Holliday, Bradley J. - The University of Texas at Austin

个人简介

National Science Foundation CAREER Award , 2009 NSF/NSEC Predoctoral Fellow, 2002 Link Foundation Energy Fellow, 1999

研究领域

The Holliday Research Group is broadly interested in studying problems at the interface of Inorganic and Materials Chemistry. In this area of inorganic materials, our interdisciplinary research includes the study of both small molecule and polymeric structures containing transition and f-block metals. Current research projects range from classic organometallic chemistry issues of transition metal bonding and reactivity to the synthesis of complex inorganic/organic hybrid structures and metallopolymers. Many of our research goals stem from the basic premise that the incorporation of active metal complexes directly into the backbone of conducting polymers has the potential to produce new hybrid materials which take full advantage of the unique properties of both components. In addition to the fabrication of new materials and devices, we strive to design and synthesize clever model systems to gain an understanding of the most fundamental properties and phenomena of conducting metallopolymer architectures (i.e. mechanisms of conductivity, redox-controlled binding, inter- vs. intra-chain charge transport, etc.). Long-term goals of our research include the development of novel polymer supported catalysts, light-emitting diodes, separation technologies, and photovoltaics based on conducting metallopolymers. Toward these goals, the skills of organic and inorganic synthesis and characterization are developed with the specific aim of producing and studying innovative materials with tangible applications.

近期论文

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Caraway, J. D.; Nguyen, M. T.; Mitchell, L. A.; Holliday, B. J. “Incorporation of Thieno[3,2-b]thiophene Moieties as Novel Electropolymerizable Groups in a Conducting Metallopolymer and Study of the Effect on Photostability,” Macromol. Rapid Commun., 2015, DOI: 10.1002/marc.201400555. Charlton, M. R.; Suhr, K. J.; Holliday, B. J.; Stevenson, K. J. “Electrochemical Modification of Indium Tin Oxide Using Di(4- nitrophenyl) Iodonium Tetrafluoroborate,” Langmuir, 2015, 31, 695-702. Mitchell, L. A.; Dinser, J. A.; Holliday, B. J. “(E) - 4- [7- (2, 3- Dihydrothieno[3, 4- b ] [1, 4] dioxin- 5- yl) - 2, 1, 3- benzothiadiazol- 4- yl] - 2- [(neopentylimino) methyl] phenol,” Acta Cryst., 2014, 70, o848-o849. Mitchell, L. A.; Holliday, B. J. “6-bromo-N-(6-bromopyridin-2-yl)-N-(4-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)phenyl)pyridin-2-amine,” Acta Cryst., 2014, 70, o797. Mitchell, L. A.; Holliday, B. J. “4-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)aniline,” Acta Cryst., 2014, 70, o803. Stevenson, K. J.; Veneman, P. A.; Gearba, R. I.; Mueller, K. M.; Holliday, B. J.; Ohta, T.; Chan, C. K. “Controlled Covalent Modification of Epitaxial Single Layer Graphene on 6H-SiC (0001) with Aryliodonium Salts using Electrochemical Methods,” Faraday Discuss., 2014, 172, 273-291. Mitchell, L. A.; Mejia, M. L; Keskin, S. G.; Holliday, B. J. "5-Phenyl-1, 2, 5-dithiazepane," Acta Cryst., 2014, 70, o285. Mitchell, L. A.; Stanley, J. M.; Espinosa De Hoyos, L.; Holliday, B. J. "A comparison of 3, 4, 6a, 7, 10, 10a-hexahydro-7, 10-epoxypyrimido[2, 1-a] isoindol-6(2H)-one and 2-(2-aminoethyl)-3a, 4, 7, 7a-tetrahydro-1H-4, 7-epoxyisoindole-1, 3(2H)-dione. Structural and reactivity differences of two homologous tricyclic imides," Acta Cryst., 2013, 69, 638-641. Glaz, M. S.; Biberdorf, J. D.; Nguyen, M. T.; Travis, J. J.; Holliday, B. J.; Vanden Bout, D. A."Perylene diimide functionalized polynorbornene: a macromolecular scaffold for supramolecular self-assembly," J. Mater. Chem. C, 2013, 1, 8060-8065. Ibarra, I. A.; Hesterberg, T. W.; Chang, J.-S.; Yoon, J. W.; Holliday, B. J.; Humphrey, S. M. "Molecular sensing and discrimination by a luminescent terbium-phosphine oxide coordination material," Chem. Comm., 2013, 49, 7156-7158. Yang, X.; Schipper, D.; Jones, R. A.; Lytwak, L. A.; Holliday, B. J.; Huang, S. "Anion- Dependent Self-Assembly of Near-Infrared Luminescent 24- and 32-Metal Cd-Ln Complexes with Drum-like Architectures," J. Am. Chem. Soc., 2013, 135, 8468-8471. Shen, Y.; Kuddes, D. D.; Naquin, C. A.; Hesterberg, T. W.; Kusmierz, C.; Holliday, B. J.; Slinker, J. D. "Improving light-emitting electrochemical cells with ionic additives," Appl. Phys. Lett., 2013, 102, 203305/1-203305/5. Yang, X.; Schipper, D.; Liao, A.; Stanley, J. M.; Jones, R. A.; Holliday, B. J. "Anion dependent self-assembly of luminescent Zn-Ln (Eu and Tb) salen complexes," Polyhedron, 2013, 52, 165-169. Yang, X.; Chan, C.; Lam, D.; Schipper, D.; Stanley, J. M.; Chen, X.; Jones, R. A.; Holliday, B. J.; Wong, W.-K.; Chen, S.; Chen. Q. "Anion-dependent construction of two hexanuclear 3d–4f complexes with a flexible Schiff base ligand," Dalton Trans., 2012, 41, 11449-11453. Ibarra, I. A.; Hesterberg, T. W.; Holliday, B. J.; Lynch, V. M.; Humphrey, S. M. "Gas sorption and luminescence properties of a terbium(III)-phosphine oxide coordination material with two-dimensional pore topology," Dalton Trans., 2012, 41, 8003-8009. Ostrowski, D. P.; Lytwak, L. A.; Mejia, M. L.; Stevenson, K. J.; Holliday, B. J.; Vanden Bout, D. A. "The Effects of Aggregation on Electronic and Optical Properties of Oligothiophene Particles," ACS Nano, 2012, 6, 5507-5513. Stanley, J. M.; Holliday, B. J. “Luminescent Lanthanide-Containing Metallopolymers,” Coord. Chem. Rev., 2012, 256, 1520-1530. Edelman, K. R.; Stevenson, K. J.; Holliday, B. J. “Conducting Metallopolymers as Precursors to Fabricate Palladium Nanoparticles/Polymer Hybrids for ORR Electrocatalytic Materials,” Macromol. Rapid Commun., 2012, (ACS Metal-Containing and Metallo-Supramolecular Polymers and Materials Symposium Issue), 33, 610-615 . Chen, X.-Y.; Yang, X. P.; Holliday, B. J. “4-(tri(1H-pyrazole-1-yl)methyl)phenol,”Acta Cryst., 2011, 67, o3045 . Duarte, D.; Dodabalapur, A.; Holliday, B. J. “Sensing mechanism in receptor-modified organic field effect transistor based vapor sensors,” IEEE Electron Device Letters, 2011, 1929-1932.