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个人简介

北京理工大学化学与化工学院特别研究员,日本九州大学博士、博士后,主要从事力、磁、电等多功能柔性分子基单晶材料的研究工作,作为第一作者或通讯作者在Nat. Chem., Nat. Commun., Matter, J. Am. Chem. Soc., Angew. Chem., Int. Ed.等高水平期刊发表30多篇学术论文,担任中国化学会青年化学工作者委员会委员,Chinese chemical letters以及smart molecules期刊青年编委。 教育背景 2014年4月~2016年10月日本九州大学 学术研究员 合作导师:Prof. Osamu Sato 教授 2010年10月~2014年3月日本九州大学 博士 导师:Prof. Osamu Sato 教授 2007年10月~2010年7月 中国矿业大学 硕士 导师:魏贤勇 教授 2003年10月~2007年7月 中国矿业大学 本科 导师:魏贤勇 教授 工作履历 2022年10月~至今 北京理工大学 长聘副教授/博导 2017年4月~2022年9月 北京理工大学 预聘副教授/博导 Honors and Awards 2004 JSPS Fellow, Kanagawa Academy of Science and Technology & Kyushu University 2008 New Century Excellent Talents in University of MOE 2009 Science Foundation for Distinguished Young Scholars of Fujian Province 2013 National Natural Science Foundation for Distinguished Young Scholars 2014 Leading Talents in University of Fujian Province 2014 Leading Talents in Scientific and Technological Innovation of Fujian Province

研究领域

本课题组致力于通过合理的晶体分子结构设计,获得具有新奇物理性质的分子基晶态功能材料;通过系统的性质研究和深入的结构分析,深刻揭示材料结构-性质之间的关系,从而获得新物质、发现新现象、讨论新机理。

近期论文

查看导师新发文章 (温馨提示:请注意重名现象,建议点开原文通过作者单位确认)

