Jäkle, Frieder - Rutgers University-Newark

个人简介

Education and Work Experience 2018 - curr. Chair, Department of Chemistry, Rutgers University 2016 - curr. Distinguished Professor, Rutgers University 2013 - 2016 Graduate Program Coordinator, Department of Chemistry, Rutgers University Newark 2009 - 2010 Alexander von Humboldt Foundation Visiting Professor, Goethe Universitat Frankfurt, Germany 2009 - 2016 Full Professor, Rutgers University 2006 - 2009 Associate Professor, Rutgers University 2000 - 2006 Assistant Professor, Rutgers University 1997 - 2000 Post-Doctoral Fellow, University of Toronto 1997 Ph.D. summa cum laude, TU München 1994 Diploma (Chemistry), TU München, Germany Fellowships and Academic Awards Named ACS Fellow (2019) Rutgers University Board of Trustees Award for Excellence in Research (2017) ACS Akron Section Award (2012) Boron Americas Award (2012) Visiting Professorship, Jinan University, China (2010-11) Search for Electroactive Materials (SEAM) Award (2009) Alexander von Humboldt Foundation, Friedrich Wilhelm Bessel Research Prize (2009) Rutgers University-Newark Hosford Award Lectureship (2007) Rutgers University Board of Trustees Fellowship (2006) Alfred P. Sloan Fellowship (2006-2008) National Science Foundation CAREER Award (2004-2008) DFG Postdoctoral Fellowship (1997-1999) Studienabschlußstipendium by the Fonds der chemischen Industrie (FCI) (1997) Gerhard Martin Julius Schmitt Award by the Minerva Foundation (1997)

研究领域

Main Group Chemistry & Functional Polymeric Materials Our research focuses on the development of new functional molecular and polymeric materials with interesting and unusual optical, electronic, catalytic, sensory, or stimuli responsive properties. The following are some specific examples of research topics that we are currently pursuing: Project A: Boron-doped Conjugated Oligomers, Macrocycles, and Polymers: We target new conjugated hybrid materials for applications in organic electronics, as luminescent and sensory materials. Recent studies have focused on all-polymer solar cell and near-IR imaging applications. Project B: Lewis Pair Functionalization of Polycyclic Aromatic Hydrocarbons (PAHs): We are investigating new approaches to the functionalization of PAHs and their applications in organic electronics, singlet oxygen sensitization, and triplet-triplet annihilation. Project C: Nanostructured Luminescent and Stimulus-Responsive Materials: We use controlled polymerization methods to prepare luminescent (co)polymers, study their self-assembly, thermo-responsive properties, and (bio)sensing applications. Project D: Sustainable Chemistry: Polymer-Supported Lewis Acids and Lewis Pairs: We pursue polymer-supported Lewis acids and “frustrated” Lewis pairs (FLPs) for applications in catalysis and supramolecular materials. Project E: Pyridylborate Ligands: Toward Metal-Containing Supramolecular Materials: We develop new scorpionate-type di- and polytopic ligands for use as building blocks of supramolecular and redox-active metallopolymers. Project F: Ferrocene-Based Chiral Lewis Acids and Lewis Pairs: We investigate planar chiral ferrocenes that are functionalized with Lewis acid/base sites as ambiphilic Ligands and for stereoselective synthesis.

