, 2017, 139(42): 14873-14876. (# equal contributions) Taoxiang Sun, Yan Zhang, Qi Wu, Jing Chen, Liangshu Xia, Chao Xu*. Comparative Study on the Extraction of Trivalent Americium and Europium by CMPO in Imidazolium-based Ionic Liquids and Dodecane. Solvent Extraction and Ion Exchange, 2017, 35(6): 408-422. Chao Xu*, Taoxiang Sun, Linfeng Rao*. Interactions of Bis(2,4,4-trimethylpentyl) dithiophosphinate with Trivalent Lanthanides in a Homogeneous Medium: Thermodynamics and Coordination Modes. Inorganic Chemistry, 2017, 56(5): 2556-2565. Qi Wu, Taoxiang Sun, Xianghai Meng, Jing Chen, Chao Xu*. Thermodynamic Insight into the Solvation and Complexation Behavior of U(VI) in Ionic Liquid: Binding of CMPO with U(VI) Studied by Optical Spectroscopy and Calorimetry. Inorganic Chemistry, 2017, 56(5): 3014-3021. Taoxiang Sun*, Chao Xu, Jing Fu, Qingde Chen, Jing Chen, Xinghai Shen*, Extraction of U(VI) by the ionic liquid hexyltributylphosphonium bis (trifluoromethylsulfonyl)imides: An experimental and theoretical study. Separation and Purification Technology, 2017, 188: 386-393. Pengyi Wang, Ling Yin, Jian Wang, Chao Xu, Yu Liang, Wen Yao, Xiangxue Wang, Shujun Yu, Jing Chen, Yubing Sun*, Xiangke Wang*. Superior immobilization of U(VI) and 243Am(III) on polyethyleneimine modified lamellar carbon nitride composite from water environment. Chemical Engineering Journal, 2017, 326: 863–874 Taoxiang Sun*, Chao Xu, Jing Chen, Wuhua Duan*. Formation of W/O Microemulsions in the Extraction of the Lanthanide Series by Purified Cyanex 301. Solvent Extraction and Ion Exchange, 2017, 35(3): 199-209. Daopeng Sheng#, Lin Zhu#, Chao Xu, Chengliang Xiao*, Yanlong Wang, Yaxing Wang, Lanhua Chen, Juan Diwu, Jing Chen, Zhifang Chai, Thomas E. Albrecht-Schmitt, Shuao Wang*. Efficient and Selective Uptake of TcO4– by a Cationic Metal–Organic Framework Material with Open Ag+ Sites. Environmental Science and Technology, 2017, 51(6), 3471-3479. Zhe Wang, Chao Xu, Yuexiang Lu*, Guoyu Wei, Gang Ye, Taoxiang Sun, Jing Chen*. Microplasma-assisted rapid, chemical oxidant-free and controllable polymerization of dopamine for surface modification. Polymer Chemistry, 2017, 8(30), 4388-4392. 45. Zhe Wang, Chao Xu, Yuexiang Lu*, Xiaotong Chen, Hang Yuan, Guoyu Wei, Gang Ye, Jing Chen*. Fluorescence sensor array based on amino acid derived carbon dots for pattern-based detection of toxic metal ions. Sensors and Actuators B: Chemical, 2017, 241, 1324-1330. Zhe Wang, Chao Xu, Yuexiang Lu*, Fengcheng Wu, Gang Ye, Guoyu Wei, Taoxiang Sun, Jing Chen*. Visualization of Adsorption: Luminescent Mesoporous Silica-Carbon Dots Composite for Rapid and Selective Removal of U(VI) and in Situ Monitoring the Adsorption Behavior. ACS Applied Materials & Interfaces, 2017, 9(8), 7392-7398. Fengcheng Wu, Gang Ye*, Rong Yi, Taoxiang Sun, Chao Xu, Jing Chen*. Novel polyazamacrocyclic receptor decorated core–shell superparamagnetic microspheres for selective binding and magnetic enrichment of palladium: synthesis, adsorptive behavior and coordination mechanism, Dalton Transactions, 2016, 45, 9553-9564. Taoxiang Sun*, Chao Xu, Jing Chen. Formation of W/O Microemulsions in the Extraction of Nd(III) by Bis(2,4,4-trimethylpentyl)dithiophosphinic Acid and Its Effect on Nd(III) Coordination. Dalton Transactions, 2016, 45: 1078-1084. Zhe Wang, Yuexiang Lu*, Hang Yuan, Zhonghua Ren, Chao Xu, Jing Chen. Microplasma-assisted rapid synthesis of luminescent nitrogen-doped carbon dots and their application in pH sensing and uranium detection. Nanoscale, 2015, 48(7): 20743-20748. Wuhua Duan*, Chao Xu, Jianchen Wang, Shuwei Wang, Jinghui Wang, Jing Chen, Demonstration of an Improved Total