Li, Y.-X.; Liu, Z.-K.; Cao, J.; Tao, J.; Yao, Z.-S.* Stress-Induced Inversion of Linear Dichroism by 4,4′-Bipyridine Rotation in a Superelastic Organic Single Crystal, Angew. Chem. Int. Ed. 2023, 62, e202217977. Liu, C.; Zi, X.; Li, H.-M.; Gao, K.-G.; Hong, J.; Tao, J.; Yao, Z.-S.* Anisotropic deuteration effects on a molecular ferroelectric, Matter, 2023, doi.org/10.1016/j.matt.2023.03.017 Inversion of molecular chirality associated with ferroelectric switching in a high-temperature two-dimensional perovskite ferroelectric, Wen-Feng Deng, Yu-Xia Li, Yan-Xin Zhao, Jie-Sheng Hu, Zi-Shuo Yao,* Jun Tao,* J. Am. Chem. Soc. 2023, 145, 5545?5552. Stress-induced inversion of linear dichroism by 4,4'-bipyridine rotation in a superelastic organic single crystal, Yu-Xia Li, Zhi-Kun Liu, Jie Cao, Jun Tao, Zi-Shuo Yao,* Angew. Chem., Int. Ed. 2023, 62, e202217977. Giant thermal expansion associated with a macroscopic polarization change in a single crystal of a Zn(II) complex, Zheng Tang, Cheng-Dong Liu, Yan Zhang, Xiao-Peng Sun, Jun Tao,* Zi-Shuo Yao,* Inorg. Chem. Front. 2023, 10, 692?698. Spin-crossover behaviors of iron(II) complexes bearing halogen ligands in solid state and solution, Ju Wang, Yun Li, Rong-Jia Wei, Zheng Tang, Zi-Shuo Yao,* Jun Tao,* Inorg. Chem. 2023, 62, 1354?1361. Magnetic and dielectric switchings actuated by the rotation of the picoline ligand in an iron-based dinuclear phase-transition complex, Zheng Tang, Jun Wen, Gui-Lin Zhuang,* Rong-Jia Wei, Xiao-Peng Sun, Zi-Shuo Yao,* Jun Tao,* Inorg. Chem. 2023, 62, 266?274. Two-dimensional coordination polymer showing spin-crossover behavior with a 64 K wide hysteresis loop, Ya-Nan Dong, Zhi-Kun Liu, Jin-Peng Xue, Yun Li, Ke Sun, Zi-Shuo Yao,* Jun Tao,* Inorg. Chem. 2022, 61, 20232?20236. Synergistic valence tautomerism and fluorescence emission in a two-dimensional coordination polymer, Wen-Ting Liu, Jie-Sheng Hu, Meng Yu,* Jin-Peng Xue, Zhi-Kun Liu, Jia-Ping Wang, Jun Tao,* Chem. Commun. 2022, 58, 13903–13906.?? Synergistic strategies for the synthesis of Fe(II)-based bifunctional fluorescent spin-crossover materials, Ke Sun, Jin-Peng Xue, Zi-Shuo Yao,* Jun Tao,* Dalton Trans. 2022, 51, 16044–16054. Perspective ?? Architectural isomerism in the three-dimensional Prussian blue analogue {[CoII(TPA)]3[FeIII(CN)6][CoIII(CN)6]}: Synthesis, crystal structures, and magnetic properties, Jing-Lin Liu, Xue-Yang Ji, Jin-Peng Xue, Jie-Sheng Hu, Zi-Shuo Yao,* Jun Tao,* Cryst. Growth & Des. 2022, 22, 5092–5099. A spin-crossover framework endowed with pore-adjustable behavior by slow structural dynamics, Jin-Peng Xue, Yang Hu, Bo Zhao, Zhi-Kun Liu, Jing Xie, Zi-Shuo Yao,* Jun Tao,* Nat. Commun. 2022, 13, 3510. ?? A series of dynamic single crystals of [MII(en)3]SO4 (M = Ni, Mn, and Cd) shows tunable dielectric properties and anisotropic thermal expansion, Cong Wu, Kai-Ge Gao, Zi-Shuo Yao,* Jun Tao,* Dalton Trans. 2022, 51, 6809–6816. Altering elastic-plastic mechanical response of a series of isostructural metal-organic complex crystals, Zheng Tang, Xiao-Peng Sun, Shu-Dong Wang, Xue-Yang Ji, Yun Li, Zi-Shuo Yao,* Jun Tao,* Sci. China Chem. 2022, 65, 710–718. ?? Discovery of kinetic effect in a valence tautomeric cobalt-dioxolene complex, Xiao-Peng Sun,* Zheng Tang, Jiajia Li, Pengtao Ma, Zi-Shuo Yao, Jingping Wang, Jingyang Niu,* Jun Tao,* Inorg. Chem. 2022, 61, 4240–4245. Giant single-crystal-to-single-crystal transformations associated with chiral interconversion induced by elimination of chelating ligands, Yun Li, Bo Zhao, Jin-Peng Xue, Jing Xie, Zi-Shuo Yao,* Jun Tao,* Nat. Commun. 