近期论文

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F. Vidal, J. Gomezcoello, R. A. Lalancette, F. Jäkle* J. Am. Chem. Soc. 2019, in press; DOI: 10.1021/jacs.9b07452 "Lewis Pairs as Highly Tunable Dynamic Crosslinks in Transient Polymer Networks" M. K. Baraniak, R. A. Lalancette, F. Jäkle* Chem. Eur. J. 2019, in press; DOI: 10.1002/chem.201903196 "Electron-deficient Borinic Acid Polymers: Synthesis, Supramolecular Assembly, and Examination as Catalysts in Amide Bond Formation" A. C. Tagne Kuate, R. A. Lalancette, T. Bannenberg, M. Tamm, F. Jäkle* Dalton Trans. 2019, in press; DOI:10.1039/C9DT02728A "Diferrocenylmercury Diphosphine Diastereomers with Unique Geometries: trans-Chelation at Pd(II) with Short Hg(II)…Pd(II) Contacts" H. Lin, C. McConnell, B. Jilus, S.-Y. Liu,* F. Jäkle* Macromolecules 2019, 52, 4500-4509; DOI: 10.1021/acs.macromol.9b00466 "Changing up BN-Styrenes: Effect of Substitution Pattern on the Free Radical Polymerization and Polymer Properties" Y. Yu, C. Dong, A. F. Alahmadi, B. Meng,* J. Liu,* F. Jäkle,* L. Wang J. Mater. Chem. C 2019,7, 7427-7432; DOI: 10.1039/C9TC01562K "A p-π* Conjugated Triarylborane as an Alcohol-Processable n-Type Semiconductor for Organic Optoelectronic Devices" M. Vanga, R. A. Lalancette, F. Jäkle Chem. Eur. J. 2019, 25, 10133-10140; DOI: 10.1002/chem.201901231; "Hot Paper" "Controlling the Optoelectronic Properties of Pyrene by Regioselective Lewis Base-Directed Electrophilic Aromatic Borylation" K. Liu, R. A. Lalancette, F. Jäkle* J. Am. Chem. Soc. 2019, 141, 7453-7462; DOI: 10.1021/jacs.9b01958 "Tuning the Structure and Electronic Properties of B-N fused Dipyridylanthracene and Implications on the Self-Sensitized Reactivity with Singlet Oxygen" F. Vidal, F. Jäkle*, Angew. Chem. Int. Ed. 2019, 58, 5846-5870; DOI: 10.1002/anie.201810611 "Functional Polymeric Materials Based on Main Group Elements" A. C. Tagne Kuate, R. A. Lalancette, F. Jäkle*, Organometallics 2019, 38, 677-687; DOI: 10.1021/acs.organomet.8b00862 "Mechanistic Studies into the Sn/Hg Exchange Reaction of 1,2-Fc(PPh2)(SnMe3) with HgCl2: Competitive Sn-Me over Sn-Fc Cleavage in Non-Coordinating Solvents" F. Jäkle*, Chapter 4 in "New Polymeric Materials Based on Element-Blocks", Y. Chujo, Ed; Springer Nature, Singapore, 2019, pp 59-76. ISBN 978-981-13-2889-3; DOI: 10.1007/978-981-13-2889-3_4 "Borylated Polystyrenes as Versatile Functional Materials" T. A. Welsh, A. Laventure, A. F. Alahmadi, G. Zhang, T. Baumgartner, Y. Zou, F. Jäkle,* G. C. Welch*, ACS Appl. Energy Mater. 2019, 2, 1229-1240; DOI: 10.1021/acsaem.8b01793 "Borane Incorporation in a Non-Fullerene Acceptor To Tune Steric and Electronic Properties and Improve Organic Solar Cell Performance" Y. Ren, F. Jäkle*, Chapter 4 in "Main Group Strategies towards Functional Hybrid Materials", T. Baumgartner, F. Jäkle, Eds. John Wiley & Sons Ltd, Chichester, 2018, pp 79-110. "Incorporation of Group 13 Elements into Polymers" (ISBN 9781119235958) A. F. Alahmadi, R. A. Lalancette, F. Jäkle*, Macromol. Rapid Commun. 2018, 39, 1800456; DOI: 10.1002/marc.201800456 "Highly Luminescent Ladderized Fluorene Copolymers Based on B–N Lewis Pair Functionalization" R. Zhu, M. K. Baraniak, F. Jäkle, G. Liu*, J. Phys. Chem. B 2018, 122, 8293-8300; DOI: 10.1021/acs.jpcb.8b06125 "Anion Specificity in Dimethylsulfoxide-Water Mixtures Exemplified by a Thermosensitive Polymer" A. C. Tagne Kuate, R. A. Lalancette, F. Jäkle*, Angew. Chem. Int. Ed. 2018, 57, 6552-6557; DOI: 10.1002/anie.201803086 "Diferrocenylmercury-Bridged Diphosphine: A Unique Chiral, Ambiphilic, and Redox-active Bidentate Ligand" F. Vidal, H. Lin, C. Morales, F. Jäkle*, Molecules 2018, 23, 405; DOI: 10.3390/molecules23020405; "Polysiloxane/Polystyrene Thermo-Responsive and Self-Healing Polymer Network via Lewis Acid-Lewis Base Pair Formation" B. Meng, Y. Ren, J. Liu,* F. Jäkle,* L. Wan, Angew. Chem. Int. Ed. 2018, 57, 2183-2187; DOI: 10.1002/anie.201712598; "p-π Conjugated Polymers Based on Stable Triarylborane with n-Type Behavior in Optoelectronic Devices" Y. Adachi, Y. Ooyama, Y. Ren, X. Yin, F. Jäkle,* J. Ohshita*, Polym. Chem. 2018, 9, 291-299; DOI: 10.1039/C7PY01790A; "Hybrid Conjugated Polymers with Alternating Dithienosilole or Dithienogermole and Tricoordinate Boron Units" K. Liu, R. A. Lalancette, F. Jäkle*, J. Am. Chem. Soc. 2017, 139, 18170-18173; DOI: 10.1021/jacs.7b11062 "B-N Lewis Pair Functionalization of Anthracene: Structural Dynamics, Optoelectronic Properties and O2 Sensitization" X. Yin, K. Liu, Y. Ren, R. A. Lalancette, Y.-L. Loo, F. Jäkle*, Chem. Sci. 2017, 8, 5497-5505; DOI: 10.1039/c6sc03097a "Pyridalthiadiazole Acceptor-Functionalized Triarylboranes with Multi-Responsive Optoelectronic Characteristics"