肖啸 - 四川大学 - 化学学院

个人简介

学习经历 2015.05–2019.07 美国明尼苏达大学，化学系，博士，导师：Thomas R. Hoye 2013.09–2015.05 美国明尼苏达大学，化学系，硕士，导师：Thomas R. Hoye 2009.09–2013.07 中国科学技术大学，化学系，学士工作经历 2022.07–至今四川大学，化学学院 2019.08–2022.02 美国哥伦比亚大学，化学系，博士后，导师：Colin Nuckolls

研究领域

课题组研究方向以有机合成化学为基础，包括但不局限于：手性有机光电材料的设计与合成，自下而上构建新型碳纳米结构，电化学相关的高分子材料，绿色有机合成方法，以及利用计算化学对反应过程与材料性质的探讨。

近期论文

查看导师新发文章（温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

Xiao, X.*; Cheng, Q.; Bao, S. T.; Jin, Z.; Sun, S.; Jiang, H.; Steigerwald, M. L.; Nuckolls, C.* Single-Handed Helicene Nanoribbons via Transfer of Chiral Information. J. Am. Chem. Soc. 2022, Accepted. Xiao, X.; Nuckolls, C. Helicene-Based Electron Acceptors. In Helicenes; Crassous, J., Stará, I. G., Starý, I., Eds.; Wiley-Vch: Weinheim, Germany, 2022; pp 329–371. Xiao, X.; Pederson, S. K.; Aranda, D.; Yang, J.; Wiscons, R. A.; Pittelkow, M.; Steigerwald, M. L.; Santoro, F.*; Schuster, N. J.*; Nuckolls, C.* Chirality Amplified: Long, Discrete Helicene Nanoribbons. J. Am. Chem. Soc. 2021, 143, 983–991. Xiao, X.; Hoye, T. R.* One-pot, Three-Aryne Cascade Strategy for Naphthalene Formation from 1,3-Diynes and 1,2-Benzdiyne Equivalents. J. Am. Chem. Soc. 2019, 141, 9813–9818. Xiao, X.; Hoye, T. R.* The Domino Hexadehydro-Diels–Alder Reaction Transforms Polyynes to Benzynes to Naphthynes to Anthracynes to Tetracynes (and Beyond?). Nat. Chem. 2018, 10, 838–844. (link) (Highlighted in UMN Chemistry News., Synfacts 2018, 14, 1035., and Chem 2018, 4, 2272–2274.) Xiao, X.; Wang, T.; Xu, F.; Hoye, T. R.* CuI-Mediated Bromoalkynylation and Hydroalkynylation Reactions of Unsymmetrical Benzynes: Complementary Modes of Addition. Angew. Chem. Int. Ed. 2018, 57, 16564–16568. Xiao, X.; Woods, B. P.; Xiu, W.; Hoye, T. R.* Benzocyclobutadienes: An Unusual Mode of Access Reveals Unusual Modes of Reactivity. Angew. Chem. Int. Ed. 2018, 57, 9901–9905. Lee, D.; Ross, S. P.; Xiao, X.; Hoye, T. R.* Radial Hexadehydro-Diels-Alder Reactions Chem, 2021, 7, 2527–2537. Aranda, D.; Schuster, N. J.; Xiao, X.; Ávila Ferrer, F. J.; Santoro, F.*; Nuckolls, C.* Origin of Chiroptic Amplification in Perylene-Diimide Helicenes J. Phys. Chem. C 2021, 125, 2554–2564. Shen, H.; Xiao, X.; Hoye, T. R.* Benzyne Cascade Reactions via Benzoxetenonium Ions and Their Rearrangements to o-Quinone Methides. Org. Lett. 2019, 21, 1672–1675. Shen, H.; Xiao, X.; Haj, M. K.; Willoughby, P. H.; Hoye, T. R.* BF3-Promoted, Carbene-like, C–H Insertion Reactions of Benzynes. J. Am. Chem. Soc. 2018, 140, 15616–15620. Xu, F.; Xiao, X.; Hoye, T. R.* Photochemical Hexadehydro-Diels–Alder Reaction. J. Am. Chem. Soc. 2017, 139, 8400–8403. (link) (Selected as 'SYNFACT of the month', Synfacts 2017, 13, 809.) Xu, F.; Xiao, X.; Hoye, T. R.* Reactions of HDDA-Derived Benzynes with Perylenes: Rapid Construction of Polycyclic Aromatic Compounds. Org. Lett. 2016, 18, 5636–5639. Huang, Z.; Shang, R.; Zhang, Z.; Tan, X.; Xiao, X.; Fu, Y.* Copper-Catalyzed Decarboxylative Coupling of Alkynyl Carboxylates with 1,1-Dibromo-1-alkenes. J. Org. Chem. 2013, 78, 4551–4557. Shang, R.; Huang, Z.; Xiao, X.; Lu, X.; Fu, Y.*; Liu, L. β-Aryl Nitrile Construction via Palladium-Catalyzed Decarboxylative Benzylation of α-Cyano Aliphatic Carboxylate Salts. Adv. Synth. Catal. 2012, 354, 2465–2472.