2021, 12, 6908. ?? Spin-crossover iron(II) long-chain complex with slow spin equilibrium at low temperatures, Qi Zhao, Jin-Peng Xue, Zhi-Kun Liu, Zi-Shuo Yao,* Jun Tao,* Dalton Trans. 2021, 50, 11106–11112. Halogen-substituted spin-crossover Fe(III) compounds with photoresponsive properties, Zhi-Kun Liu, Zi-Shuo Yao,* Jun Tao,* Inorg. Chem. 2021, 60, 10291–10301. Adjusting rotational behaviour of molecular rotors by a rational tuning of molecular structure, Hui-Miao Li, Gui-Ming Zhong, Shu-Qi Wu, Osamu Sato, Xiao-Yan Zheng, Zi-Shuo Yao,* Jun Tao,* Inorg. Chem. 2021, 60, 8042–8048. Reverse Hofmann-type spin-crossover compound showing a multichannel controllable color change in an ambient environment, Jing-Hua Yang, Yan-Xin Zhao, Jin-Peng Xue, Zi-Shuo Yao,* Jun Tao,* Inorg. Chem. 2021, 60, 7337–7344. Stepwise dielectric switching occurs in two photo-responsive complexes possessing two-dimensional structures, Yu-Xia Li, Xiao-Lei Wang, Yue Li, Osamu Sato,* Zi-Shuo Yao,* Jun Tao,* Inorg. Chem. 2021, 60, 380–386. Encapsulating low-coordinated Pt clusters within a metal-organic framework induces spatial charge separation boosting photocatalytic hydrogen evolution, Yao-Yao Wang, Zheng Tang, Xue-Yang Ji, Song Wang,* Zi-Shuo Yao,* Jun Tao,* Catal. Sci. Technol. 2020, 10, 5048–5059. Temperature-dependent hysteretic two-step spin crossover in two-dimensional Hofmann-type compounds, Yue Li, Min Liu,* Zi-Shuo Yao, Jun Tao,* Dalton Trans. 2020, 49, 7245–7251. Homochiral versus racemic polymorphs of spin-crossover iron(II) complexes with reversible LIESST effect, Ting-Ting Ma, Xiao-Peng Sun, Zi-Shuo Yao,* Jun Tao,* Inorg. Chem. Front. 2020, 7, 1196-1204. Bistable molecular materials with dynamic structures, Zi-Shuo Yao,* Zheng Tang, Jun Tao,* Chem. Commun. 2020, 56, 2071-2086. Feature Article?? Switchable on–off spin-crossover properties of iron(II) compounds by trimming intermolecular hydrogen bonds, Na Li, Jin-Peng Xue, Jing-Lin Liu, Yao-Yao Wang, Zi-Shuo Yao,* Jun Tao,* Dalton Trans. 2020, 49, 998-1001. Hot Article?? A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors, Xiao-Peng Sun, Zheng Tang, Zi-Shuo Yao,* Jun Tao,* Chem. Commun. 2020, 56, 133-136. ?? A two-dimensional spin-crossover coordination polymer exhibiting interlayer multiple C–Hδ+···Hδ?–B dihydrogen bonds, Jin-Peng Xue, Wen-Jie Wu, Quan-Song Li, Zi-Shuo Yao,* Jun Tao,* Inorg. Chem. 2019, 58, 15705-15709. Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal, Zi-Shuo Yao,* Han-Xi Guan, Yoshihito Shiota, Chun-Ting He, Xiao-Lei Wang, Shu-Qi Wu, Xiao-Yan Zheng, Sheng-Qun Su, Kazunari Yoshizawa, Xue-Qian Kong, Osamu Sato,* Jun Tao,* Nat. Comm. 2019, 10, 4805. ?? Spin crossover and photomagnetic behaviors in one-dimensional looped coordination polymers, Xiao-Peng Sun, Tao Liu, Zi-Shuo Yao,* Jun Tao,* Dalton Trans. 2019, 48, 9243-9249. Facile synthesis of homochiral compounds integrating circularly polarized luminescence and two-photon excited fluorescence, Wen-Ting Deng, Hang Qu, Zhe-Yu Huang, Lin Shi, Zhi-Yong Tang, Xiao-Yu Cao,* Jun Tao,* Chem. Commun. 2019, 55, 2210-2213. Ligand substituent effects on the spin-crossover behaviors of dinuclear iron(II) compounds, Chun-Feng Wang, Zi-Shuo Yao,* Guo-Yu Yang, Jun Tao,* Inorg. Chem. 2019, 58, 1309-1316. Solvent effects on the structural packing and spin-crossover properties of a mononuclear iron(II) complex, Xiao-Peng Sun, Rong-Jia Wei,* Zi-Shuo Yao,* Jun Tao,* Cryst. Growth Des. 2018, 18, 6853-6862. Monitoring the spin states of ferrous ions by fluorescence spectroscopy in spin-crossover-fluorescent hybrid materials, Chun-Feng Wang, Guo-Yu Yang, Zi-Shuo Yao,* Jun Tao,* Chem.–Eur. J.?2018, 24, 3218-3224.

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