Cowley, Alan H. - The University of Texas at Austin

个人简介

Fellow of the Royal Society, 1999

研究领域

The primary focus of research in the Cowley lab is synthetic main group chemistry. This includes the synthesis and reactivity of novel 1,2-bis(imino)ancenaphthene (BIAN) and tetrakis(imino)pyracene (TIP) complexes, and research done in conjuction with the Center for Electrochemistry focusing on ionic liquids and Group 13/15 semiconductor materials for use in photovoltaic applications.

近期论文

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Powell, Adam B.; Bielawski, Christopher W.; Cowley, Alan H. Design, Synthesis, and Study of Main Chain Poly(N-Heterocyclic Carbene) Complexes: Applications in Electrochromic Devices J. Am. Chem. Soc. (2010), 132(29), 10184-10194. Raj, D. B. Ambili; Francis, Biju; Reddy, M. L. P.; Butorac, Rachel R.; Lynch, Vincent M.; Cowley, Alan H. Highly Luminescent Poly(Methyl Methacrylate)-Incorporated Europium Complex Supported by a Carbazole-Based Fluorinated β-Diketonate Ligand and a 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene Oxide Co-Ligand Inorg. Chem. (2010), 49(19), 9055-9063. Findlater, Michael; Hill, Nicholas J.; Cowley, Alan H. Pentacarbonyl(trimethylamine)chromium and pentacarbonyl(trimethylamine)molybdenum J. Chem. Crystallogr (2010), 40(1), 64-66 Hill, Nicholas J.; Reeske, Gregor; Cowley, Alan H. Reactions of the persistent phosphinyl radical ·P[CH(SiMe3)2]2 with elemental chalcogens Main Group Chem. (2010), 9(1,2), 5-10 Vasudevan, Kalyan V.; Butorac, Rachel R.; Abernethy, Colin D.; Cowley, Alan H. Synthesis and coordination compounds of a bis(imino)acenaphthene (BIAN)-supported N-heterocyclic carbene Dalton Trans. (2010), 39(31), 7401-7408 Sivakumar, Sarika; Reddy, M. L. P.; Cowley, Alan H.; Vasudevan, Kalyan V. Synthesis and crystal structures of lanthanide 4-benzyloxy benzoates: Influence of electron-withdrawing and electron-donating groups on luminescent properties Dalton Trans. (2010), 39(3), 776-786. Ramya, A. R.; Reddy, M. L. P.; Cowley, Alan H.; Vasudevan, Kalyan V. Synthesis, Crystal Structure, and Photoluminescence of Homodinuclear Lanthanide 4-(Dibenzylamino)benzoate Complexes Inorg. Chem. (2010), 49(5), 2407-2415 Powell, Adam B.; Bielawski, Christopher W.; Cowley, Alan H. SYNTHESIS, STUDY, AND APPLICATIONS OF POLYMERIC N-HETEROCYCLIC CARBENES Comment Inorg. Chem. (2010), 31(3-4), 75-82 Biju, Silvanose; Reddy, M. L. P.; Cowley, Alan H.; Vasudevan, Kalyan V. 3-Phenyl-4-acyl-5-isoxazolonate complex of Tb3+ doped into poly-β-hydroxybutyrate matrix as a promising light-conversion molecular device J. Mater. Chem. (2009), 19(29), 5179-5187 Biju, Silvanose; Ambili Raj, D. B.; Reddy, M. L. P.; Jayasankar, C. K.; Cowley, Alan H.; Findlater, Michael Dual emission from stoichiometrically mixed lanthanide complexes of 3-phenyl-4-benzoyl-5-isoxazolonate and 2,2'-bipyridine J. Mater. Chem. (2009), 19(10), 1425-1432. Powell, Adam B.; Bielawski, Christopher W.; Cowley, Alan H. Electropolymerization of an N-Heterocyclic Carbene-Gold(I) Complex J. Am. Chem. Soc. (2009), 131(51), 18232-18233. Powell, Adam B.; Brown, Jaclyn R.; Vasudevan, Kalyan V.; Cowley, Alan H. Facile syntheses of thiophene-substituted 1,4-diazabutadiene (α-diimine) ligands and their conversion to phosphenium triiodide salts Dalton Trans. (2009), (14), 2521-2527 Korotkikh, Nikolai I.; Cowley, Alan H.; Moore, Jennifer A.; Glinyanaya, Nataliya V.; Panov, Ilia S.; Rayenko, Gennady F.; Pekhtereva, Tatyana M.; Shvaika, Oles P. Reaction of 1-tert-butyl-3,4-diphenyl-1,2,4-triazol-5-ylidenes with a malonic ester Org. Biomol. Chem. (2008), 6(1), 195-199. Vasudevan, Kalyan V.; Findlater, Michael; Cowley, Alan H. Synthesis and reactivity of tetrakis(imino)pyracene (TIP) ligands; bifunctional analogues of the BIAN ligand class Chem. Comm. (2008), (16), 1918-1919. Findlater, Michael; Hill, Nicholas J.; Cowley, Alan H. Synthesis and structure of two new (guanidinate)boron dichlorides and their attempted conversion to boron(i) derivatives Dalton Trans. (2008), (33), 4419-4423 Vidovic Dragoslav; Reeske Gregor; Findlater Michael; Cowley Alan H Synthesis and structures of boron dihalides supported by the C(6)F(5)-substituted beta-diketiminate ligand [HC(CMe)(2)(NC(6)F(5))(2)](-) Dalton Trans. (2008), (17), 2293-7 Vidovic, Dragoslav; Findlater, Michael; Cowley, Alan H. A β-Diketiminate-Supported Boron Dication J. Am. Chem. Soc. (2007), 129(27), 8436-8437. Lu, Zheng; Hill, Nicholas J.; Findlater, Michael; Cowley, Alan H. Diboron complexes of binucleating bis(amidinate) ligands Inorg. Chim. Acta (2007), 360(4), 1316-1322 Lu, Zheng; Findlater, Michael; Cowley, Alan H. "A ?-diketiminato hydroxyphosphenium cation: phosphinous acid-secondary phosphine oxide tautomerism revisited" Chem. Comm. 34 (2008): 184-186. Reeske, Gregor; Hoberg, Clint R.; Cowley, Alan H. "One-Step redox route to N-heterocyclic phosphenium ions" Inorganic Chemistry 46 (2007): 4358.