Partitioning Process for High Level Liquid Waste Using Annular Centrifugal Contactors, Separation Science and Technology, 2015, 50(8): 1249-1256. Chao Xu, Linfeng Rao*. Interactions of bis(2,4,4-trimethylpentyl)dithiophosphinate with NdIII and CmIII in a Homogeneous Medium: a Comparative Study of Thermodynamics and Coordination Modes. Chemistry - A European Journal, 2014, 20(45): 14807-14815. Xihong He, Chao Xu*, Jing Chen*. Extraction of Trivalent Lanthanides with Purified Cyanex 302: Determination of Distribution Coefficients and Structural Characterization of Extracted Species. Separation and Purification Technology, 2014, 132: 317-322. Wuhua Duan, Jing Chen, Jianchen Wang, Shuwei Wang, Xiaogui Feng, Xinghai Wang, Shaowei Li, Chao Xu. Application of annular centrifugal contactors in the hot test of the improved total partitioning process for high level liquid waste. Journal of Hazardous Materials, 2014, 278: 566-571 Xiaoqi Sun, Guoxin Tian, Chao Xu, Linfeng Rao*, Sinisa Vukovic*, Sung Ok Kang SO, Benjamin P. Hay. Quantifying the Binding Strength of U(VI) with Phthalimidedioxime in Comparison with Glutarimidedioxime. Dalton Transactions, 2014, 43(2): 551-557. Chao Xu, Guoxin Tian, Simon J. Teat, Guokui Liu, Linfeng Rao*. Thermodynamic and Structural Trends in Hexavalent Actinyl Cations: Complexation of Dipicolinic Acid with NpO22+ and PuO22+ in Comparison with UO22+. Chemistry - A European Journal, 2013, 19(49): 16690-16698. Chao Xu, Guoxin Tian, Simon J. Teat, Linfeng Rao*. Complexation of U(VI) with Dipicolinic Acid: Thermodynamics and Coordination Modes. Inorganic Chemistry, 2013, 52(5): 2750-2756. Chao Xu*, Gang Ye, Shuwei Wang, Wuhua Duan, Jianchen Wang, Jing Chen. Solvent Extraction of Strontium from Nitric Acid Medium by Di-tert-Butyl Cyclohexano-18-Crown-6 in n-Octanol: Extraction Behavior and Flowsheet Demonstration. Solvent Extraction and Ion Exchange, 2013, 31(7): 731-742. Chao Xu*, Chunmiao Wang, Jianchen Wang, Jing Chen. Third Phase Formation in the Extraction of Zirconium(IV) by TRPO in Kerosene, Separation Science and Technology, 2013, 48(1): 183-191. Xiaoqi Sun, Chao Xu, Guoxin Tian, Linfeng Rao*. Complexation of Glutarimidedioxime with Fe(III), Cu(II), Pb(II), and Ni(II), the Competing Ions for the Sequestration of U(VI) from Seawater. Dalton Transactions, 2013, 42(40): 14621-14627. Chao Xu*, Jianchen Wang, Jing Chen. Solvent Extraction of Strontium and Cesium – a Review of Recent Progresses, Solvent Extraction and Ion Exchange, 2012, 30(6): 623-650. (Invited Review Article) Chao Xu, Liyong Yuan, Xinghai Shen*, Maolin Zhai*. Efficient Removal of Caesium ions from Aqueous Solution Using a Calix Crown Ether in Ionic Liquids: Mechanism and Radiation Effect. Dalton Transactions, 2010, 39: 3897-3902. Chao Xu, Xinghai Shen*, Qingde Chen, Hongcheng Gao. Investigation on the Extraction of Strontium Ions from Aqueous Phase Using Crown Ether-Ionic Liquid Systems. Science in China Series B-Chemistry, 2009, 52(11): 1858-1864. Liyong Yuan, Chao Xu, Jing Peng, Ling Xu, Maolin Zhai*, Jiuqiang Li, Genshuan Wei, Xinghai Shen. Identification of the Radiolytic Product of Hydrophobic Ionic Liquid [C4mim][NTf2] During Removal of Sr2+ from Aqueous Solution. Dalton Transactions, 2009, 38: 7873-7875. Yifeng He, Qingde Chen, Chao Xu, Jingjing Zhang, Xinghai Shen*. Interaction between Ionic Liquids and beta-Cyclodextrin: A Discussion of Association Pattern. Journal of Physical Chemistry B, 2009, 113(1): 231-238. 沈兴海,徐超,刘新起,褚泰伟。离子液体在金属离子萃取分离中的应用,2006,28 (3): 129-138.

学术兼职

201908- 201908 第十届全国环境化学大会放射环境放射化学分会 共同召集人 201808- 至今 中国化学会核化学与放射化学分会 理事会副秘书长 201808- 至今 《核化学与放射化学》期刊 编委 201706- 至今 中国核学会锕系物理与化学分会 理事

推荐链接
down
wechat
bug